• Title/Summary/Keyword: physico-chemical changes

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Postmortem Changes in the Physico-Chemical Characteristics of Korean Native Chicken (저장기간에 따른 한국산 토종닭고기의 품질 특성)

  • 성삼경;권연주;김대곤
    • Korean Journal of Poultry Science
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    • v.25 no.2
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    • pp.55-64
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    • 1998
  • This study was carried out to investigate the postmortem changes in physico-chemical characteristics of chicken meat with different breeds. Thigh and breast meats from Korean Native Chicken(KNC, 15-wk old), Wangchoo(15-wk old), and broiler(7-wk old) were stored at 5 ˚C. Differences in postmortem pH changes were not recognized among breeds, and pH showed by the lowest value at the 1st day of postmortem in all breeds. Breast meat had tendency to drop pH faster than thigh meat. Heme pigment contents showed no differences among breeds. KNC showed the lowest cholesterol contents in all breeds, total collagen contents showed the lowest value at the 1st day of postmortem, and thereafter it was gradually increased. Heat soluble collagen contents was lowest in Wangchoo. Water soluble and salt soluble protein showed the lowest extractability at the 1st day of storage. Broiler showed the highest extractability of these proteins and Wangchoo showed the lowest. Water holding capacity(WHC) had increasing tendency whilst cooking loss had decreasing tendency by the ageing. WHC of breast and thigh meat showed the highest values in KNC and broiler, respectively. Myofibrillar fragmentation index (MFI) was significantly increased in all breeds by the ageing. Breast and thigh meat showed almost same MFI in KNC and broiler, and in KNC and Wangchoo, respectively. Hardness of breast meat showed decreasing tendency by the ageing.

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Density Functional Theoretical Study on Intermolecular Interactions of 3,6-Dihydrazino-1,2,4,5-tetrazine Dimers

  • Hu, Yin;Ma, Hai-Xia;Li, Jun-Feng;Gao, Rong;Song, Ji-Rong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2897-2902
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    • 2010
  • Seven fully optimized geometries of 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) dimers have been obtained with density functional theory (DFT) method at the B3LYP/$6-311++G^{**}$ level. The intermolecular interaction energy was calculated with zero point energy (ZPE) correction and basis set superposition error (BSSE) correction. The greatest corrected intermolecular interaction energy of the dimers is $-23.69\;kJ{\cdot}mol^{-1}$. Natural bond orbital (NBO) analysis is performed to reveal the origin of the interaction. Based on the vibrational analysis, the changes of thermodynamic properties from the monomers to dimer with the temperature ranging from 200.0 K to 800.0 K have been obtained using the statistical thermodynamic method. It was found that the hydrogen bonds dominantly contribute to the dimers, while the binding energies are not only determined by hydrogen bonding. The dimerization process can not occur spontaneously at given temperatures.

Physico-Chemical Properties of Ginseng Leaf Tea As Affected by Decontamination Treatment (인삼엽록차의 살균처리에 따른 이화학적 특성 변화)

  • 김영회;권중호;변명우;이수정;조한옥
    • Journal of Food Hygiene and Safety
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    • v.6 no.1
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    • pp.49-56
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    • 1991
  • Physico-chemical properties were investigated on ginseng leaf tea which was decontaminated by the current ethylene oxide fumigation and gamma irradiation, respectively. Chemical components such as soluble matter, saponin and polyphenols were found to be stable to both treatments, while ascorbic acid and chlorophylls were relatively labile to fumigation and irradiation more than 5 kGy. Instrumental analysis has shown that EO fumigation causes apparent changes in pH and color of extracts and volatile profile of the sample, as compared to negligible changes in the irradiated sample at a decontaminating dose, 5 kGy.

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Physico-chemical properties and mechanism of color change of methyl 5-hydroxy-dinaphtho [1, 2-2', 3'] furan-7, 12-dione-6-carboxylate (메틸 5-하이드록시 디나프토 [1, 2-2', 3'] 후란-7, 12 디온 6-키복시레이트의 물성 및 변색기전)

  • 장혜선;박유미;강경환;우영아;박정일;김박광
    • YAKHAK HOEJI
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    • v.37 no.2
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    • pp.198-203
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    • 1993
  • Physico-chemical properties of methyl 5-hydroxy-dinaphtho[1,2-2',3'] furan-7,12-dione-6-carboxylate(MHDDC) were examined. The yellowish color of the solution at pH 8 below changes to a bluish color when the solution is basified to pH 10 above. This color change was presumed to a change of the molecular structure from a quinoid-type to a quinoid-type with the dissociation to the hydroxyl group as shown in chart 1.

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Effects of Soil Amendment Application on Soil Physico-chemical Properties and Yields of Summer Forage Crops in the Sukmoon Reclaimed Tidal Land in Korea (석문 간척지에서 돈분액비 및 석고처리가 여름철 사료작물 수량 및 토양이화학성에 미치는 영향)

  • Choi, Ki-Choon;Yoon, Sei-Hyung;Shin, Jae-Soon;Kim, Dong-Kwan;Han, Hyo-Shim;Supanjani, Supanjani;Lee, Kyung-Dong
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.354-361
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    • 2010
  • Soil physico-chemical properties and microbial densities are affected by organic sources and soil amendment applied to improve soil environments or quality. Generally organic fertilizer effects on forage crops yield and soil properties are partly due to changes of soil composition. We investigated the effects of swine slurry (SS), swine slurry composting-biofilteration(SCB) and chemical fertilizer(F) with gypsum(G) combinations on soil physico-chemical properties and yields of summer forage crop in the Sukmoon reclaimed tidal land in Korea. The forage crops used in this experiment were corn and sorghum$\times$sudangrass hybrid(hereafter sorghum). Our results showed that the soil physico-chemical properties in the combined (F+G, SS+G, SCB+G) treatments increased contents of organic matter and exchangeable $Ca^{2+}$, but exchangeable $Na^+$, $K^+$ and $Mg^{2+}$ reduced to 1-10% for two forage crops, compared to non-combined (F, SS, SCB) treatment. The density of soil microorganism such as bacteria, actinomycetes and fungi, increased significantly by SS+G and SCB+G treatments. This means that treatment of combined organic fertilizer with G lowered salinity levels and improved with microbial growth. The combined treatments also increased the total yields 2.3-6.2% for corn and 2.0-8.7% for sorghum, compared with non-combined treatment. This experiment suggests the combined treatments could increase the total yields of summer forage crops and change of soil physico-chemical properties in the Sukmoon reclaimed tidal land in Korea.

Property Enhancement of SiR-EPDM Blend Using Electron Beam Irradiation

  • Deepalaxmi, R.;Rajini, V.
    • Journal of Electrical Engineering and Technology
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    • v.9 no.3
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    • pp.984-990
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    • 2014
  • Polymers are the most commonly used di-electrics because of their reliability, availability, ease of fabrication and cost. The commercial and industrial demand for advanced polymeric materials which are capable of being used in harsh environment is need of the hour. The study of the effect of electron beam irradiation on polymeric materials is an area of rapidly increasing interest. This paper discusses the resultant beneficial effects of electron beam irradiation on the SiR-EPDM blend having 50:50 composition. The changes in mechanical and electrical properties of SiR-EPDM blend which are exposed to three different doses of electron beam radiation namely 5 Mrad, 15 Mrad and 25 Mrad are presented. The irradiated blends are analyzed for their electro-mechanical and physico chemical properties. The electrical changes induced by irradiation are investigated by arc resistance, surface resistivity and volume resistivity measurements as per ASTM standards. The mechanical changes are observed by the measurement of tensile strength and elongation at break. Physico chemical investigation has been done using the FTIR, in order to investigate the irradiation induced chemical changes.

A Study on Seasonal Changes of Lakes Water Quality Characteristics -Based on experiments in the SEOSAN area- (호수의 계절별 수질 특성에 관한 연구 - 서산 지역을 중심으로 -)

  • 이영신
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.128-132
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    • 1998
  • In this study, water quality characteristics of lakes in the Seosan area are analyzed. Components water quality were analysed at 10 sampled points in each lakes, and the results were evaluated for seasonal variation. It was found that water quality was over II~III class. Most of lakes in the Seosan area which implies that are suitable as the maintenance water. The concenturation of T-N, T-P was observed IV~V class during all seasons. Particularly, T-N concenturation peaks in spring, while was lowered in other seasons. In the lake, high concenturation of T-N, T-P bring about Eutrophication when algae was growth causing various physico-chemical changes in the water. It is suggested that the water quality management strategies need to be applied for each lake.

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The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped land VI. Relationship between annual change of soil phsico-chemical properties and yield of silage corn (신개간경사지 토양개량과 작물생육에 관한 연구 VI. 토양의 물리화학성 년차간 변화가 옥수수 청예수량에 미치는 영향)

  • 허봉구;김무성
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.1
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    • pp.22-29
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    • 1991
  • This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

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Changes in physico-chemical properties of expanded tobacco leaves by $CO_2$ process according to the storage periods (저장기간에 따른 $CO_2$ 팽화처리 원료잎담배의 이화학적 특성 변화)

  • 김병구;이규서
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.2
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    • pp.143-150
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    • 2000
  • This study was carried out to investigate the effect of storage period on the physico-chemical properties of tobacco leaves expanded by $CO_2$. The flue-cured and burley tobacco leaves produced from 1996 to 1999 were processed, and stored for that year or 3 years in processing plant. As compared with 1996 crop, the expanded rate of flue-cured tobacco leaves in 1999 crop was higher approximately 18%, while that of burley was higher about 10%. The filling capacity of cigarettes was decreased as storage time became shorter, but the combustibility was improved. The rate of large particles (over 3.36mm) of expanded tobacco showed decreasing tendency as the storage period became longer. The change rate of chemical contents in tobacco leaves between before and after expansion had no significant difference among corp years. The tar and CO contents of cigarettes smoke were reduced in the case of flue-cured tobacco leaves as storage time became shorter, while they were slightly increased in the case of burley tobacco leaves. The ammonia content of burley leaves was decreased remarkably in 1996 and 1999 crop.

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The Changes of Physico-chemical Properties of the Frying Oils during Potato and Chicken Frying (감자 및 닭튀김 중의 튀김유의 물리화학적 특성의 변화)

  • 손종연;정문숙;안명수
    • Korean journal of food and cookery science
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    • v.14 no.2
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    • pp.177-181
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    • 1998
  • The changes of the physico-chemical characteristics of potato and chicken frying oil with frying number were examined. The changes in temperatures of frying oil during the potato flying were greater than that during the chicken frying. The weight loss of potato during deep frying was about 21.9% and about 12.3% for chicken. The acid values and conjugated dienoic acid values of the potato and chicken frying oils increased with increased frying number. Their values were greater in the chicken frying oil than in the potato frying oil. The peroxide values of frying oil did not change regularly as frying number increased. But iodine values of the frying oils decreased with increased frying number. Linoleic acid content of the frying oil decreased, whereas oleic acid content increased with frying number.

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