• Title/Summary/Keyword: physico-chemical property

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Settling Characteristics of Saemankeum fine-Cohesiv Sediments : Effects of Physico-Chemical Properties (새만금 미세점착성 퇴적물의 침강특성 : 퇴적물의 물리.화학적 특성의 영향)

  • Hwang, Gyu-Nam;Jo, Yong-Sik
    • Journal of Korea Water Resources Association
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    • v.35 no.5
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    • pp.475-484
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    • 2002
  • A series of settling tests and physico-chemical property tests on Saemankeum fine-cohesive sediments has been conducted in order to investigate the correlation between settling properties and their physico-chemical properties which are represented as grain size distribution, mineralogical composition, and percentage of organic contents. Experimental results of physico-chemical property tests show that Saemankeum sediments are relatively large in average grain size(52${\mu}{\textrm}{m}$), and contain very small organic materials(2%), and are dominantly composed of Quarts in mineralogical aspect which has relatively low cohesion. Thus, Saemankeum sediments might be specified as the sediments whose settling properties are more influenced by the gravity than the cohesion. This characteristics of Saemankeum sediments are found to lead to relatively small settling velocity in flocculated settling region in which increasing cohesion results in increasing settling velocity, while relatively large settling velocity in hindered settling region in which settling velocity decreases with increasing cohesion.

Density Functional Theoretical Study on Intermolecular Interactions of 3,6-Dihydrazino-1,2,4,5-tetrazine Dimers

  • Hu, Yin;Ma, Hai-Xia;Li, Jun-Feng;Gao, Rong;Song, Ji-Rong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2897-2902
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    • 2010
  • Seven fully optimized geometries of 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) dimers have been obtained with density functional theory (DFT) method at the B3LYP/$6-311++G^{**}$ level. The intermolecular interaction energy was calculated with zero point energy (ZPE) correction and basis set superposition error (BSSE) correction. The greatest corrected intermolecular interaction energy of the dimers is $-23.69\;kJ{\cdot}mol^{-1}$. Natural bond orbital (NBO) analysis is performed to reveal the origin of the interaction. Based on the vibrational analysis, the changes of thermodynamic properties from the monomers to dimer with the temperature ranging from 200.0 K to 800.0 K have been obtained using the statistical thermodynamic method. It was found that the hydrogen bonds dominantly contribute to the dimers, while the binding energies are not only determined by hydrogen bonding. The dimerization process can not occur spontaneously at given temperatures.

Improvement on the Functional Properties of Gelatin Prepared from the Yellowfin Sole Skin by Precipitation with Ethanol (알코올처리에 의한 각시가자미껍질 젤라틴의 기능성 개선)

  • Kim, Jin-Soo;Lee, Eung-Ho
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.683-689
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    • 1994
  • With a view to utilizing effectively fish skin wastes from marine manufactory, a gelatin solution extracted from yellowfin sole skin was fractionated by precipitation with ethanol, and then the functional and physico-chemical properties for the fractionated gelatin were determined. Ethanol was added up to 50% of ethanol content to a gelatin solution extracted from yellowfin sole skin, then the mixture was left to stand at $0^{\circ}C$ for 12 hours. Finally, the precipitates were dried by hot-air ($40^{\circ}C$). The gel strength and melting point of a 10% gel of gelatin prepared from yellowfin sole skin by precipitation with ethanol has 322.4g and $23.3^{\circ}C$, respectively. The physico-chemical properties of the ethanol treated fish skin gelatin were superior to those of fish skin gelatin prepared without ethanol treatment. Besides, the functional properties of the ethanol treated gelatin were lower in solubility and higher in water holding capacity, oil binding capacity, emulsifying activity, emulsifying stability, foam expansion and foam stability than those of pork skin gelatin sold on market as well as gelatin prepared without ethanol treatment. It may be concluded, from these results, that the fish skin gelatin prepared by precipitation with ethanol can be effectively utilized as a human food by improving the functional properties.

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Comparison on Physico-Chemical and Affective Properties in Mackerel Cooked by Electric Pan and under Superheated Steam (구이용 전기팬과 과열증기로 열처리한 고등어구이의 이화학적인 품질특성 및 기호도 비교평가)

  • Yu, Gwang Yeon;Cho, In Hee
    • Korean journal of food and cookery science
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    • v.32 no.2
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    • pp.204-210
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    • 2016
  • Purpose: This study analyzed and compared the physico-chemical and affective properties between mackerels cooked by an electric pan and under superheated steam. Methods: Mackerel were cooked by an electric pan ($95^{\circ}C$) for 10 min and mackerel cooked under superheated steam ($250^{\circ}C$) for 5 min to be internal temperatures of $75{\pm}5^{\circ}C$ and tests to measure proximate composition, color values, texture profiles, microorganism counts and sensory acceptance were performed. Results: The moisture contents were 60.30% and 73.81% in mackerels cooked by electric pan and under superheated steam, respectively. The rate of weight loss in mackerel cooked by electric pan was 39%, whereas it was 29% in mackerel cooked under superheated steam. Mackerel cooked under superheated steam exhibited more yellowness, higher springiness, cohesiveness, gumminess, chewiness, and resilience with more acceptable preferences (appearance, odor, taste, and texture) compared to the mackerel cooked by electric pan. Conclusion: The application of superheated steam technology to fish products could reduce the cooking time and nutritional loss. Also, it could produce highly preferred fish products compared to that prepared by conventional electric pan.

A Study on Settling Properties of Cohesive Sediments in Shihwa Lake (시화호 점착성 퇴적물의 침강 특성에 관한 연구)

  • LEE YOUNG-JAE;LEE SANG-HWA;HWANG KYU-NAM;RYU HONG-RYUL
    • Journal of Ocean Engineering and Technology
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    • v.19 no.4 s.65
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    • pp.42-48
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    • 2005
  • The sediment of Shihwa Lake contains an abundant quantity of cohesive sediments. The transport processes of the cohesive sediments are complex and difficult to predict, quantitatively. The cohesive sediments are the primary reason for the pollution of the environment and water quality in the coastal region. In this study, a column test has been performed. In order to quantify the settling velocities of sediment from Shihwa Lake, an experiment was conducted using a specially designed 1.8m tall settling column. A series of settling tests and physico-chemical property tests on Shihwa Lake cohesive sediments has been conducted to investigate the correlation between settling properties and their physico-chemical properties, which are represented as grain size distribution, mineralogical composition, and percentage oj organic contents. Experimental results of physico-chemical property tests show that Shihwa Lake sediments are relatively large in average grain $size(74\mu m)$ contain very small organic $material(6\%)$, and are dominantly composed of Quarts, which has relatively low cohesion. Thus, Shihwa Lake sediments might be specified as those whose settling properties are more influenced by gravity than cohesion. It is concluded that the magnitude of settling velocities of muddy sediments can be quite different, regionally, and it implies that field or laboratory experiments for settling velocity measurement should be preceded over the numerical modeling of muddy sediment transport, in order to obtain the reliable prediction results for a given specific site.

A Laboratory Study on Rheological Properties of Fluid Mud (머드유동층의 유동학적 특성에 관한 실험적 연구)

  • Nguyen, Dinh Phuc;Jung, Eui-Taek;Park, Kun-Chul;Hwang, Kyu-Nam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.3
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    • pp.203-209
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    • 2012
  • In this study, rheological properties of kaolinite and three different porcelain fluid muds are quantitatively estimated with the latest rheometer, in which variations of their viscosities and yield stresses with their densities are estimated. This study also involves the measurements for the basic physico-chemical properties of fluid muds and the qualitative analysis of their correlation between physico-chemical and rheological properties. Experimental results of rheological tests show that fluid muds in general belong to Pseudo-plastic fluids and both viscosities and yield stresses of them increase exponentially with the increase of density while they are remarkably different in quantity depending on sediments.

Characterizing a Full Spectrum of Physico-Chemical Properties of Ginsenosides Rb1 and Rg1 to Be Proposed as Standard Reference Materials

  • Kim, Il-Woung;Hong, Hee-Do;Choi, Sang-Yoon;Hwang, Da-Hye;Her, Youl;Kim, Si-Kwan
    • Journal of Ginseng Research
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    • v.35 no.4
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    • pp.487-496
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    • 2011
  • Good manufacturing practice (GMP)-based quality control is an integral component of the common technical document, a formal documentation process for applying a marketing authorization holder to those countries where ginseng is classified as a medicine. In addition, authentication of the physico-chemical properties of ginsenoside reference materials, and qualitative and quantitative batch analytical data based on validated analytical procedures are prerequisites for certifying GMP. Therefore, the aim of this study was to propose an authentication process for isolated ginsenosides $Rb_1$ and $Rg_1$ as reference materials (RM) and for these compounds to be designated as RMs for ginseng preparations throughout the world. Ginsenoside $Rb_1$ and $Rg_1$ were isolated by Diaion HP-20 adsorption chromatography, silica gel flash chromatography, recrystallization, and preparative HPLC. HPLC fractions corresponding to those two ginsenosides were recrystallized in appropriate solvents for the analysis of physico-chemical properties. Documentation of the isolated ginsenosides was made according to the method proposed by Gaedcke and Steinhoff. The ginsenosides were subjected to analyses of their general characteristics, identification, purity, content quantitation, and mass balance tests. The isolated ginsenosides were proven to be a single compound when analyzed by three different HPLC systems. Also, the water content was found to be 0.940% for $Rb_1$ and 0.485% for $Rg_1$, meaning that the net mass balance for ginsenoside $Rb_1$ and $Rg_1$ were 99.060% and 99.515%, respectively. From these results, we could assess and propose a full spectrum of physicochemical properties for the ginsenosides $Rb_1$ and $Rg_1$ as standard reference materials for GMP-based quality control.

Relation of the Physico-chemical Properties of Forest Soil to Site Indices of Larix leptolepis Stands (산림 토양의 이화학적 성질과 낙엽송 임분의 지위지수와의 관계)

  • Park, Nam-Chang;Lee, Kwang-Soo;Park, Mun Sueb;Shin, Hyeon Chul;Jun, Kwon Seok;Jung, Su-Young
    • Journal of Korean Society of Forest Science
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    • v.97 no.6
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    • pp.589-596
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    • 2008
  • This study was carried out in order to estimate site indices in un-stocked land by the physico-chemical properties of forest soil and to investigate the distribution of the physico-chemical properties by soil horizons. In Larix leptolepis Gordon stand, 80 sites were selected respectively to A and B horizon in soil. About the analysis method of data there was used stepwise regression analysis. Soil pH and T.N. of the physico-chemical properties turned out to be positively related to the site index. However, O.M. and Avail. $P_2O_5$ in soil were found out negatively related. In the degree of contribution of the variables to site index by each one of the stands, the highly effective variables were Base Sat., C.E.C., Sand, Exch. $Ca^{{+}{+}}$, and Exch. $Mg^{{+}{+}}$ in A horizon, Exch. $Ca^{{+}{+}}$, Base Sat., T.N., Avail. $P_2O_5$, and Clay in B horizon, and Exch. $Ca^{{+}{+}}$ and Base Sat. in both of A and B horizon. In conclusion, these results will provide not only the important criteria for establishment of management forest plan in un-stocked land but also the useful guidance for selecting the suitable sites and trees.

A Study on Physico-Chemical Properties on Mixed Fuel Oil of Very Low Sulfur Fuel Oil-High Sulfur Fuel Oil (VLSFO-HSFO) (저유황-고유황 혼합연료유의 물리화학적 특성연구)

  • Song, In-Chul;Shin, Su-Hyun;Kim, Sae-Mi;Lee, Hee-Jin;Seo, Jeong-Mog
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.864-872
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    • 2020
  • In accordance with the sulfur regulations of the International Maritime Organization (IMO), very low sulfur fuel oil (VLSFO) shows various production-dependent physico-chemical properties. This study aims to use as basic data for oil spill response according to study of physico-chemical characteristics of VLSFO and mixed fuel oil of VLSFO-HSFO. The mixed fuel oil was prepared by mixing 25, 50, 75 mass% of HSFO with VLSFO containing 0.46 and 0.36 mass% of sulfur. The physico-chemical properties such as the kinematic viscosity, pour point and distribution of Saturates, Aromatics, Resins, and Asphaltenes (SARA) were studied in the laboratory. As mixed of 75 mass% of HSFO with high the kinematic viscosity and low pour point in VLSFO, the kinematic viscosity of the mixed fuel oil increased to 350.2 %, and VLSFO with pour point of 23℃ and -11℃ lowered or raised to -3℃ and -6℃ respectively. As HSFO was mixed in VLSFO with a small Asphaltenes distribution, the Saturates distribution decreased to 68.8% and Asphaltenes distribution increased to 1,417 % dramatically.

Property Enhancement of SiR-EPDM Blend Using Electron Beam Irradiation

  • Deepalaxmi, R.;Rajini, V.
    • Journal of Electrical Engineering and Technology
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    • v.9 no.3
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    • pp.984-990
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    • 2014
  • Polymers are the most commonly used di-electrics because of their reliability, availability, ease of fabrication and cost. The commercial and industrial demand for advanced polymeric materials which are capable of being used in harsh environment is need of the hour. The study of the effect of electron beam irradiation on polymeric materials is an area of rapidly increasing interest. This paper discusses the resultant beneficial effects of electron beam irradiation on the SiR-EPDM blend having 50:50 composition. The changes in mechanical and electrical properties of SiR-EPDM blend which are exposed to three different doses of electron beam radiation namely 5 Mrad, 15 Mrad and 25 Mrad are presented. The irradiated blends are analyzed for their electro-mechanical and physico chemical properties. The electrical changes induced by irradiation are investigated by arc resistance, surface resistivity and volume resistivity measurements as per ASTM standards. The mechanical changes are observed by the measurement of tensile strength and elongation at break. Physico chemical investigation has been done using the FTIR, in order to investigate the irradiation induced chemical changes.