• Advances in concrete construction
• /
• v.5 no.3
• /
• pp.289-301
• /
• 2017

The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.

• Advances in concrete construction
• /
• v.11 no.3
• /
• pp.207-217
• /
• 2021

This study relates to a production of Quaternary Cement Concrete (QCC) prepared by using Micro Silica (MS), Marble Dust (MD) and Rice Husk Ash (RHA), followed by an investigation towards fresh and hardened properties of blended concrete. A total of 39 mixes were cast by incorporating different percentages of MS (6%, 7% and 8%), MD (5%, 10% and 15%) and RHA (5%, 10%, 15% and 20%) as partial replacement of Ordinary Portland Cement. The workability of fresh concrete was maintained in the range of 100±25 mm by adding 0.7% of Super Plasticizer in the mix. Optimum mechanical strength was observed at combination of 8% MS+5% MD+10% RHA. Marble dust replacement from 10 to 15% and Rice husk ash replacements from 15 to 20% depicted a substantial reduction in compressive strength at all ages. Durability parameter with respect to water absorption at 28 days shows an increasing trend as the percentage of blending increases.

• Advances in concrete construction
• /
• v.12 no.5
• /
• pp.429-437
• /
• 2021

In the era of building engineering the intensification of Self Compacting Concrete (SCC) is world-shattering magnetism. It has lot of rewards over ordinary concrete i.e., enrichment in production, cutback in manpower, brilliant retort to load and vibration along with improved durability. In the present study, the mechanical strength of CM-2 (SCC containing 10% of rice husk ash (RHA) as cement replacement and 600 grams of glass fibers per cubic meter) was investigated at various dosages of cement replacement by fly ash (FA) and GGBS. A total of 17 SCC mixtures including two control SCC mixtures (CM-1 and CM-2) were developed for investigating fresh and hardened properties in which, ten ternary cementitious blends of SCC by blending OPC+RHA+FA, OPC+RHA+GGBS and five quaternary cementitious blends (OPC+RHA+FA+GGBS) at different replacement dosages of FA and GGBS were developed with reference to CM-2. For constant water-cement ratio (0.42) and dosage of SP (2.5%), the addition of glass fibers (600 grams/m³) in CM-1 i.e., CM-2 shows lower workability but higher mechanical strength. While fly ash based ternary blends (OPC+RHA+FA) show better workability but lower mechanical strength as FA content increases in comparison to GGBS based ternary blends (OPC+RHA+GGBS) on increasing GGBS content. The pattern for mixtures appeared to exhibit higher workablity as that of the concentration of FA+GGBS rises in quaternary blends (OPC+RHA+FA+GGBS). A decrease in compressive strength at 7-days was noticed with an increase in the percentage of FA and GGBS as cement replacement in ternary and quaternary blended mixtures with respect to CM-2. The highest 28-days compressive strength (41.92 MPa) was observed for mix QM-3 and the lowest (33.18 MPa) for mix QM-5.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.10 no.4
• /
• pp.506-513
• /
• 2022

In this paper, as part of a study for carbon neutrality, the quality properties of quaternary component high-fluidity concrete, which significantly replaced up to 80 % of the cement usage by using three industrial by-products, were evaluated. As a result of the evaluation, even if a large amount of industrial by-products were replaced by more than 80 % of the amount of cement used, it was possible to obtain quality that satisfies the target performance in all concrete mix. In the case of flow properties, mechanical properties, and durability, compared to the existing standard concrete mix, the performance tends to decrease, but it is judged that the performance above the required performance level can be satisfied. When considered comprehensively, the quaternary component High-Fluidity Concrete with a large mixing amount of fine powder of blast furnace slag showed relatively good performance.

• Advances in concrete construction
• /
• v.9 no.4
• /
• pp.387-395
• /
• 2020

This study has been carried out in two-phases to develop Fiber Reinforced Self-Compacting Concrete (FRSCC) performance. In the first phase, the composition of the quaternary composite binder compromised CEM I 42.5N (58-70%), Rice Husk Ash (25-37%), quartz sand (2.5-7.5%) and limestone crushing waste (2.5-7.5%) were optimized. And in the second phase, the effect of two fiber types (steel brass-plated and basalt) was investigated on the SCC optimized with the optimum CB as disperse reinforcement at 6 different ratios of 1, 1.2, 1.4, 1.6, 1.8, and 2.0% by weight of mix for each type. In this study, the theoretical principles of the synthesis of self-compacting dispersion-reinforced concrete have been developed which consists of optimizing structure-formation processes through the use of a mineral modifier, together with ground crushed cement in a vario-planetary mill to a specific surface area of 550 m2 / kg. The amorphous silica in the modifier composition intensifies the binding of calcium hydroxide formed during the hydration of C3S, helps reduce the basicity of the cement-composite, while reducing the growth of portlandite crystals. Limestone particles contribute to the formation of calcium hydrocarbonate and, together with fine ground quartz sand; act as microfiller, clogging the pores of the cement. Furthermore, the results revealed that the effect of fiber addition improves the mechanical properties of FRSCC. It was found that the steel fiber performed better than basalt fiber on tensile strength and modulus of elasticity; however, both fibers have the same performance on the first crack strength and sample destruction of FRSCC. It also illustrates that there will be an optimum percentage of fiber addition.

• Structural Engineering and Mechanics
• /
• v.86 no.4
• /
• pp.431-441
• /
• 2023

The aim of this paper is to present a new sustainable ternary and quaternary binder by partially replacing ordinary Portland cement (OPC) with different percentages of supplementary cementitious materials. The motivation is to reduce our dependency on OPC to reduce CO₂ emission and carbon foot print. As the main substitute for the OPC, siliceous fly ash was used. Moreover, silica fume and nanosilica were also used. During examinations the main mechanical parameters of concrete composites, i.e., compressive strength (f_cm) and splitting tensile strength (f_ctm) were assed. The microstructure of these materials was also analysed. It was found that the concrete incorporating pozzolanic materials is characterized by a well-developed structure and has high values of mechanical parameters. The quaternary concrete containing: 80% OPC, 5% FA, 10% SF, and 5% nS have shown the best results in terms of good strength parameters as well as the most favourable microstructure, whereas the worst mechanical parameters with microstructure containing microcracks at phase interfaces were characterized by concrete with more content of FA additive in the concrete mix, i.e., 15%. Nevertheless, all concretes made on quaternary binders had better parameters than the reference one. It can be stated that sustainable concrete incorporating pozzolanic materials could be good substitute of ordinary concretes.

• Journal of Ocean Engineering and Technology
• /
• v.26 no.3
• /
• pp.26-32
• /
• 2012

Recently, concrete using multicomponent blended cement has been required to increase the freeze-thaw and sulfate resistances of concrete structures exposed to a marine environment. Thus, the purpose of this study was to propose the use of concrete containing multicomponent blended cement as one of the alternatives for concrete structures exposed to a marine environment. For this purpose, batches of concrete containing ordinary portland cement (OPC), binary blended cement (OPC-G, G: ground granulated blast slag), ternary blended cement (OPC-GF, F: fly ash), and quaternary blended cement (OPC-GFM, M: mata-kaolin) were made using a water-binder ratio of 50%. Then, the durability levels, including thesulfate and freeze-thaw resistances, were estimated for concrete samples containing OPC, OPC-G, OPC-GF, and OPC-GFM. It was observed from the tests that the durability levels of the concrete samples containing OPC-G and OPC-GF were found to be much better than that of the concrete containing OPC. The optimum mixing proportions were a40% replacement ratio of ground granulated blast slag for the binary blended cement and a30% replacement ratio of ground granulated blast slag and 10% fly ash for the ternary blended cement.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.3 no.3
• /
• pp.268-276
• /
• 2015

In this study, $CO_2$ reduction type quaternary component high fluidity concrete was produced with more than 80% reduction in cement quantity to increase the use of industrial byproducts and enhance construction performance, thereby reducing $CO_2$ emissions. Furthermore, the quality properties, and $CO_2$ reduction performance of this concrete were evaluated. As a result of the quality evaluation of quaternary component blended high fluidity concrete with $CO_2$ reduction, the target performance could be achieved with a 80% or more reduction of cement quantity by mixing a large amount of industrial byproducts. The required performance level was obtained even though the flow, dynamic, and durability characteristics decreased a little compared to conventional mix. In addition, to analyze the $CO_2$ reduction performance of quaternary component blended high fluidity concrete with $CO_2$ reduction, the life cycle assessment (LCA) of the concrete was performed and the results showed that compared to the conventional mix, the carbon emissions decreased by 62.2% and the manufacturing cost by 24.5%.

• Advances in nano research
• /
• v.16 no.3
• /
• pp.217-229
• /
• 2024

This paper presents results of visual analysis of cracks formation and propagation of concretes made of quaternary binders (QBC). A composition of the two most commonly used mineral additives, i.e. fly ash (FA) and silica fume (SF) in combination with nanosilica (nS), has been proposed as a partial replacement of the cement. The principal objective of the present study is to achieve information about the effect of simultaneous incorporation of three pozzolans as partial replacement to the OPC on the fracture processes in concretes made from quaternary binders (QBC). The modern and precise non-contact measurement method (NCMM) via digital image correlation (DIC) technique was used, during the studies. In the course of experiments it was established that the substitution of OPC with three pozzolans including the nanoadditive in FA+SF+nS FA+SF+nS combination causes a clear change of brittleness and behavior during fractures in QBCs. It was found that the shape of cracks in unmodified concrete was quasi-linear. Substitution of the binder by SCMs resulted in a slight heterogeneity of the structure of the QBC, including only SF and nS, and clear heterogeneity for concretes with the FA additive. In addition, as content of FA rises throughout each of QBC series, material becomes more ductile and shows less brittle failure. It means that an increase in the FA content in the concrete mix causes a significant change in fracture process in this composite in comparison to concrete with the addition of silica modifiers only.

• Computers and Concrete
• /
• v.13 no.5
• /
• pp.621-632
• /
• 2014

This paper is aimed at adapting Artificial Neural Networks (ANN) to predict the compressive strength of High Performance Concrete (HPC) containing binary and quaternary blends. The investigations were done on 23 HPC mixes, and specimens were cast and tested after 7, 28 and 56 days curing. The obtained experimental datas of 7, 28 and 56 days are trained using ANN which consists of eight input parameters like cement, metakaolin, blast furnace slag and fly ash, fine aggregate, coarse aggregate, superplasticizer and water binder ratio. The corresponding output parameters are 7, 28 and 56 days compressive strengths. The predicted values obtained using ANN show a good correlation between the Experimental data. The performance of the 8-9-3-3 architecture was better than other architectures. It concluded that ANN tool is convenient and time saving for predicting compressive strength at different ages.