• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1997년도 추계총회 및 학술발표회 논문집
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• pp.126-130
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• 1997

A series of Thermoplastic polyurethane elastomers was prepared via a two-step polymerization process. The NCO/OH feed ratio of polyurethane synthesized in this study was varied from 1 to 1.3. Studies have been made on the effects of chemical and physical cross-linkina, and the properties of thermoplastic polyurethane elastomers based on isophorone diisocyanate (IPDI)/1,4-butanediol (BD)/poly(propylene glycol) (PPG, MW:2000), isophorone diisocyanate (IPDI)/BD /poly(oxytetramethylene) glycol (PTMG, MW:2000) was compared. These materials were characterized using FTIR spectrometer, dynamic mechanical thermal analyzer, and tensile retraction tester. PTMG based polyurethane elastomers showed higher elasomeric behavior than PPG based polyurethane elastomers at the same NCO/OH ratio. This feature has been connected with the specific nature of the polyols. The permanent set(%) was decreased with increasing maximum elongation from 50% to 300%.

• Elastomers and Composites
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• 제54권1호
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• pp.30-34
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• 2019

Four different diisocyanates (IPDI; isophorone diisocyanate, HDI; hexamethylene diisocyanate, HMDI; dicyclohexylmethane-4,4'-diisocyanate, and XDI; m-xylylene diisocyanate) were used to prepare polyurethane gel-coats, and the weatherabilities, physical properties, and surface characteristics of the gel-coats were investigated with respect to the chemical structure of the diisocyanates. The weathering test results indicated that all of the diisocyanates used in this study were suitable for use in the preparation of the polyurethane gel-coat. However, the set-to-touch times and physical properties of the polyurethane gel-coat indicated that the cycloaliphatic diisocyanate (IPDI and HMDI) were ideal for the preparation of polyurethane gel-coats.

• 패션비즈니스
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• 제8권1호
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• pp.141-155
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• 2004

Chitosan, the natural biodegradable polymer derived from chitin by de- acetylation, has been widely applied to the textile finishing processes for excellent anti-microbial characteristic and handle improvement of fabric. The purpose of this study is to investigate the change of handle when cotton fabric is treated with chitosan-polyurethane mixed solution. The viscosity values of chitosan solutions were 8cps and 50cps, and the wet-pick-up% was maintained at 90%. In case of mixing with water soluble polyurethane, the mixture ratio of chitosan and polyurethane was settled on the solid content ratio of 1:0, 1:0.5, 1:1, 1:2. Also the change of physical properties by neutralization in NaOH solution was studied. The results can be summarized up as follows : 1. Extensibility(EM) and tensile energy(WT) of cotton fabric treated with chitosan are decreased, but bending rigidity(B) is remarkably increased. With the addition of polyurethane, the decrease of EM and WT is weakened and the increase of B is weakened. The case of neutralization is similar to the case of polyurethane addition. 2. By treating fabric with chitosan, FUKURAMI(Fullness and softness) is decreased, but KOSHI(Stiffness), SHARI(Crispness), HARI(Anti-drape Stiff ness) are increased. With the addition of polyurethane, the decrease of FUKURAMI is diminished and the increase of KOSHI, SHARI, HARI are diminished. 3. As the viscosity of chitosan solution increased, the air permeability value increased. The addition of polyurethane decreased the air permeability.

• Korean Chemical Engineering Research
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• 제50권3호
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• pp.403-409
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• 2012

Poly (carbonate diol), isophrone diisocyanate와 dimethylol propionic acid로 부터 제조된 polyurethane prepolymer의 말단 NCO기를 aniline으로 capping시켜 aniline terminated waterborne polyurethane dispersion (ATWPUD)을 합성하였다. 이 ATWPUD와 물에 분산되어 있는 multi-walled carbon nanotube (MWCNT)를 혼합시켜 전도성 코팅 용액을 제조한 후, 이것을 polycarbonate 기재 위에 도포하여 코팅 막을 형성하였다. ATWPUD와 MWCNT를 혼합하여 얻어진 코팅 막의 표면저항 값은 $10^{7.6}{\sim}10^{7.7}{\Omega}/cm^2$로 순수한 waterborne polyurethane dispersion (WPUD)과 MWCNT의 혼합물로부터 제조된 코팅 막의 $10^{10.9}{\Omega}/cm^2$ 보다 우수한 전기전도도를 나타내었다. 또한 ATWPUD에 첨가되는 MWCNT의 양이 증가될수록 코팅 막의 전기전도도는 증가하였지만 연필경도 및 부착력은 감소되었다.

• Elastomers and Composites
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• 제47권4호
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• pp.318-328
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• 2012

본 연구에서는 blocked isocyanate와 하이브리드 기술을 이용해서 1액 경화형 폴리우레탄 탄성체를 제조하였다. 1액 경화형 하이브리드 폴리우레탄의 제조를 위해서 hydroxyl group을 포함하는 실리카 하이브리드를 합성하고 입자크기, 형태 및 탄성체 내의 하이브리드 입자분포를 확인하였다. 또한, 열해리특성, 기계적 물성, 성형특성을 조사하였다. 1액 경화형 폴리우레탄 탄성체의 열해리 특성을 평가한 결과 온도가 높을수록, 열처리 시간이 길어질수록 blocking된 isocyanate의 해리가 더 잘 진행되었다. 합성된 실리카 하이브리드는 직경이 23~27 nm이고 구형이었으며 하이브리드 폴리우레탄의 단면을 FE-SEM과 EDS를 사용해서 분석한 결과 하이브리드 입자가 폴리우레탄 분자구조 내에 잘 분산되어있는 것을 확인하였다. 하이브리드 폴리우레탄의 경우에는 하이브리드를 포함하지 않는 폴리우레탄 탄성체에 비해 기계적물성, 내마모성 및 열적특성이 향상되었으며 가소제를 사용하는 경우에는 물성의 변화가 거의 없는 것으로 확인되었다.

• Elastomers and Composites
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• 제39권3호
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• pp.209-216
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• 2004

Polyurethane prepolymer에 2-hydroxyethylmethacrylate(HEMA)와 acrylamide(AA)를 반응 시켜 두 가지 타입의 polyurethane-acrylate 중합체들을 합성하였다. 합성된 중합체들을 소량의 benzyl chloride와 증류수를 이용하여 수용성 중합체인 폴리우레탄-아크릴레이트계 양이온성 보류향상제를 제조하였다. 이렇게 두 가지 형태로 제조된 중합체에 대하여 보류향상제로서 중요한 특성인 보류, 탈수특성 및 비압축강도 등의 물성들을 다양한 방법으로 고찰하였다. 합성된 폴리우레탄-아크릴레이트계 양이온성 보류향상제는 rpm에 따라 큰 변화 없이 70% 내외의 보류도를 유지하였으며, 합성한 보류향상제의 첨가로 인한 화학적 산소 요구량(COD)의 경우는 미첨가시의 COD보다 상당히 낮은 값이 관찰되었다. 탈수량의 경우 무처리한 펄프보다 보류향상제의 처가 시에 탈수성이 향상되었으며, 보류향상제의 첨가 시 비압축강도가 소량 증가되었고, PU-HEMA가 PU-AA보다 우수한 강도를 나타내었다.

• 한국산업융합학회 논문집
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• 제26권6_3호
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• pp.1289-1295
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• 2023

Polyurethane foam insulation required for storing and transporting cryogenic liquefied gas is already widely used as a thermal insulation material for commercial LNG carriers and onshore due to its stable price and high insulation performance. These polyurethane foams are reported to have different mechanical performance depending on the density, and the density parameter is determined depending on the amount of the blowing agent. In this study, density-dependent polyurethane foam was fabricated by adjusting the amount of blowing agent. The mechanical properties of polyurethane foam were analyzed in the room temperature and cryogenic temperature range of -163℃ at 1.5 mm/min, which is a quasi-static load range, and the cells were observed through microstructure analysis. The characteristics of linear elasticity, plateau, and densification, which are quasi-static mechanical behaviors of polyurethane foam, were shown, and the correlation between density and mechanical properties in a cryogenic environment was confirmed. The correlation between mechanical behavior and cell size was also analyzed through SEM morphology analysis. Polyurethane foam with a density of 180 kg/m³ had a density about twice as high as that of a polyurethane foam with a density of 96 kg/m³, but yield strength was about 51% higher and cell size was about 9.5% smaller.

• 한국지반공학회지:지반
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• 제12권3호
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• pp.99-108
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• 1996

본 연구에서는 케미칼 그라우팅웅의 폴리우레탄계 2성분 주입약액 및 그의 반응고결물인 발포 고결체의 물리적, 화학적 성질에 관하여 조사하였다. 이들의 성질을 좌우하는 요소들을 규명키 위한 실험결과, 폴리우레탄계 주입약액 및 그의 고결생성물의 물리적, 화학적 거동은 토질의 상태 즉, 온도, 함수비 및 흙의 밀도 등과 같은 주입대상지발의 조건에 의해 크게 영향받는 것을 알 수 있었다. 또한, 폴리우레탄계 약액그라우팅의 지반보강효과 및 차수효과를 검증키 위해 현재 건설중인 지하철등에서의 터널 굴착시의 폴리우레탄계 약액주입 시공예를 중심으로 그 효과를 조사하였다.

• 대한안전경영과학회지
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• 제15권4호
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• pp.185-196
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• 2013

Polyurethane is an elastomer polymer, which is flexible, tough and resistant. This material is widely used various fields such as automobile, aeroplane, textiles, construction industries. Currently there exists more than 1,000 manufacturing companies in Korea that are closely related to Polyurethane. In spite of a number of Polyurethane manufacturing companies, there are little attention in academia as well as industries to study the safety and manufacturing process improvement on Polyurethane. In this paper, we consider a case study for the Polyurethane manufacturer to improve productivity by using safety management and manufacturing process reengineering. After careful analysis, we derive three enhancements to increasing the safety and productivity for the target company. Especially, we achieve about 16% productivity improvement in roller manufacturing process by replacing manual stirring job with automated mixing machine.

• 한국염색가공학회지
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• 제29권1호
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• pp.25-36
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• 2017

This study worked on the synthesis of waterborne polyurethane/epoxy hybrid resins containing aminosilane compound to replace conventional phenol resins used for a coating material for loudspeaker dampers, which are not harmful to human being. Waterborne polyurethane resins were synthesized from two diisocyanate of 4,4'-diphenylethane diisocyanate and toluene diisocyanate, two polyols of polyester polyols(PEP), polycarbonatediol(PCD), including and anionic center of dimethylol butanoic acid, a chain extenders of ethylenediamine(EDA), and a neutral agent of triethylamine. Synthesized polyurethane resins and commercially available bisphenol A type waterborne epoxy resin were blended in weight ratios of 80:20 to prepare polyurethane/epoxy hybrid resins. The synthesized waterborne polyurethane/epoxy hybrid resins were reacted with aminosilane compound to improve mechanical properties. Aminosilane-treated polyurethane /epoxy hybrid resins showed better mechanical properties.