• Title/Summary/Keyword: polymer particle

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Regeneration of Intervertebral Disc Using Poly(lactic-co-glycolic acid) Scaffolds Included Demineralized Bone Particle In Vivo (In vivo 상에서 탈미네랄화된 골분이 함유된 PLGA 지지체를 이용한 추간판 디스크 재생)

  • Jang, Ji Eun;Kim, Hye Yoon;Song, Jeong Eun;Lee, Dongwon;Kwon, Soon Yong;Chung, Jin Wha;Khang, Gilson
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.669-676
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    • 2013
  • Demineralized bone particle (DBP) is a biomaterial used widely in the field of tissue engineering. In this study, in order to study the effect of DBP/poly(lactic-co-glycolic acid) (PLGA) scaffold on disc regeneration in vivo environment, we prepared the porous DBP/PLGA hybrid scaffold. Disc defect was induced by removing the nucleus pulposus tissue after incision the annulus fibrosus tissue in half and scaffolds were transplanted. After 1, 2 and 3 months later, the extracted discs were confirmed by collagen synthesis and glycosaminoglycan (sGAG). We conducted histology (H&E, Safranin-O, Alcian blue, Type I Collagen, Type II Collagen). From the results, it was confirmed that collagen and sGAG content were high in DBP/PLGA scaffold, and the regeneration of intervertebral disc was possible.

Dielectric and Piezoelectric of Ceramic-Polymer Composite with Ceramic Particle Size (세라믹 분말 크기가 압전 세라믹-폴리머 복합체의 유전 및 압전 특성에 미치는 영향)

  • 이형규;김호기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.63-65
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    • 1989
  • Piezoelectric BaTiO$_3$-polymer composite were investigated for dielectric and piezoelectric properties with the barium titanate active particle size. Under the condition of the same density and ceramic volume ratio of composite, the dielectric and piezoelectric constant of composite are increasing as the ceramic particle size in composite are increasing. The surface layer model was quoted to explain these phenomena in our system and experimentally confirmed. The connectivity parameter of modified cube model of composite was calculated from the dielectric constant variation as their particle size. The connectivity parameter X and Y were 77.8% and 98.9% respectively. It means that the barium titanate particle distribution in composite nearly approach to the parallel mode. It was experimentally confirmed that the surface layer has low dielectric and nonferroelectric properties. Dielectric constant and thickness of surface layer were calculated from the equivalent circuit of composite.

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Study on Model of Emulsion Polymeration 2. Kinetics of Termonomer Emulsion Polymerization (유화중합의 모델연구 2. 삼모노머유화중합의 동력학)

  • Park, S.B.;SE, C.S.
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.300-305
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    • 1998
  • Kinetics of termonomer emulsion polymerization during interval II (i.e, after completion of latex particle formation) were studied through pseudo-homopolymerization (PHP) method. Extended Smith-Ewart equation and equation of instantaneous polymer composition are respectively reduced to the corresponding equation for homopolymerization by defining average rate constants. Average number of radicals per particle and instantaneous polymer compositions were respectively predicted by varying termonomer composition within latex particles for systems containing no more than one growing radical per particle. Styrene-Methyl methacrylate-Acrylonitrile (SMA) system was used for model calculation.

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Dispersion Polymerization of Acrylamide in Methanol/Water Media

  • Lee, Ki-Chang;Lee, Seung-Eun;Song, Bong-Keun
    • Macromolecular Research
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    • v.10 no.3
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    • pp.140-144
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    • 2002
  • Dispersion polymerization of acrylamide was carried out in the media of methyl alcohol/$H_2O$ mixtures using hydroxypropyl cellulose and ammonium persulfate as steric stabilizer and initiator, respectively. The effects of concentrations of initiator and steric stabilizer, amount of monomer, polymerization temperature, methyl alcohol/$H_2O$ ratio, and purification of monomer and nitrogen purge on the particle size of the latices and molecular weight of the polymers were investigated. The average particle diameter increased with increasing concentration of initiator, water content in methyl alcohol/$H_2O$ media, and polymerization temperature, but decreased with monomer and stabilizer concentrations. The viscosity average molecular weight increased with increasing concentrations of monomer, steric stabilizer, and water content in dispersion media, but decreased with initiator concentration and polymerization temperature. The PAM polymers prepared with the purified monomer and the nitrogen purging before the reaction showed the highest molecular weight.

Mechanical Properties of Denture Base Resin through Controlling of Particle Size and Molecular Weight of PMMA (폴리(메틸 메타아크릴레이트) 입자 크기 및 분자량 제어에 따른 의치상 재료로서의 기계적 물성 변화)

  • 양경모;정동준
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.493-501
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    • 2003
  • Poly(methyl methacrylate) (PMMA) particles, denture base resin, were synthesized by suspension polymerization through control of polymerization conditions (stabilizer concentration, co-monomer concentration, and the agitation speed) and evaluated changes in molecular weight and particle size. We also investigated their mechanical properties of compression-molded samples which were from synthesized polymer powder mixed with methyl methacrylate (MMA) solution. under the condition of volumetric ratio as 2:1(PMMA powder and MMA solution). The results shows that the mechanical properties were mainly affected by particle size over 100 ${\mu}$m (in particle size) and by molecular weight under 100 ${\mu}$m (in particle size). From these results, we concluded that the most appropriate particle size of PMMA powder for heat-cured denture base resins is around 100 ${\mu}$m. and its molecular weight is around 300000 (M$\sub$n/).

DI water Nozzle Design for Effective Removal of the Particles Generated during Wafer-sawing (Wafer-Sawing시 발생하는 particle을 효과적으로 제거하기 위한 DI water 노즐의 최적 설계)

  • 김병수;이기준;이성재
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.53-60
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    • 2003
  • CCD(Charge-Coupled Device) wafers, with a layer of micro lenses on top, usually are not passivated with dielectric films. Micro lenses, in general, are made of polymer material, which usually has a large affinity for particles generated in the various chip fabrication processes, most notably the wafer sawing for chip-dicing. The particles deposited on the micro lens layer either seriously attenuate or deflect the incoming light and often lead to CCD failure. In this study we introduce new type of saws which would significantly reduce the particle-related problems found in conventional type of saws. In the new saws, the positions and diverging angles of side and center nozzles have been optimized so as to flush the particles effectively. In addition, an independent nozzle is added for the sole purpose of flushing the generated particles. The test results show that, with the new saws. the ratio of the particle-related CCD chip failures has been dropped drastically from 9.1% to 0.63%.

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Study on the Preparation of Alginic Acid-PMMA Graft Polymer and the Surface Modification of Montmorillonite with the Graft Polymer (Alginic Acid-PMMA Graft Polymer의 합성 및 이를 Coupling제로 한 Montmorillonite 표면의 개질화에 관한 연구)

  • 손차호;김경환;박천욱
    • Textile Coloration and Finishing
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    • v.4 no.4
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    • pp.81-89
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    • 1992
  • Graft polymers of alginic acid-PMMA, different in composition and Mv of branched PMMA, were prepared by emulsion graft polymerization at various MMA concentrations. In aqueous dispersion solution, the adsorption of graft polymer on the montmorillonite was carried out to modify the surface property of powder, and the adsorption of PMMA in organic solvents (acetone, benzene) on the modified surface of powder were observed. The results obtained were as follows. 1. In emulsion graft polymerization of MMA on the sodium alginate in aqueous solution, SA conversion, MMA conversion and % grafting were increased with increasing MMA concentration where as graft efficiency was decreased. 2. The adsorption amount of graft polymer was increased with the elevation of temperature and the increased of dispersion concentration and with the increase of branched PMMA composition of graft polymer. 3. In organic solvent, the adsorption of PMMA on the surface modified particle was proceeded by the orientation along the stretched branched PMMA of adsorbed graft polymer which is in radial direction to the particle surface. 4. The adsorbed amount of PMMA was increased as the temperature and concentration of PMMA solution, the branching of adsorbed graft polymer and the solvency of solvent were increased.

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