• Title/Summary/Keyword: residual oxygen

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Impact of Residual Extractives in Kraft Pulps on Brightness and Color

  • Shin, Soo-Jeong;Sung, Yong-Joo;Park, Jong-Moon;Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.5
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    • pp.20-25
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    • 2009
  • Residual extractives had a noticeable impact on the brightness of unbleached hardwood kraft pulps (trembling aspen). The brightness-impacting extractives were effectively removed by oxygen delignification. In addition, oxygen delignification was more effective in removing chromophores in hardwood unbleached kraft pulps than in those of softwood (loblolly pine). The residual extractives in unbleached hardwood kraft pulps also affected the pulp color, primarily redness and the L value. These redness-related extractives in unbleached hardwood kraft pulps were also effectively removed by oxygen delignification. There were no significant color differences between untreated and solvent-extracted oxygen-delignified aspen kraft pulps. The residual extractives in unbleached and oxygen-delignified softwood (loblolly pine) kraft pulps did not have a significant impact on either brightness or pulp color.

Effect of Oxygen Addition on Residual Stress Formation of Cubic Boron Nitride Thin Films (입방정 질화붕소 박막의 잔류응력 형성에 미치는 산소 첨가 효과)

  • Jang, Hee-Yeon;Park, Jong-Keuk;Lee, Wook-Seong;Baik, Young-Joon;Lim, Dae-Soon;Jeong, Jeung-Hyun
    • Journal of the Korean institute of surface engineering
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    • v.40 no.2
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    • pp.91-97
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    • 2007
  • In this study we investigated the oxygen effect on the nucleation and its residual stress during unbalanced magnetron sputtering. Up to 0.5% in oxygen flow rate, cubic phase (c-BN) was dominated with extremely small fraction of Hexagonal phase (h-BN) of increasing trend with oxygen concentration, whereas hexagonal phase is dominated beyond 0.75% flow rate. Interestingly, the residual stress in cubic-phase-dominated films was substantially reduced with small amount of oxygen (${\sim}0.5%$) down to a low value comparable to the h-BN case. This may be because oxygen atoms break B-N $sp^3$ bonds and make B-O bonds more favorably, increasing $sp^2$ bonds preference, as revealed by FTIR and NEXAFS. It was confirmed by experimental facts that the threshold bias voltage for nucleation and growth of cubic phase were increased from -55 V to -70 V and from -50 V to -60 V respectively. The reduction of residual stress in O-added c-BN films is seemingly resulting from the microstructure of the films. The oxygen tends to increase slightly the amount of h-BN phase in the grain boundary of c-BN and the soft h-BN phase of 3D network including surrounding nano grains of cubic phase may relax the residual stress of cubic phase.

A Study on the strength improvement in weldment by the impact loading (충격하중에 의한 용접구조물의 강도 증가에 관한 연구)

  • 이천수
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1998.10a
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    • pp.121-124
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    • 1998
  • It is well known that during the oxygen cutting residual thermal stresses are produced in weldment. Surface compressive residual stress is one of reasons for improvement on fatigue durability. To reduce the residual stress and improve the fatigue strength applied the impact loading in oxygen cutting frame. After applying the impact loading, redistribution of residual stress was measured by cutting method and tested fatigue tests.

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Effect of Residual Impurity on Magnetic Properties of the Permalloy Soft Magnet by Powder Injection Molding (분말사출성형으로 제조된 퍼말로이 연자성체에서 잔류 불순물이 자기특성에 미치는 영향)

  • 정원용;최준환;정우상
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.291-296
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    • 2000
  • The manufacturing method of permalloy soft magnet with the Ni contents of 46.6 and 47.2 wt% was investigated by powder injection molding technology. The magnetic properties of permalloy were greatly affected on the residual carbon and oxygen content of the sintered magnet. Solvent extraction and thermal debinding process to minimize the residual carbon content in sintered magnet were developed by controlling the debinding atmosphere. The residual carbon content depends on the debinding condition of the binder system for powder injection molding and the residual oxygen content on the sintering atmosphere. The sintered magnet produced by powder injection molding process had a 50 ppm. residual carbon, 150 ppm. residual oxygen. The coercivity and maximum relative permeability of permalloy soft magnet were 0.46 Oe and 14,600 respectively.

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Impact of Lignin Determination Method on Oxygen Delignification Chemistry

  • Shin Soo-Jeong;Lai Yuan-Zong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.50-55
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    • 2005
  • In previous report, we investigated the impact of hexeneuronic acid and some residual extractiveson lignin determination. These non-lignin components severely interfered lignin content determination which also affect on the oxygen delignification comparison between aspen and pine unbleached kraft pulps. Very different pattern was observed whether based on uncorrected conventional kappa number or based on corrected kappa number in oxygen delignification comparison. Lower kappa number aspen pulps showed poor response to oxygen delignification when kappa number was used as lignin determination method but better response with using the acid lignin method. Phenolic hydroxyl group in kraft pulps were also compared based on uncorrected or corrected kappa numberfor lignin content. Based on uncorrected kappa number, lower kappa number oxygen-delignified pulps had lower phenolic hydroxyl group. However, lower kappa number oxygen-delignified pulps showed much higher phenolic hydroxyl group based on the corrected lignin content. For accurate comparison for residual lignin properties from different pulps, lignin determination should be corrected from non-lignin components contribution to lignin.

A Study on the Recycling Method of Vehicle Mat Residual Product (자동차 내장매트 부산물의 재활용방안에 관한 연구)

  • Jang, Seong-Ho;Park, Gil-Pyeong;Park, Jin-Sik
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1199-1203
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    • 2006
  • This paper analyzes the separation efficiency of vehicles mat residual product, and caloric value, element analysis and heavy metal of separated PE & PVC mat residual product. A results of separation efficiency, fiber fraction of PE & PVC mat residual product was analyzed 71.9% and 18.6%, respectively. Caloric value of PE & PVC mat residual product was analyzed 3,894kca1/kg and 10,203kca1/kg, respectively. A results of element analysis, main component of PVC mat were carbon(33.2%) and oxygen(21.0%), and main component of PE mat fiber were carbon(75.4), hydrogen(11.3%) and oxygen(9.1%). Lead and cadmium concentration of PVC powder was detected 98.9mg/kg and 19.8mg/kg, but Lead and cadmium concentration of fiber was detected 15.7mg/kg and 6.1mg/kg.

A Study on the strength improvement in weldment by the impact loading (충격하중에 의한 용접구조물의 강도 증가에 관한 연구)

  • 양영수
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.3
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    • pp.76-82
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    • 2000
  • It is well known that during the oxygen cutting process residual thermal stresses are produced in weldment. The local non-uniform heating and subsequent cooling which takes place during any welding process causes complex thermal strains and stresses to finally lead to residual stresses exceed to the yield stress. High tensile stresses combined with applied structural load in the region near the welded joint can given rise to distortion brittle fracture change of the fatigue strength and stress corrosion cracking. The appropriate treatment of the welded component which reduces the peak of he welding residual stresses is believed to lower risk of the fracture during the service of the structure. In this study the impact loading in oxygen cutting frame was applied to reduce the residual stress. After applying the impact loading redistribution of resid-ual stress was measured by cutting method and the effect of fatigue was tested.

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Impact of Residual Extractives and Hexenuronic Acid on Lignin Determination of Kraft pulps

  • Shin Soo Jeong;Schroeder Leland R;Lai Yuan Zong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.62-68
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    • 2004
  • The amount of non-lignin components in unbleached and oxygen-delignified kraft pulps and their impact on lignin determinations was investigated. The lignin analyses investigated were kappa number and Klason lignin in conjunction with acid-soluble lignin. The species investigated were loblolly pine, and aspen. The non-lignin components that impacted on lignin determination were residual extractives and hexenuronic acid in unbleached and oxygen-delignified kraft pulps. In the hardwoods, significant amounts of extractives remained after kraft pulping and oxygen delignification. These residual extractives in the hardwood pulps had an impact on the lignin determination, more so on the acid lignin method than kappa number. Hexenuronic acid only impacts on kappa number determination both softwood and hardwood pulps, not on acid lignin. Hexeneuronic acid contributed as lignin content more in aspen than pine pulps, and more in oxygen-delignified than unbleached kraft pulps. Impact of hexenuronic acid on should be corrected both softwood and hardwood pulps for accurate kappa number.

Study on Co-incineration of Municipal Solid Waste and Organic Sludges (도시쓰레기와 유기성 하수 슬러지 혼합소각에 관한 연구)

  • Jurng, Jong-Soo;Chin, Sung-Min
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.238-244
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    • 2005
  • This study performs the pilot-plant experiments to evaluate the effect of the oxygen enrichment on the co-incineration of municipal solid waste and organic sludge from a wastewater treatment facility. The design capacity of the stoker-type incinerator pilot-plant is 150 kg/h. Combustion chamber temperatures were measured as well as the stack gas concentrations, i.e., NOx, CO, and the residual oxygen. The maximum ratio of organic sludge waste to the total waste input is 30%. Also the oxygen-enriched air with 23% of oxygen in supplied air is used for stable combustion. As the co-incineration ratio of the sludge increased up to 30% of the total waste input, the primary and the secondary combustion chamber temperature was decreased $to900^{\circ}C$ (primary combustion chamber), $750^{\circ}C$(secondary combustion chamber), respectively, approximately $200^{\circ}C$ below the incineration temperature of the domestic waste only (primary: $1,100^{\circ}C$, secondary: $950^{\circ}C$). However, if the supplied air was enriched to 22% oxygen content in air, the incinerator temperature was high enough to burn the waste mixture with 30% sludge, which has the heating value of 1,600 kcal/kg.

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Influence of Residual Oxygen on the growth of AlN Thin Films with Substrate Temperature (기판 온도 변화에 따른 AlN 박막 성장에 잔류 산소가 미치는 영향)

  • Kim, Byoung-Kyun;Lee, Eul-Tack;Kim, Eung-Kwon;Jeong, Seok-Won;Roh, Yong-Han
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.463-467
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    • 2008
  • Aluminum nitride (AlN) thin films have been deposited on Au electrodes by using reactive RF magnetron sputtering method in a gas mixture of Ar and $N_2$ at different substrate temperature. It was found that substrate temperature was varied in the range up to $400^{\circ}C$, highly c-axis oriented film can be obtained at $300^{\circ}C$ with full width at half maximum (FWHM) $3.1^{\circ}$. Increase in surface roughness from 3.8 nm to 5.9 nm found to be associated with increase in grain size, with substrate temperature; however, the AlN film fabricated at $400^{\circ}C$ exhibited a granular type of structure with non-uniform grains. The Al 2p and N 1s peak in the X-ray photoelectron spectroscopy (XPS) spectrum confirmed the formation of Al-N bonds. The XPS spectrum also indicated the presence of oxynitrides and oxides, resulting from the presence of residual oxygen in the vacuum chamber. It is concluded that the AlN film deposited at substrate temperature of $300^{\circ}C$ exhibited the most desirable properties for the application of high-frequency surface acoustic devices.