• Title/Summary/Keyword: phase morphology

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The Effect of The Second Phase Morphology on the Micro And Macro Fracture Behaviour of Dual Phase Steel (鋼 의 微視 및 巨視的 破壞擧動 에 미치는 第二相形態 의 영향)

  • 김정규;송삼홍;이장현
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.6 no.3
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    • pp.239-246
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    • 1982
  • The effect of the second phase morphology on the fracture ductility of dual phase steel was studied by means of tensile tests carried out room temperature. In this case the second phase morphology is characterized by two kinds; one is the MEF microstructure in which martensite encapsulated islands of ferrite, the other is the FEM microstructure in which ferrite encapsulated islands of martensite. The fracture ductility is improved by variation of the second phase morphology, but is essentially uneffected in the range of high strength ratio (4.7). Also the variation of ductility is well understood according to the difficulty of cleavage crack formation of the ferrite grain and to the brittleness of the martensitic structure.

Morphological Effect of Dispersed Phase on Gas Separation Properties through Heterophase Polymer Membrane: Theoretical and Experimental Approaches.

  • Park, Cheolmin;Jo, Won-Ho;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.55-56
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    • 1996
  • Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

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Effects of the Morphology of Secondary Phases and Carbon Content on the Plastic Deformation of TRIP steel (변태유기소성강의 소성변형에 미치는 2차상의 형상과 고용탄소의 영향)

  • 홍승갑
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.116-119
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    • 1999
  • The effects of secondary phase morphology and carbon content on the plastic deformation of 0.2C-1.5Si-1.5mn TRIP(TRansformed Induced Plasticity) steel have been investigated at various annealing and bainitic transformation temperatures. The morphology of ferrite and secondary phases was controlled by the annealing temperature and the distribution of secondary phase was controlled by the bainitic transformation temperature. The secondary phase contributed to elongation and/or UTS depending on the ferrite morphology which determined deformation mode simple elongation or rotation of secondary phase along the tensile direction In case of the sample containing the granular type retained austenite the elongation was improved as carbon stabilized the austenite phase. If the film-shape retained austenite in acicular ferrite was dominant however UTS was enhanced as the transformed martensite was hardened by carbon.

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Phase Morphology and Foaming of Polypropylene/Ethylene-octene Copolymer Blends (폴리프로필렌/에틸렌옥텐 공중합체 블렌드의 상분리 구조 및 발포 특성)

  • 서관호;임정철
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.707-718
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    • 2001
  • Polypropylene (PP) exhibits many beneficial properties such as low density high thermal stability, chemical resistance, good processability and recyclability. However, only limited research has been done on expanded polypropylene (EPP). In this study, we were trying to prepare EPP with chemical blowing agent. Ethylene-octene copolymer (mPE) was melt blended with PP to enhance melt fluidity of PP at processing temperature and to make more flexible foamed material. Prior to foaming, phase morphology of PP/mPE blends were investigated to examine the effect of phase morphology on the foaming ratio and cell structure of foams. Phase morphology of PP/mPE blends were affected by the content of mPE and mixing torque ratio. At the same composition, it was affected by mixing rpm. High blowing ratio and stable cell structure were obtained in the blend which has the continuous PP matrix with dispersed droplets of mPE.

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Morphology of Sub-Microscale Atmospheric Aerosols composed of Two Liquid Phases According to the Loading Ratio of Organics/Water

  • Yoo, Kee-Youn
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.130-134
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    • 2017
  • Organic aerosols dispersed in the atmosphere likely undergo phase separation. Such internally mixed particles are often described as comprising an organic phase and an aqueous phase separately. We studied the morphology of two liquid separated aerosols in the sub-microscale by using a simple thermodynamic model with Russian doll geometry. The morphology of particles can be easily predicted from the simple criteria on the surface tension and two algebraic equations (the volume constraint and Young equation). This result may give the potential explanation about the complex morphology of the organic airborne particles.

Morphology Development of HAp Crystallites in GEL Matrix

  • Chang, Myung-Chul
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.133-136
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    • 2007
  • The crystal morphology of hydroxyapatite [HAp] phase in gelatin [GEL] matrices was investigated with the condition of a GEL precursor treatment in an aqueous solution of $H_{3}PO_{4}$ at $37-80^{\circ}C$. Needle-shaped nanocomposite particles were prepared through a dynamic reaction during a coprecipitation process using a phosphoric GEL solution. Various types of mineralized morphology appeared with a phosphorylated condition of the GEL solution. HAp/GEL nanocomposite slurries showed the existence of an octacalcium phosphate [OCP] phase during the process.

Beryllium Effects on the Morphology of Iron Intermetallics in the A356 Aluminium Casting Alloy (주조용 A356합금에서 Fe계 금속간화합물의 형상에 미치는 Be의 영향)

  • Lee, Jeong-Keun;Park, Chong-Sung;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.18 no.4
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    • pp.357-363
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    • 1998
  • Microstructure of A356 aluminium alloys cast in a permanent mold was investigated by optical microscope and image analyzer, with particular respect to the shape and size distribution of iron intermetallics known as ${\beta}-phase$ ($Al_5FeSi$). Morphologies of the ${\beta}-phase$ was found to change gradually with the Be:Fe ratio like these. In Be-free alloys, ${\beta}-phase$ with needlelike morphology was well developed, but script phase was appeared when the Be:Fe ratio is above 0.2:1. With the Be:Fe ratios of 0.4:1-1:1, script phase as well as Be-rich phase was also observed. In case of higher Be addition, above 1:1, Be-rich phase was observed on all regions of the specimens, and increasing of the Be:Fe ratios gradually make the Be-rich phase coarse. It was also observed that the ${\beta}-phase$ with needlelike morphology was coarsened with increase of the Fe content in Be-free alloys. However, in Be-added alloys, length and number of these ${\beta}-phases$ were considerably decreased with the increased Be:Fe ratio. It was concluded that Fe impurity element to be crystallized into needlelike intermetallics was tied up by Be addition element, and new phases were crystallized into script or Be-rich intermetallics.

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Polyetherimide/Dicyanate Semi-interpenetrating Polymer Networks Having a Morphology Spectrum

  • Kim, Yu-Seung;Min, Hyun-Sung;Kim, Sung-Chun
    • Macromolecular Research
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    • v.10 no.2
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    • pp.60-66
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    • 2002
  • The morphology, dynamic mechanical behavior and fracture behavior of polyetherimide (PEI)/dicyanate semi-interpenetrating polymer networks (semi-IPNs) with a morphology spectrum were analyzed. To obtain the morphology spectrum, we disported PEI particles in the procured dicyanate resin containing 300 ppm of zinc stearate catalyst. The semi-IPNs exhibited a morphology spectrum, which consisted of nodular spinodal structure, dual-phase morphology, and sea-island type morphology, in the radial direction of each dispersed PEI particle due to the concentration gradient developed by restricted dissolution and diffusion of the PEI particles during the curing process of the dicyanate resin. Analysis of the dynamic mechanical data obtained by the semi-IPNs demonstrated that the transition of the PEI-rich phase was shifted toward higher temperature as well as becoming broader because of the gradient structure. The semi-IPNs with the morphology spectrum showed improved fracture energy of 0.3 kJ/$m^2$, which was 1.4 times that of the IPNS having sea-island type morphology. It was found that the partially introduced nodular structure played a crucial role in the enhancement of the fracture resistance of the semi-IPNs.

Vitrification Phenomena in Polysulfone/NMP/water system (폴리술폰/NMP/물 계의 고화 현상에 관한 연구)

  • Kim, Je-Young;Kanamori, Toshiyuki;Lee, Hwan-Kwang;Baik, Ki-Jun;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.53-55
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    • 1998
  • 1. INTRODUCTION : Since the knowledge of vitrification phenomena can lead to a better understanding of the mechanism of membrane formation, it is desirable to include vitrification line into the phase diagrams. While the final morphology obtained during phase inversion depends upon the kinetics as well as the thermodynamics of the phase separation, the equilibrium phase diagram and vitrification line for amorphous polymers are still a good tool for controlling the morphology and interpreting the membrane structure.

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Morphology of Silk Fibroin/Poly(vinyl alcohol) Blend Film (견피브로인/Poly(vinyl alcohol) 브렌드 필름의 형태학적 구조)

  • 엄인철;박영환
    • Journal of Sericultural and Entomological Science
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    • v.40 no.2
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    • pp.169-175
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    • 1998
  • The morphology of silk fibroin/poly(vinyl alcohol)(PVA)blend films was investigated using optical microscopy and confocal laser scanning microscopy. The effects of blend ratio and molecular weight of silk fibroin and PVA on phase separation were studied. Macro-phase separation occurred for the silk fibroin-rich/poor region whereas micro-phase separation took place for the dispersed/continuous phase, In spite of differences in molecular weight and blend ratio, it is observed that the dispersed phase and continuous one are composed of silk fibroin and PVA component, respectively. As the molecular weight of silk fibroin and silk fibroin content in blend ratio are decreased, the compatibility of blend is increased due to the reduction of micro-phase separation.

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