• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.147-152
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• 2001

The purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29%, polymer-cement ratios of 0, 5, 10, 15 and 20% are prepared, and tested for compressive strength, tensile strength, flexural strength, water permeability. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.402-408
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• 2002

The permeable polymer-modified concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, the purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29 ％, polymer-cement ratios of 0, 5, 10, 15 and 20 ％ are prepared, and tested for compressive strength, splitting tensile strength, flexural strength, water permeablility. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

• Korea-Australia Rheology Journal
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• v.21 no.3
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• pp.185-191
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• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• Journal of Industrial Technology
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• v.22 no.A
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• pp.161-168
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• 2002

Latex modified concrete is governed by both cement hydration and polymer film formation processes in its binder phase. Such the reactions are expected to improve the polymer-cement co-matrixes themselves and the bond between the cement hydrates and aggregates, and to improve the properties of hardened latex-modified concrete. The purpose of this study was to study the strength and chemical resistance of Rapid-setting latex modified concrete(RSLMC) with the main experimental variables such as latex content(0, 5, 10, 15, 20%) and water-cement ratio(36, 38, 40%) at latex content 15%. Water absorption test was earned out to estimate water permeability resistance. Chemical resistance test was carried out to measure the weight change and to observe the appearance of RSLMC immersion in hydrochloric acid, sulfuric acid, and calcium choloride.

• Journal of Korean Association for Spatial Structures
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• v.9 no.4
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• pp.61-72
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• 2009

As a trend of construction has become high-rise and larger, it is necessary to reduce the self-weight of structures and buildings. One of the most effective methods to reduce the self-weight of structures and buildings is to use the lightweight aggregate concrete. To complement the strength of the lightweight aggregate concrete, polymer was added to concrete's mixing. In this study, experiments to make the moderate mixing proportion of polymer modified lightweight concrete were performed. Also the hardened concrete tests were performed to investigate the physical characteristics of the polymer-modified lightweight aggregate concrete. As a result, the flexural strength was increased by a small quantity of SBR Latex. Based on the test results the estimating equation was proposed through the regression analysis.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.1011-1016
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• 2001

The purpose of this study is to find out the effect of polymer glass transition temperature on mechanical properties of polymer latex-modified mortars in comparison with ordinary cement mortar. The Polymer latex-modified mortars are prepared with 5, 10, 15 and 20% of polymer cement ratio respectively, and properties of modified mortars such as air content, compressive, flexural and tensile strengths are tested. The test results indicate that the types of polymer dispersion and the polymer-cement ratio are very important factors to characterize the properties of polymer-modified mortars, and also the glass transition temperature of polymer dispersions has an important effect on the performance of polymer-modified mortars. The modifying effects of two kinds of polymer dispersion, St/BA-1 and SBR, are evaluated.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.758-762
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• 1998

In preparing void latex particles by emulsion polymerization, the weight mean particle size of which is ranged $0.3{\mu}m{\sim}1.5{\mu}m$, reaction parameters were investigated in order to elucidate their effects on the size distribution and the solid content of emulsion polymer. Experimental results showed that the weight mean particle size of hydrophillic core polymer was reduced as the concentration of sodium dodecylbenzene sulfonate (SDS) increased. The size of void polymethyl-methacrylate-polystyrene composite latex particles became larger as the concentration of styrene monomer and the sodium persulfate increased. However, the size of void latex particles was reduced as the feeding rate of acrylic acid increased. The solid content of emulsion polymer was strongly dependent on the addition of stylene monomer. By increasing the concentration of styrene monomer the solid content of emulsion polymer increased linearly.

• Clean Technology
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• v.11 no.1
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• pp.41-50
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• 2005

In this study, semibatch emulsion copolymerization of n-BA as adhesive component and MMA as coagulant component were carried out for the stable acrylic polymer latex in aqueous phase for polymer cement using LE-type nonionic surfactant as environmental friendly surfactant. The stable polymer emulsion was obtained with the increases of chain length(n) of this surfactant. The effect on the amount of LE-50 as nonionic surfactant were showed that the concentration of polymer latex were increased by increasing the amount of LE-50, whereas the average particle size were decreased by increasing the amount. The addition of functional monomer in initial reactor charge showed a significant effect on the final polymer concentration and the latex particle size. The single polymerization of each n-BA or MMA showed a very low concentration of polymer latex and very big particle size due to coagulation. In the polymerization composed of mixed monomer with MMA and n-BA, the larger the ratio of MMA to n-BA in the copolymers, the greater the amount of coagulum produced. It was found that a stable copolymers were obtained in the range of 15-35 % of n-BA. Moreover, incorporation of some functional monomers in addition to of main monomers became more stable polymer latex. Through DSC and IR analysis, the final polymer latex was composed by MMA/n-BA/AA/AM with a single Tg depending on the reaction conditions. As a result, the conditions of this acrylic polymerization could also be effectively controlled to get the desired final products.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.789-794
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• 2012

For the purpose of development of the latex suitable for polymer cement mortar, experiments on the preparation of carboxylated styrene butadiene latex by the method of the two-step emulsion polymerization were performed. Methyl methacrylate, methacrylic acid and acrylic acid were selected as carboxylic co-monomer, styrene and butadiene as monomer, sodium dodecylbenzene sulfonate and sodium salt of lauryl sulfonate as anionic emulsifiers, and nonylphenoxy poly (ethyleneoxy) ethanol (n=10, 20, 40) as latex stabilizer. Potassium persulfate and sodium bisulfite were also used as redox initiator, and sodium monohydrogen phosphate and potassium carbonate as electrolytes. The effects of categories and concentration of carboxylic co-monomer, molecular weight control agent, crosslinking agent, and styrene/butadiene monomer ratio on the characteristics of latex were investigated. Polymerization recipes for preparation of polymer cement mortar could be proposed. The prepared latexes were tested for the physical properties such as compressive and flexural strength when latexes were mixed with cement mortar. The results showed that the latex could be adapted to polymer cement mortar. Also, it was recognized that the compressive and flexural strength were exhibited 25.4% and 45.3% respectively higher improvement than the quality standards at 28 days curing time.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.315-320
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• 2002

The effects of slag content and polymer-binder ratio on the strength properties of the polymer-modified concretes using ground granulated blast-furnace slag and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive, tensile and flexural strengths of the SBR-modified concretes using slag increase with increasing polymer-binder ratio and slag content, and maximized at a slag content of 40 ％. In particular, the SBR-modified concretes with a slag content of 40 ％ provide approximately two times higher tensile and flexural strengths than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.