• Title/Summary/Keyword: polyethylene

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Physical and Rheological Properties of Thermoplasticized Crosslinked-Polyethylene Foam in Supercritical Methanol

  • Cho, Hang-Kyu;Hong, Soon-Man;Baek, Kyung-Yeol;Koo, Chong-Min;Lee, Hong-Shik;Lee, Youn-Woo
    • Macromolecular Research
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    • v.17 no.12
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    • pp.950-955
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    • 2009
  • The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

Evaluation of Jacket Compounds for Underground Distribution Power Cables (지중 배전케이블용 자켓 컴파운드의 특성평가)

  • 한재홍;송일근;김동명;이재봉;정창수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.687-694
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    • 2002
  • In order to replace the jacket material for URD power cables, the 6 kinds of polyethylene compounds were manufactured and evaluated. The characteristics of the compounds were investigated by water vapor transmission (WVT) test, thermal and mechanical test. In WVT test, all the polyethylene compounds showed the superior water resistance to conventional PVC. The molecular structure and density of polyethylene play an important role in WVT. Also, the polyethylene compounds showed the suitable characteristics in thermal and mechanical test. Especially, the linear polyethylene compounds showed the superior characteristics to LDPE ones. Due to the fillers in compounds, the abrasion resistance was decreased and the cut-through resistance was increased. From this study, it can be considered that the polyethylene compounds may be suitable to jacket material for URD power cables.

Mechanical Properties of Polyethylene Films Containing Hydroxypropylated Potato Starch (하이드록시프로필화 감자 전분을 함유한 Polyethylene 필름의 기계적 특성)

  • 김미라;이선자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.2
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    • pp.423-428
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    • 1999
  • Potato starches were hydroxypropylated with 2.5, 5.0, 7.5, and 10.0% propylene oxide(PO) to improve mechanical properties of starch polyethylene film. Starch polyethylene cast films were prepared that contained 5% or 10% of the hydroxypropylated potato starch. Mechanical properties of these films were measured and compared to those of the films containing native potato starch. DS(degree of substitution) increased proportionally as propylene oxide concentration increased. Relative crystallinity in X ray diffraction patterns was decreased and starch granule observed by scanning electron micro scopy was destroyed by severe hydroxypropylation. In color properties of films, b value was not significantly different in the films but 5% starch polyethylene films with 2.5 PO starch showed the lowest L and a value. Tensile strength and strain energy of the films except the film containing 10.0 PO starch were higher than those of the containing native starch.

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Characterization of Water Vapor Transmission & Dielectric Breakdown in Insulation Materials for Jacket Compound (자켓 컴팍운드용 절연재의 수증기투과 및 절연파괴 특성)

  • 송재주;한재홍;송일근;한용희;한병성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.52-56
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    • 2001
  • Experiments of 2 type on insulating compounds accomplished to change PVC using in URD(Underground) power cable jacketing. one was DB(Dielectric Breakdown) test on the pure base resins and the others were WVT(Water Vapor Transmission) test on the compounds which contained C/B(Carbon Black), anti-oxidant to base resin. a kind of specimens made by pressing to resin of pellet or lump form was HDPE(High Density Polyethylene), MDPE(Medium Density Polyehylene), LDPE(Low Density Polyethylene), LLDPE(Linear Low Density Polyethylene), PVC(Polyvinyl Chloride). As a results of AC DB and WVT test, we saw that strength of Insulation was HDPE> LLDPE = MDP E> LDPE and WVT ratio was HDPE

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The Stability of Chlorobutanol Solution in Polyethylene and Glycol-modified Polyethylene Terephthalate Containers (Polyethylene과 Glycol-modified Polyethylene Terephthalate 용기내에서의 Chlorobutanol용액의 안정성)

  • Min, Shin-Hong;Kwon, Jong-Won;Jheong, Gu-Choong
    • Journal of Pharmaceutical Investigation
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    • v.16 no.1
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    • pp.8-11
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    • 1986
  • There have been many difficulties in utilization of polyethylene (PE) container for volatile ingredients because of its high permeability. We selected glycol-modified polyethylene terephthalate (PETG) lately being used and evaluated the stability of 0.5% chlorobutanol solution for PETG. We used PE bottle, glass flask and rubber stoppered vial for comparison and assayed chlorobutanol contents of the samples stored at various temperatures for nine weeks by HPLC method. The results indicated that the stability of chlorobutanol in PETG container was almost similar to that in glass flask, and was superior to that in PE bottle and rubber stoppered vial.

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Effect of Polyethylene Glycol on Release of Heparin from Silicone Segment Devices (실리콘 segment device로부터의 헤파린 방출에 미치는 폴리에틸렌글리콜의 영향)

  • 김성호
    • YAKHAK HOEJI
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    • v.29 no.2
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    • pp.70-75
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    • 1985
  • The influence of polyethylene glycol derivatives on heparin release from cylindrical monolithic type silicone segment devices was examined in physical saline solution. This water-soluble carrier caused the devices to absorb the water in aqueous media. The release rate of heparin from the devices was increased as molecular weight of polyethylene glycol was increased. Water soluble carrier incorporated into silitone segment devices permits controlled release of heparin that otherwise would be released extremly slowly from the polymer. Heparin released from the silicone segment containing polyethylene glycol showed the first-order kinetics. Without changing the release-pattern, the release rate of heparin could be controlled by varing molecular weight of polyethylene glycol, the water-soluble carrier and depleting polyethylene glycol on the outlayer of devices. The mechanism of release probably showed the creation of pore or microdomine through the devices secondary to the swelling.

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C-and Fe-(Beewax.Polyethylene) PTC Thermistors (C- 및 Fe-(Beewax.Polyethylene) 정특성 감온소자)

  • Lee, Jong-Hyeon;Son, Byeong-Gi;Lee, Jong-Deok
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.4
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    • pp.6-11
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    • 1976
  • The carbon (the iron) -beewax.polyethylene thermistors have been prepared by heating the well ground mixture of carbon (iron), beewax and polyethylene at 16$0^{\circ}C$ for one hour and by cooling it under pressure of 12kgw/cm2. The resistivity for the former (the latter) increased from 102$\Omega$.cm (104$\Omega$.cw) to 1010$\Omega$.cm(1010$\Omega$.cm) as temperature changed from 2$0^{\circ}C$ to 9$0^{\circ}C$. The resistivity, 102$\Omega$.cm at room temperature for the former, was lower by order Q( two than that for the papostor made by the earlier reporter. The reproducibility, which has been an important Problem for this type of thermistors to be industrialized, was improved by introducing pressure in cooling procedure for both carbon and iron thermistors.

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Evaluation of Warm-Recycled Asphalt Mixtures using Polyethylene Wax-Based Additive (중온화 첨가제를 사용한 중온 재생 아스팔트 혼합물 평가)

  • Lee, Jin Wook;Lee, Moon Sup;Kim, Yong Joo;Cho, Dong Woo;Kwon, Soo Ahn
    • International Journal of Highway Engineering
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    • v.15 no.4
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    • pp.43-51
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    • 2013
  • PURPOSES : The main purposes of this study are to examine the influences of polyethylene wax-based WMA additive on the optimum asphalt content of warm-recycled asphalt mixture based on the Marshall mix design and to evaluate performance of warm-recycled asphalt mixture containing 30% RAP with polyethylene wax-based WMA additive. METHODS: Physical and rheological properties of the residual asphalt were evaluated in terms of penetration, softening point, ductility and performance grade (PG) in order to examine the effects of polyethylene wax-based WMA additive on the residual asphalt. Also, To evaluate performance characteristics of the warm-recycled asphalt mixtures using polyethylene wax-based WMA additive along with a control hot-recycled asphalt mixture, indirect tensile strength test, modified Lottman test, dynamic immersion test, wheel tracking test and dynamic modulus test were conduced in the laboratory. RESULTS : Based on the limited laboratory test results, polyethylene wax-based WMA additive is effective to decrease mixing and compacting temperatures without compromising the volumetric characteristics of warm-recycled asphalt mixtures compared to hot-recycled asphalt mixture. Also, it doesn't affect the optimum asphalt content on recycled-asphalt mixture. All performance test results show that the performance of warm-recycled asphalt mixture using polyethylene wax-based WMA additive is similar to that of a control hot-recycled asphalt mixture. CONCLUSIONS: Overall, the performance of warm-recycled asphalt mixture using polyethylene wax-based WMA additive is comparable to hot-recycled asphalt mixture.

Physical and Mechanical Properties of Composite Panel Manufactured from Wood Particle and Recycled Polyethylene (목재 파티클과 재생폴리에틸렌을 이용한 목질복합패널의 물리·기계적 성질)

  • Han, Tae-Hyung;Kwon, Jin-Heon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.4
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    • pp.340-348
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    • 2009
  • The recycled polyethylene was used for making wood-plastic composite panels. In this experiment, the sizes of wood particles used were 1/32", 1/4" and 1/2" in mesh number, and the contents of the recycled polyethylene were 10%, 30% and 50%. The physical and mechanical properties of the composite panels were investigated. At a given content of recycled polyethylene, the density of composite panel decreases with the increase of wood particle size. The thickness swelling and water adsorption decrease with the increase of recycled polyethylene, where significantly lower at 10%, compared with at 30%. In the water soaking experiment for 14 days, the dimensional stability of composite panel appeared good in the composite panel with recycled polyethylene content of 30% or higher. As the content of recycled polyethylene increases, the internal bonding strength and the modulus of rupture in bending strength increases. In SEM, the molten recycled polyethylene showed interlocking action through its penetration into tracheid openings including pits as well as binder between wood particles as the matrix material, thus increasing bonding strength and improving the physical and mechanical properties of composite panel.

Effect of Subatomospheric Pressure and Polyethylene Film Package on the Kacdugi Fermentation (깍두기의 숙성(熟成)에 미치는 감압(減壓) 및 Polyethylene Film 포장처리(包裝處理) 효과(效果))

  • Kim, Soon-Dong;Yoon, Soo-Hong;Kang, Meung-Su;Park, Nam-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.15 no.1
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    • pp.39-44
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    • 1986
  • Kacdugi fermented in the subatomospheric pressure(350mmHg) and polyethylene film package to improve the quality and to investigate the effect of fermentative control at $25^{\circ}C$. Brix degree, acidity, vitamin C content and number of total microbe and Lactobacilli was determined and also, the edible period of kacdugi was checked up by sensory assessment. The increasing rate of brix degree during kacdugi fermentation was high in the subatomospheric pressure, but decreased at the last period of fermentation as same tendency to the control, and it was preferably increased at the last period of fermentation in the polyethylene film package. However, the acidity was higher in the control than sbuatomospheric pressure but it was low in the polyethylene film package. Vitamin C content was high in the control at beginning and middle period of fermentation but high in sbuatomospheric pressure, and was low in the polyethylene film package at the last period of fermentation. The number of Lactobacilli was more in the subatomospheric pressure and polyethylene film package than the control, but it was suddenly incressed for the total microbe in the polyethylene film package at last period of fermentation. The edible periods of kacdugi by the sensory assessment of sour flavor, hardness and complex flavor was second days in the control. third days in the polyethylene film package, and fifth days in the subatomospheric pressure after soaking.

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