• Title/Summary/Keyword: reactive processing

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Reactive Synthesis of ZrB2-based Ultra High Temperature Ceramics

  • Liu, Hai-Tao;Zhang, Guo-Jun
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.308-317
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    • 2012
  • Reactive processing, such as reactive hot pressing (RHP) and reactive spark plasma sintering (R-SPS), is effective densification method to prepare $ZrB_2$-based ultra high temperature ceramics (UHTCs). The present paper reviewed some typical reactive processing of $ZrB_2$-based UHTCs. All the reactions from the starting materials in the reactive processing are thermodynamically favorable, which generate enough energy and driving force for the densification of the final products under a relatively low temperature. Besides, compared with non-reactive processing, anisotropic $ZrB_2$ grains, such as $ZrB_2$ platelets, can only be obtained in the reactive processing, resulting in an improvement of the mechanical properties.

Hydrogenations of Butadiene Rubber and Natural Rubber by Reactive Processing

  • Suchiva, K.;Boonkerd, K.
    • Elastomers and Composites
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    • v.34 no.4
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    • pp.332-340
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    • 1999
  • Hydrogenations of BR and NR performed by a noncatalytic method using p-toluenesulphonylhydrazide were carried out by reactive processing. The experimental procedures for carrying out the reaction were established. Two steps comprising premixing of the rubber with TSH followed by hydrogenation in compression mould were proved to be suitable. The percentages of hydrogenation attained by reactive processing were higher than those of the reaction carried out in solution at the same [TSH]/[C=C] ratio, reaction temperature and time. In-creasing the reaction temperature and reaction time resulted in increases of the percentage of hydrogenation. For BR, the maximum percentage of hydrogenation obtained was 36% at [TSH]/[C=C]=1/1.5. For NR, the highest percentage of hydrogenation was 34% at [TSH]/[C=C]=1/1.5. Cis-trans isomerisation was also observed to occur during hydrogenation of both BR and NR. Thermal stabilities of the hydrogenated BR and NR were shown to improve over those or the unhydrogenated counterparts.

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A Study on a Reactive Power Control using Digital Filtering (디지털 필터링을 이용한 무효전력 제어에 관한 연구)

  • 우천희;강신준;이덕규;우광방;이성환
    • Journal of Institute of Control, Robotics and Systems
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    • v.4 no.4
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    • pp.517-524
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    • 1998
  • This paper discusses the development of a reactive power controller using digital signal processing. Digital Signal Processing is the technique of using digital devices to Process continuous signals or data, often in real-time. And DSP algorithms are associated with a discrete time interval between input samples. When one designs a digital filter, one can use a Laplace transform to determine the continuous time frequency response. The corresponding discrete time transform is called Z transform and depends upon discrete samples of the input spaced equally in time. The objectives of this paper are to minimize real power losses and improve the power factor of a given system. Also, the implementation of a direct-form non recursive filter on the TMS320C31 has been described. The application of this microprocessor-based controller using DSP on test system reveals its numerous advantages. Performance and features of the controller for the reactive power control are analyzed.

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Dyeing and Crosslinking of Chitosan Fibers with $\alpha$-Bromoacrylamide Reactive Dyes ($\alpha$-Bromoacrylamide계 반응염료에 의한 키토산 섬유의 염색 및 가교)

  • 박병기;박봉수;정용식;이근완
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.26-33
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    • 2002
  • Dyeing properties and crosslinking effect of bifunctional reactive dyes on chitosan fiber were investigated to improve the stability of chitosan fiber against the mild acidic solution and the wet processing. Chitosan fibers were crosslinked with epichlorohydrin for comparing purpose, and dyed with C. I. Reactive Red 194, C. I. Reactive Blue 50, and the reactive dye having two $\alpha$-bromoacrylamide groups at various concentrations. The initial dyeing rates of reactive dyes are rapid and chitosan fibers absorb the relatively large amount of dyes. The chitosan fibers dyed with these dyes show the low degree of swelling and the low solubility in 1 % acetic acid solution and also represent the higher thermal stability The reactive dye with two $\alpha$-bromoacrylamide groups shows higher crosslinking effect than other dyes.

Progress in research and development for REBCO coated conductors by reactive co-evaporation

  • Oh, S.S.;Kim, H.S.;Ha, H.S.;Ko, R.K.;Ha, D.W.;Lee, H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.4
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    • pp.1-5
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    • 2013
  • This paper reviews recent progress in research and development (R&D) of reactive co-evaporation for high performance REBCO coated conductors in Korea. Two types of reactive co-evaporation methods were developed for the deposition of SmBCO and GdBCO superconducting layers respectively on the IBAD (Ion Beam Assisted Deposition)-MgO template in the Korean coated conductor project. Batch type reactive co-evaporation equipment and its processing were developed for SmBCO coated conductors at Korea Electrotechnology Research Institute (KERI) in conjunction with the Korea Advanced Institute of Science and Technology (KAIST), and a very high critical current exceeding 1,000 A/cm at 77 K in the self field was achieved through the optimization of deposition parameters. Reel-to-reel type reactive co-evaporation processing with a high conversion rate was also developed, while long length GdBCO coated conductors have been routinely produced by SuNAM Co. The minimum critical current of 422 A/cm-w at 77 K in self field was confirmed for 1 km-long GdBCO tape.

Hybrid Message Robot Architecture (하이브리드 메시지 로봇 아키텍처)

  • Lee Hyoung-Gu
    • Proceedings of the Korea Information Processing Society Conference
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    • 2006.05a
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    • pp.1463-1466
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    • 2006
  • 이동형 로봇을 위한 아키텍처가 제안된다. 제안되는 로봇 아키텍처는 하이브리드 deliberative/reactive 타입이다. 아키텍처는 세 층으로 구성되는데 deliberation 층, 태스크 실행 층, reactive 층이다. 태스크 실행 층에 공용 메시지 박스를 두어서 세 층간의 메시지 교환 용도로 사용한다. 시스템의 구성 모듈은 서로 독립적으로 작동하고 다른 모듈과의 메시지 교환은 메시지 박스를 통해서 이루어지도록 하여 시스템의 확장성과 유연성이 확보된다.

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Crosslinking Characteristics of High Density Polyethylene by Reactive Melt Processing (반응 용융 가공에 의한 고밀도 폴리에틸렌의 가교 특성 연구)

  • Lee Jong Rok;Lee Dong Gun;Hong Soon Man;Kang Ho-Jong
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.385-391
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    • 2005
  • Reactive melt processing has been carried out to investigate crosslinking characteristics of high density polyethylene OTDPE) with dicummyl peroxide (DCP) and perbutyle peroxide (PBP). The increase of torque in the internal mixer indicated that the crosslinking in HDPE has been occurred by peroxides. As a result, the substantial decrease of density, melting temperature, and melt enthalpy were found while the melt viscosity increased in partially crosslinked HDPE. In the mechanical properties of partially crosslinked HDPE, the increase of maximum strength and the decrease in elongation at break were clearly noticed and these were more pronounced when PBP was applied as a crosslinking agent. It seems that the maximum strength was obtained with reactive processing temperature at $150^{circ}C$, however, the mixing time did not affect to the strength of partially crosslinked HDPE.

Polypropylene Reactive Nanocomposites with Functional Nanoclays

  • Phandee, Atinuch;Magaraphan, Rathanawan;Nithitanakul, Manit;Manuspiya, Hathaikarn
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.280-280
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    • 2006
  • Na-bentonite (local clay mineral) and Na-montmorillonite were treated with quaternary alkylammonium cations. The effect of the molecular structure and functional groups of the surfactants on the organoclays was investigated by X-ray diffraction (XRD). For the preparation of nanocomposites, organoclays were melt-blended with polypropylene in a twin screw extruder and $Surlyn^{(R)$. ionomer was used as a reactive compatibilizer. The clay dispersions in the composites were investigated by X-ray diffraction (XRD). XRD spectra showed no peak at low angle indicated that the silicate clay layer has a nearly exfoliated dispersion in the polymer matrix. Thermal and mechanical properties of nanocomposites were higher than those of PP.

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Processing of Polymer-derived Microcellular Ceramics Containing Reactive Fillers

  • Kim, Young-Wook;Jang, Doo-Hee;Eom, Jung-Hye;Song, In-Hyuck;Kim, Hai-Doo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.101-102
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    • 2006
  • Processing techniques for producing microcellular silicon carbide, mullite, and cordierite ceramics have been developed by a reaction method that incorporates a polysiloxane and reactive fillers. The techniques developed in this study offer substantial flexibility for producing microcellular ceramics whereby cell size, cell density, degree of interconnectivity, composition, and porosity can all be effectively controlled. It is demonstrated that the adjustment of filler composition enables the possibility of tailoring the composition and properties of the microcellular ceramics. The present results suggest that the proposed novel processing techniques are suitable for the manufacture of microcellular ceramics with high morphological uniformity.

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Remediation of contaminated soil by the coupled technique of electrokinetic method and permeable reactive method (동전기정화 및 투수성반응 복합기술에 의한 오염지반의 복원)

  • Chung, Ha-Ik;Lee, Myung-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.348-351
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    • 2006
  • This paper presents preliminary laboratory investigations on the electrokinetic (EK) remediation coupled with permeable reactive barrier (PRB) system. Atomizing slag was adopted as a PRB reactive material for remediation of groundwater contaminated with inorganic and/or organic substances. A series of laboratory experiments were performed with variable conditions such as (i) type of contaminant, (ii) applied electric field strength, (iii) processing time, and (iv) the application of PRB system. From the preliminary investigations, the coupled technology of EK with PRB system would be effective to remediate contaminated grounds without the extraction of pollutants from subsurface due to the reactions between the reactive materials and contaminants.

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