• 한국수자원학회논문집
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• 제35권5호
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• pp.475-484
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• 2002

새만금 미세점착성 퇴적물의 침강특성을 퇴적물 자체의 물리ㆍ화학적 기본특성과 연계 해석하기 위하여, 퇴적물의 입경분포, 광물질 구성 및 유기물 함량 조사로 구성되는 새만금 퇴적물에 대한 물리ㆍ화학적 특성 조사가 수행되었다. 새만금 퇴적물의 물리ㆍ화학적 특성에 대한 분석 결과, 새만금 퇴적물은 평균입경(52$\mu\textrm{m}$)이 비교적 크고 유기물 함량(2%)이 매우 작으며, 점착력이 비교적 자은 석영이 주된 광물질 구성성분으로 점착력에 의한 침강효과 보다는 중력에 의한 침강효과가 더 큰 퇴적물인 것으로 밝혀졌다. 따라서 이러한 효과로 인하여, 새만금 퇴적물은 응집효과가 침강속도를 증가시키는 응집침강 영역에서 비교적 작은 침강속도를 가지며, 응집효과가 침강속도를 감소시키는 간섭침강 영역에서는 비교적 큰 침강속도를 갖는 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2897-2902
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• 2010

Seven fully optimized geometries of 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) dimers have been obtained with density functional theory (DFT) method at the B3LYP/$6-311++G^{**}$ level. The intermolecular interaction energy was calculated with zero point energy (ZPE) correction and basis set superposition error (BSSE) correction. The greatest corrected intermolecular interaction energy of the dimers is $-23.69\;kJ{\cdot}mol^{-1}$. Natural bond orbital (NBO) analysis is performed to reveal the origin of the interaction. Based on the vibrational analysis, the changes of thermodynamic properties from the monomers to dimer with the temperature ranging from 200.0 K to 800.0 K have been obtained using the statistical thermodynamic method. It was found that the hydrogen bonds dominantly contribute to the dimers, while the binding energies are not only determined by hydrogen bonding. The dimerization process can not occur spontaneously at given temperatures.

• 한국식품과학회지
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• 제26권6호
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• pp.683-689
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• 1994

With a view to utilizing effectively fish skin wastes from marine manufactory, a gelatin solution extracted from yellowfin sole skin was fractionated by precipitation with ethanol, and then the functional and physico-chemical properties for the fractionated gelatin were determined. Ethanol was added up to 50% of ethanol content to a gelatin solution extracted from yellowfin sole skin, then the mixture was left to stand at $0^{\circ}C$ for 12 hours. Finally, the precipitates were dried by hot-air ($40^{\circ}C$). The gel strength and melting point of a 10% gel of gelatin prepared from yellowfin sole skin by precipitation with ethanol has 322.4g and $23.3^{\circ}C$, respectively. The physico-chemical properties of the ethanol treated fish skin gelatin were superior to those of fish skin gelatin prepared without ethanol treatment. Besides, the functional properties of the ethanol treated gelatin were lower in solubility and higher in water holding capacity, oil binding capacity, emulsifying activity, emulsifying stability, foam expansion and foam stability than those of pork skin gelatin sold on market as well as gelatin prepared without ethanol treatment. It may be concluded, from these results, that the fish skin gelatin prepared by precipitation with ethanol can be effectively utilized as a human food by improving the functional properties.

• 한국식품조리과학회지
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• 제32권2호
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• pp.204-210
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• 2016

Purpose: This study analyzed and compared the physico-chemical and affective properties between mackerels cooked by an electric pan and under superheated steam. Methods: Mackerel were cooked by an electric pan ($95^{\circ}C$) for 10 min and mackerel cooked under superheated steam ($250^{\circ}C$) for 5 min to be internal temperatures of $75{\pm}5^{\circ}C$ and tests to measure proximate composition, color values, texture profiles, microorganism counts and sensory acceptance were performed. Results: The moisture contents were 60.30% and 73.81% in mackerels cooked by electric pan and under superheated steam, respectively. The rate of weight loss in mackerel cooked by electric pan was 39%, whereas it was 29% in mackerel cooked under superheated steam. Mackerel cooked under superheated steam exhibited more yellowness, higher springiness, cohesiveness, gumminess, chewiness, and resilience with more acceptable preferences (appearance, odor, taste, and texture) compared to the mackerel cooked by electric pan. Conclusion: The application of superheated steam technology to fish products could reduce the cooking time and nutritional loss. Also, it could produce highly preferred fish products compared to that prepared by conventional electric pan.

• 한국해양공학회지
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• 제19권4호
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• pp.42-48
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• 2005

The sediment of Shihwa Lake contains an abundant quantity of cohesive sediments. The transport processes of the cohesive sediments are complex and difficult to predict, quantitatively. The cohesive sediments are the primary reason for the pollution of the environment and water quality in the coastal region. In this study, a column test has been performed. In order to quantify the settling velocities of sediment from Shihwa Lake, an experiment was conducted using a specially designed 1.8m tall settling column. A series of settling tests and physico-chemical property tests on Shihwa Lake cohesive sediments has been conducted to investigate the correlation between settling properties and their physico-chemical properties, which are represented as grain size distribution, mineralogical composition, and percentage oj organic contents. Experimental results of physico-chemical property tests show that Shihwa Lake sediments are relatively large in average grain $size(74\mu m)$ contain very small organic $material(6\%)$, and are dominantly composed of Quarts, which has relatively low cohesion. Thus, Shihwa Lake sediments might be specified as those whose settling properties are more influenced by gravity than cohesion. It is concluded that the magnitude of settling velocities of muddy sediments can be quite different, regionally, and it implies that field or laboratory experiments for settling velocity measurement should be preceded over the numerical modeling of muddy sediment transport, in order to obtain the reliable prediction results for a given specific site.

• 한국해안·해양공학회논문집
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• 제24권3호
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• pp.203-209
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• 2012

본 연구에서는 최신의 유동측정기를 이용하여 고령토 및 세 종류의 도자기토 시료에 대해 머드유동층의 유동학적 특성, 즉 밀도에 따른 점성 및 항복응력의 변화특성이 정량적으로 산정되었다. 본 연구에서는 또한 이러한 머드유동층의 물리화학적 기본특성들이 각 시료별로 측정되었으며, 이 기본특성들과 유동학적 특성들 사이의 상관관계가 정성적으로 분석되었다. 본 연구결과에 따르면, 머드유동층은 일반적으로 의가소성 거동특성을 보이며, 그 점성 및 항복응력은 모두 밀도가 증가함에 따라 지수함수적으로 급격히 증가하나, 각 시료별로 이 값들은 정량적으로 큰 차이를 보이는 것으로 나타났다.

• Journal of Ginseng Research
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• 제35권4호
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• pp.487-496
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• 2011

Good manufacturing practice (GMP)-based quality control is an integral component of the common technical document, a formal documentation process for applying a marketing authorization holder to those countries where ginseng is classified as a medicine. In addition, authentication of the physico-chemical properties of ginsenoside reference materials, and qualitative and quantitative batch analytical data based on validated analytical procedures are prerequisites for certifying GMP. Therefore, the aim of this study was to propose an authentication process for isolated ginsenosides $Rb_1$ and $Rg_1$ as reference materials (RM) and for these compounds to be designated as RMs for ginseng preparations throughout the world. Ginsenoside $Rb_1$ and $Rg_1$ were isolated by Diaion HP-20 adsorption chromatography, silica gel flash chromatography, recrystallization, and preparative HPLC. HPLC fractions corresponding to those two ginsenosides were recrystallized in appropriate solvents for the analysis of physico-chemical properties. Documentation of the isolated ginsenosides was made according to the method proposed by Gaedcke and Steinhoff. The ginsenosides were subjected to analyses of their general characteristics, identification, purity, content quantitation, and mass balance tests. The isolated ginsenosides were proven to be a single compound when analyzed by three different HPLC systems. Also, the water content was found to be 0.940% for $Rb_1$ and 0.485% for $Rg_1$, meaning that the net mass balance for ginsenoside $Rb_1$ and $Rg_1$ were 99.060% and 99.515%, respectively. From these results, we could assess and propose a full spectrum of physicochemical properties for the ginsenosides $Rb_1$ and $Rg_1$ as standard reference materials for GMP-based quality control.

• 한국산림과학회지
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• 제97권6호
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• pp.589-596
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• 2008

우리나라 주요 수종인 낙엽송 임분의 80개 표준지를 대상으로 산림토양의 이화학적 성질 13개 요인에 의하여 지위지수를 추정함으로써 조림예정지, 수종갱신지 등의 미립목지에 대한 낙엽송 임분의 적지를 파악하고자 하였다. 단계별 회귀분석법에 의한 지위지수 추정 결과와 임목생장과 토양의 이화학적 성질과의 관계를 요약하면 다음과 같다. 토양의 이화학적 성질이 지위지수 추정식에 미치는 영향으로 토양산도 및 전질소 인자는 대체적으로 정의상관으로 나타났으며, 유기물 및 유효인산은 부의 관계로 나타났다. 지위지수 추정식에서 인자별 기여도를 분석하기 위하여 표준편회귀계수를 구하여 기여도가 높은 인자를 분석한 바, 낙엽송 임분 토양 A층에서는 염기포화도, 양이온 치환용량, 모래, 치환성 칼슘, 치환성 마그네슘 인자 순으로, 낙엽송 임분 토양 B층에서는 치환성 칼슘, 염기포화도, 전질소, 유효인산, 점토 인자 순으로 나타났다. 한편 낙엽송 임분에서 토양 인자별 A, B층에서 공통적으로 기여도가 높은 인자는 치환성 칼슘과 염기포화도로 주로 나타났다. 이러한 연구결과는 미립목지에서 낙엽송림의 적지를 판별하는데 그 활용가치 및 기대효과가 높을 것이라 사료된다.

• 해양환경안전학회지
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• 제26권7호
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• pp.864-872
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• 2020

국제해사기구(IMO)의 황함유량 규제에 따르는 저유황연료유는 생산 공정에 따라 다양한 물리화학적 특성을 가지게 된다. 본 연구는 저유황연료유 및 저유황-고유황 혼합연료유의 물리화학적 특성연구 결과를 해양오염 방제대응의 기초자료로 활용하고자 한다. 연구에 사용된 혼합연료유는 황함유량이 0.46 mass%인 저유황연료유와 0.36 mass%인 저유황연료유에 고유황연료유를 25, 50, 75 mass% 혼합하여 제조하였다. 이 혼합연료유에 대해 동점도, 유동점 및 Saturates, Aromatics, Resins, Asphaltenes(SARA)분포 등 물리화학적 특성에 대해 실험실 연구를 하였다. 동점도가 높고 유동점이 낮은 특징의 고유황연료유가 75 mass% 혼합함에 따라, 혼합연료유의 동점도는 350.2 %까지 증가 하였으며, 유동점이 23℃와 -11℃의 저유황연료유는 각각 -3℃ 및 -6℃까지 유동점이 내려가거나 올라갔다. Asphaltenes 분포가 적은 저유황연료유에 고유황연료유를 혼합함에 따라, Saturates분포는 68.8 %까지 감소하고, Asphaltenes분포는 1,417 %까지 크게 증가하였다.

• Journal of Electrical Engineering and Technology
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• 제9권3호
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• pp.984-990
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• 2014

Polymers are the most commonly used di-electrics because of their reliability, availability, ease of fabrication and cost. The commercial and industrial demand for advanced polymeric materials which are capable of being used in harsh environment is need of the hour. The study of the effect of electron beam irradiation on polymeric materials is an area of rapidly increasing interest. This paper discusses the resultant beneficial effects of electron beam irradiation on the SiR-EPDM blend having 50:50 composition. The changes in mechanical and electrical properties of SiR-EPDM blend which are exposed to three different doses of electron beam radiation namely 5 Mrad, 15 Mrad and 25 Mrad are presented. The irradiated blends are analyzed for their electro-mechanical and physico chemical properties. The electrical changes induced by irradiation are investigated by arc resistance, surface resistivity and volume resistivity measurements as per ASTM standards. The mechanical changes are observed by the measurement of tensile strength and elongation at break. Physico chemical investigation has been done using the FTIR, in order to investigate the irradiation induced chemical changes.