• Title/Summary/Keyword: polymer particle

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A Study on the Conditioning with Polymer and the Particle Size Distribution of Intermittent Aerobic Digestion Sludge (간헐포기 소화 슬러지의 고분자 응집제에 의한 개량과 입도 분포 변화에 관한 연구)

  • Kim, Hee-Jun;Kim, Seong-Hong;Choi, Jae-Seong
    • Journal of Environmental Health Sciences
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    • v.30 no.3
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    • pp.253-258
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    • 2004
  • Synthetic organic polyelectrolytes can be used to condition sludges to enhance their dewaterability. Intermittent aerobic digestion is an useful digestion technology and has many advantages like neutral pH, low installation cost and easiness to operation. The objectives of this study were to investigate the dewaterability of intemittent aerobic digestion sludge and to find the relationship between dewaterability and particle size distribution change under the conditioning of intermittent aerobic digestion sludge by cationic polyelectrolyte. Digested sludge from intermittent aerobic digestion was used and cationic polyacrylamide polymer was added as a conditioner. CST(capillary suction time), TTF(time-to-filtration) were tested as a dewaterability index and the number of particle distribution was analyzed using particle size analyzer. The results indicate that cationic polyelectrolytes is useful to enhance dewaterability of intermittent aerobic digestion sludge. Mean particle diameter was increased as polymer dosage increased and its value was reached up to 100 mm on the condition of optimal cationic polymer dosage. CST and TTF are well correlated with mean particle diameter when the weighting order is 1.7. By the optimal conditioning with cationic polymer, particles in the filtrate are also reduced significantly and this means that conditioning is helpful to main stream by reducing SS loading from return flow.

Effect of Anionic Polymer on Particle Size Distribution in PAC Coagulation Process for Phosphorus Removal (PAC를 이용한 인제거 공정에서 음이온계 고분자 첨가가 입도 분포에 미치는 영향)

  • Kim, Sunghong;Lee, Dongwoo;Kim, Donghan;Kim, Dooil
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.170-175
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    • 2013
  • Achieving very low phosphorus levels in treated wastewater will require the installation of additional treatment. Phosphorus removal experiments by chemical coagulation were carried out for the effluent of wastewater treatment plant in this study. TP (total phosphorus) or phosphate were highly related to the addition of PAC (poly aluminium chloride) which is one of the inorganic coagulants. But, organic polymer did not significantly affect the phosphorus removal efficiency. Polymer affected the flocculation of particle especially particle matter less than 10 micrometer so, the number of micro particles was decreased by polymer dose. Chlorination would not affect on chemical coagulation process and TP and turbidity could be effectively removed by the co-addition of PAC and polymer.

Effect of Particle Sizes of Polymer Binders for Pigment Inks on Touch of Fabrics (안료 잉크용 바인더의 입자 크기가 직물의 태에 미치는 영향)

  • Park, Seongmin;Han, Minwoo;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.32 no.4
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    • pp.226-231
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    • 2020
  • This study investigated effect of particle sizes of polymer binders for digital textile printing(DTP) pigment inks on touch of fabrics. The polymer binders were synthesized via miniemulsion polymerization of methyl methacrylate(MMA), butyl acrylate(BA), N-ethylolacrylamide(NEA) and methacrylic acid(MAA). The prepared binders were applied to black pigment inks and those black pigment inks were used to dye cotton fabrics. Then, color strength, rubbing fastness, stiffness, surface and bending properties of the dyed fabrics were investigated. Depending on the particle size of the polymer binder used, color strength, friction fastness, stiffness, surface and bending properties change. Generally, the larger the particle size of the polymer binder, the softer properties.

Decreasing Particle Size of (+)-Dihydromyricetin Using Hydrophilic Polymer in Fractional Precipitation (분별침전에서 친수성 고분자 물질을 이용한 (+)-dihydromyricetin의 입자크기 감소)

  • Ji, Seong Bin;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.370-375
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    • 2018
  • In this study, we have applied fractional precipitation with hydrophilic polymer in order to decrease the particle size of the (+)-dihydromyricetin from plant materials. When compared with the case where no hydrophilic polymer was employed, the addition of hydrophilic polymer in fractional precipitation resulted in a considerable decrease in the size of the (+)-dihydromyricetin precipitate. Among the polymers used, HPMC 2910 was the most effective for inhibition of precipitate growth. A polymer concentration of 0.1% (w/v) yielded the smallest particle size. The particle size was reduced by ~40% compared to control. In addition, the precipitate size was inversely correlated with the absolute value of the zeta potential of the suspension with polymer.

Preparation and Swelling Properties of Poly(potassium acrylate-co-acrylamide) Superabsorbent Particles (폴리(아크릴산 포타슘-co-아크릴아마이드) 고흡수성 입자의 제조 및 팽윤 특성)

  • 손오건;심상준;이동현;이영관;김지홍;김덕준
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.18-23
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    • 2004
  • Superabsorbent poly(potassium acrylate-co-acrylamide)s were synthesized in particle form using inverse suspension polymerization technique. Mean diameter of the prepared polymer particles decreased from 300 to 50 $\mu\textrm{m}$ with increasing surfactant concentration. The dynamic and equilibrium swelling behaviors during water absorption and drying process were investigated by weight measurement. The swelling ratio of polymer particles in water changed according to not only polymer crosslinking density, but particle size, saline concentration of aqueous medium, and copolymer compositions. Water sorption amount was increased with decreasing particle size, crosslinking agent concentration, and ion concentration in bulk solution. Being different from the water sorption process, the drying process was not significantly affected by particle size, polymer composition, or crosslinking amount.

Decreasing Particle Size of Paclitaxel Using Polymer in Fractional Precipitation Process (고분자물질을 이용한 분별침전 공정에서 파클리탁셀의 입자크기 감소)

  • Kim, Min Jae;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.278-283
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    • 2016
  • In this study, we have for the first time applied fractional precipitation with hydrophilic polymer in order to decrease the particle size of the anticancer agent paclitaxel from plant cell cultures. When compared with the case where no hydrophilic polymer was employed, the addition of hydrophilic polymer in fractional precipitation resulted in a decrease in the size of the paclitaxel precipitate. Among the polymers used, HPMC 2910 was the most effective for inhibition of precipitate growth. A polymer concentration of 0.2% (w/v) obtained the smallest particle size. The particle size was reduced by ~35% compared to control. In addition, the precipitate size was inversely correlated with the absolute value of the zeta potential.

A Study on Dispersion Copolymerization of Styrene/n-Butylmethacrylate and Alumina (스티렌/노말 부틸 메타크릴레이트와 알루미나의 분산 공중합에 관한 연구)

  • Bang, Hyun-Su;Cho, Ur-Ryong
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.549-554
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    • 2008
  • In order to synthesize polymer particle containing inorganic material, styrene and n-butylmethacrylate were copolymerized with alumina by dispersion polymerization. The weight ratio of styrene to n-butylmethacrylate was 3 : 1. A poly(N-vinyl pyrrolidon) was added as stabilizer. 2,2'-AzobisCisobutyronitrile) and 3-methacryloxypropyl trimethoxysilane were used as initiator and coupling agent, respectively. The weight ratio of 70 : 30 of isopropanol to distilled water was used as dispersion medium. According to the TEM measurement, we could confirm that alumina was dispersed into the polymer particle. The increase 'of concentration of alumina resulted in enhancement of particle size, but decreased its distribution. By the XRD method, it was found that the increase of alumina concentration showed the increase of intensity in peak and the increased 2$\theta$ value. From the TGA measurement, the increase of alumina concentration caused high heat resistance of the polymer. With respect to the type of initiator, the longer half life of initiator, the smaller particle size. We also found that the increase of particle stabilizer concentration made the decreased of particle size due to the accelerated generation of polymer particle in the early stage of reaction.

Effect of Reaction Conditions on the Preparation of Nano-sized Ni Powders inside a Nonionic Polymer

  • Kim, Tea-Wan;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.462-463
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    • 2006
  • Monodispersed and nano-sized Ni powders were synthesized from aqueous nickel sulfate hexahydrate $(NiSO_4{\cdot}6H_2O)$ inside nonionic polymer network by using wet chemical reduction process. The sucrose was used as a nonionic polymer network source. The effect of reaction conditions such as the amount of sucrose and a various reaction temperature, nickel sulfate hexahydrate molarity. The influence of a nonionic polymer network on the particle size of the prepared Ni powders was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and particle size analysis (PSA). The results showed that the obtained Ni powders were strong by dependent of the reaction conditions. In particular, the Ni powders prepared inside a nonionic polymer network had smooth spherical shape and narrow particle size distribution.

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A Comparative Study on the Conditioning and Dewaterability of Digested Sludge from Intermittent Aerobic Digestion (간헐포기 소화슬러지의 개량과 탈수 특성에 관한 비교 연구)

  • Kim, Seong Hong;Choi, Young Gyun;Chung, Tai Hak
    • Journal of Korean Society on Water Environment
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    • v.20 no.4
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    • pp.370-375
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    • 2004
  • Synthetic organic polyelectrolytes can be used to condition sludges to enhance their dewaterability. When conditioning biological sludges, the charge on the polymer has a significant impact on the effectiveness of the polymer as a conditioner. The objectives of this investigation were to determine the most effective type and dosage of polymer for conditioning digested sludge prior to dewatering, and to investigate the relationship between dewaterability and particle size. 3 types of digested sludge were used under the different digestion processes like anaerobic digestion, aerobic digestion and intermittent aerobic digestion. CST(capillary suction time), TTF(time-to-filter) and SRF(specific resistance to filtration) were tested as a dewaterability index and the number of particle distribution was analyzed using particle size analyzer. The results indicate that cationic polymer appears to be required for effective conditioning of these 3 types digested sludge and the optimal polymer dosage is about 0.6% of SS. CST and TTF are well correlated with mean particle diameter of which the dimension order is 1.7.

Effect of particle size on graphite reinforced conductive polymer composites (입자의 크기에 따른 흑연 보강 전도성 고분자 복합재료의 특성 연구)

  • Heo, S.I.;Yun, J.C.;Oh, K.S.;Han, K.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.257-260
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    • 2005
  • Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. The ratio and particle size of graphite powder were varied to investigate electrical conductivity of cured composites. In this study, graphite reinforced conductive polymer composites with high filler loadings(>66wt.%) were manufactured to accomplish high electrical conductivity. With increasing the loading ratio of graphite powder, the electrical conductivity and flexural strength increased. However. above 80wt.% filler loadings, flexural strength decreased due to lack of resin. Regardless of graphite particle size, electrical conductivity wasn’t varied. On the other hand, with decreasing particle size, flexural strength increased due to high specific surface area.

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