• Title/Summary/Keyword: polyethylene

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Characteristics of Asphalt Concrete Mixed with Polyethylene Aggregate (폐비닐 골재 혼합 아스콘의 성질)

  • Kim, Youngchin
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.12
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    • pp.5-11
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    • 2017
  • The 19 mm-sized aggregate was produced by melting vinyl waste (waste polyethylene film) generated from vinyl greenhouses in rural areas. It was mixed with As'cone at various weight ratios, and then insulation effect test, tension test after repeated freezing and thawing, ice pull-out strength test and field density test were conducted for the mixtures. These results demonstrated that as the mixing ratio of polyethylene aggregate increased, the insulation effect increased, due to the many pore spaces that existed in the polyethylene aggregate. After repeatedly freezing and thawing As'cone, the tensile strength significantly increased at 2.5% of the polyethylene aggregate content rather than 0% of polyethylene aggregate content but it also slightly decreased at 5% and 10% of polyethylene aggregate content in comparison to 2.5% of its polyethylene aggregate content. As'cone added with polyethylene aggregate by 2.5% resulted in lower ice pull-out strength than that of normal As'cone. As a result of the porosity test for the samples taken at the site, porosity of the As'cone, which added polyethylene aggregate, was smaller than that of the general As'cone.

Enhancement of Oxygen and Moisture Permeability with Illite-Containing Polyethylene Film

  • Seong, Dong Min;Lee, Hyesun;Chang, Jeong Ho
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.601-605
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    • 2019
  • This work reports the preparation of ceramic hybrid films with illite-polyethylene composites analyzed as a function of concentration of added illite in polyethylene. The enhancement of oxygen and water-vapor transmission rate of illite-polyethylene film was evaluated to determine its influence on the freshness in fruit packaging. Particle size of illite materials was controlled in the range of 1~10 ㎛ and then mixed with LDPE to form the masterbatch. Ceramic hybrid films were prepared through a blown film making process. To determine the dispersity and abundancy of illite materials in the polyethylene matrix, various characterizations of illite-PE hybrid masterbatch and films were performed using SEM, TGA, and FT-IR. The oxygen and water-vapor transmission rate of illite-polyethylene film was found to be two times higher than that of LDPE film.

Structure-property relationship of melt intercalated maleated polyethylene nanocomposites

  • Reddy, M.M.;Gupta, Rahul K.;Bhattacharya, S.N.;Parthasarathy, R.
    • Korea-Australia Rheology Journal
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    • v.19 no.3
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    • pp.133-139
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    • 2007
  • Low density polyethylene nanocomposites were prepared by melt intercalating maleic anhydride grafted polyethylene and montmorillonite clay. It has been found that maleic anhydride has promoted strong interactions between polyethylene and montmorillonite, leading to the homogeneous dispersion of clay layers. Rheological experiments revealed that prepared nanocomposites exhibited shear thinning behaviour. Polyethylene nanocomposites exhibited an increase in steady shear viscosities compared to virgin polyethylene owing to strong polymer clay interactions. The tensile strength of nanocomposites was improved but elongation at break decreased considerably. Also, barrier properties improved significantly with montmorillonite content.

On the Pyrolysis of Polymers IV. Pyrolysis of Polythylene and Polypropylene (高分子物質의 熱分解에 關한 硏究 (第4報) Polyethylene 및 Polypropylene의 熱分解에 關하여)

  • Chwa-Kyung Sung;Icksam Noh;Jung Yup Kim;Sung Bong Chang
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.122-127
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    • 1963
  • Pyrolysis fo polyethylene and polypropylene has been studied in order to clarify the mechanism of chain scission and effect of oxygen on degradation. Rate of weight decrease was measured under nitrogen and air atmosphere at constant temperature for the samples of high density polyethylene, low density polyethylene and isotactic polypropylene, and then gaseous hydrocarbons produced from pyrolysis were analysed by gas chromatography. Although there is little substantial difference between composition of hydrocarbon gases from pyrolysis of high density polyethylene and low density polyethylene except some difference in quantity of total gas produced, gas composition from polypropylene pyrolysis differs from that of polyethylene pyrolysis. Gases from pyrolysis under air contain much more unsaturated hydrocarbons than those from pyrolysis under inert gas.

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A Study on the Physical Properties of a Compound Using the Crosslinking of Vinylized-mesoporous Silica and Regenerated Polyethylene (비닐화 실란이 도입된 메조포러스 실리카와 재생 폴리에틸렌의 가교결합을 이용한 컴파운드의 물성 연구)

  • Tae-Yoon Kim;Hyun-Ho Park;Chang-Seop Lee
    • Journal of the Korean Chemical Society
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    • v.67 no.6
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    • pp.420-428
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    • 2023
  • Crosslinking was introduced into vinylized-mesoporous silica and recycled polyethylene. By introducing a vinyl group into the mesoporous silica, it becomes a material capable of inducing cross-linking with non-polar polyethylene. By synthesizing vinylized-mesoporous silica and inducing crosslinking with recycled polyethylene, a recycled polyethylene composite with improved physical properties than existing recycled polyethylene was synthesized. In addition, even when a small amount is added according to the grade of recycled polyethylene using vinylized-mesoporous silica, the crosslinking reaction proceeds and all physical properties are improved. Four types of vinylized-mesoporous silica were synthesized, and the shape, microstructure, and functional groups were analyzed by TEM, BET, FT-IR, and XRD. Using vinylized-mesoporous silica, three types of compounds were blended by crosslinking reaction with recycled polyethylene. In order to confirm the presence or absence of crosslinking, analysis was performed using XPS and FT-IR, and physical properties such as tensile strength, elongation, flexural strength, and flexural modulus were confirmed using a universal testing machine. As a result, by applying vinylized-mesoporous silica to recycled polyethylene in various grades, the weak physical properties of existing recycled polyethylene were overcome. By applying the vinylized-mesoporous silica, recycled polyethylene composite material that overcomes the weak physical properties to the normal polyethylene, it shows the optimal physical property index that can be used commercially. Therefore, it is expected that it can potentially increase the use of recycled polyethylene and recycle resources.

Prediction of Short-term Behavior of Buried Polyethylene Pipe (지중매설 폴리에틸렌 관의 단기거동 예측)

  • Park, Joonseok;Lee, Young-Geun;Kim, Sunhee;Park, Jung-Hwan;Kim, Eung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.907-914
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    • 2012
  • Flexible pipes take advantage of their ability to move, or deflect, under loads without structural damage. Common types of flexible pipes are manufactured from polyethylene (PE), polyvinyl chloride (PVC), steel, glass fiber reinforced thermosetting polymer plastic (GFRP), and aluminum. In this paper, we present the result of an investigation pertaining to the short-term behavior of buried polyethylene pipe. The mechanical properties of the polyethylene pipe produced in the domestic manufacturer are determined and the results are reported in this paper. In addition, vertical ring deflection is measured by the laboratory model test and the finite element analysis (FEA) is also conducted to simulate the short-term behavior of polyethylene pipe buried underground. Based on results from soil-pipe interaction finite element analyses of polyethylene pipe is used to predict the vertical ring deflection and maximum bending strain of polyethylene pipe.

FTIR study of gamma and electron irradiated high-density polyethylene for high dose measurements

  • Al-Ghamdi, Hanan;Farah, Khaled;Almuqrin, Aljawharah;Hosni, Faouzi
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.255-261
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    • 2022
  • A reliable and well-characterized dosimetry system which is traceable to the international measurement system, is the key element to quality assurance in radiation processing with cobalt-60 gamma rays, X-rays, and electron beam. This is specifically the case for health-regulated processes, such as the radiation sterilization of single use medical devices and food irradiation for preservation and disinfestation. Polyethylene is considered to possess a lot of interesting dosimetric characteristics. In this work, a detailed study has been performed to determine the dosimetric characteristics of a commercialized high-density polyethylene (HDPE) film using Fourier transformed infrared spectrometry (FTIR). Correlations have been established between the absorbed dose and radiation induced infrared absorption in polyethylene having a maximum at 965 cm-1 (transvinylene band) and 1716 cm-1 (ketone-carbonyl band). We have found that polyethylene dose-response is linear with dose for both bands up to1000 kGy. For transvinylene band, the dose-response is more sensitive if irradiations are made in helium. While, for ketone-carbonyl band, the dose-response is more sensitive when irradiations are carried out in air. The dose-rate effect has been found to be negligible when polyethylene samples are irradiated with electron beam high dose rates. The irradiated polyethylene is relatively stable for several weeks after irradiation.

Mechanical Properties on Poly Lactic Acid based Graft Copolymer with Polyethylene Glycol Acrylate (Polyethylene Glycol Acrylate를 이식 공중합 기반의 Poly Lactic Acid에 관한 기계적 특성)

  • Kim, Ki-Jun;Sung, Wan-Mo;Kim, Joo-Han;Jung, Hyung-Hak
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.643-649
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    • 2017
  • Biodegradable enzymes such as lipase and proteinase can hydrolyze not only fatty acid esters and triglycerides, but also aliphatic polyesters. We measured the biodegradability that biodegradable enzymes have an important role in the degradation of natural aliphatic poly material such as PLA, corn starch, and polyethylene glycol in the natural environment. However, we investigated on the biodegradability of PLA, PLA and Polyethylene acrylate blended, and PLAcoPolyethylene polymerized with PLA graft copolymer Polyethylene glycol acrylate. When prepared biodegradable polymers. the Mechanical properties of them were measured on Biodegradability, thermal properties, real time in-situ electrical monitoring of polymers resin. Therefore BOD and biodegradation of PLAcoPolyethylene was graft copolymerized with PLA and polyethylene acrylate were measured at a lower rate than the other samples.

Otoplasty with High Density Polyethylene Implant(MEDPOR®) (잠복이에서 고밀도 폴리에틸렌 삽입물(MEDPOR®)을 이용한 귀성형술)

  • Lee, Keun-Cheol;Kwon, Yong-Seok;Heo, Jung;Moon, Ju-Bong;Kim, Seok-Kwun
    • Archives of Plastic Surgery
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    • v.36 no.2
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    • pp.167-173
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    • 2009
  • Purpose: The key points of treatment of cryptotia are the elevation of invaginated ear helix and the correction of deformed cartilage. Prevention of stabilized cartilage contouring from returning to the previous state is also important. The authors carried otoplasty by modified Onizuka's method or Ohmori's method that conchal cartilage graft or high density polyethylene implant(MEDPOR$^{(R)}$) graft served as fixation after spreading posterior aspect of adhered antihelix and a splint for prevention of recurrence of cartilage deformities. The aim of this study is to reveal the availability of the high density polyethylene implant(MEDPOR$^{(R)}$) graft for the correction of cryptotia. Methods: We have repaired 17 cryptotic deformities using cartilage graft from cavum of concha(12 cases) or high density polyethylene implant(5 cases) for correction of deformed cartilage. We investigate the operative time, complications, and satisfaction of postoperative ear shape on both autogenous cartilage graft group and high density polyethylene implant graft group. Results: There was 1 case of reinvagination on autogenous cartilage graft group. Implant exposure was occurred on high density polyethylene implant graft group, as 1 case. These were statistically no differences between autogenous cartilage graft group and high density polyethylene implant graft group to the satisfaction of ear shape. Conclusion: High density polyethylene implant(MEDPOR$^{(R)}$) present an alternative to autogenous material as they allow of fibrovascular ingrowth, leading to stability of the implant and decreased infection rates. The correction of deformed cartilage by using the high density polyethylene implant(MEDPOR$^{(R)}$) is a good option for the treatment of cryptotia.

A Fundamental Study on the Waste Polyethylene Chips Mixed with Soil (폐비닐 골재 혼합토의 기본 성질에 관한 연구)

  • 김영진;김현민
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.03b
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    • pp.548-555
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    • 2000
  • It was investigated whether the waste polyethylene chips can be recycled as construction materials in geotechnical engineering field. The standard Proctor test, the hydraulic conductivity test, the large box direct shear test, the thermal conductivity test, the frost heaving test and the time domain reflectometry test were performed on weathered granite soil mixed with variable amount of the waste polyethylene chips. The experimental results showed that the hydraulic conductivity and the shear strength of weathered granite soil increase with increasing the amount of the waste polyethylene chips. On the other hand, the thermal conductivity, the amount of frost heaving and the unfrozen water contents of weathered granite soil decrease with increasing the amount of the waste polyethylene chips.

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