• 제목/요약/키워드: silicone

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Status and Prospect of Test Methods of Quality Silicone Water Repellent for Protecting Reinforced Concrete

  • Sun, H.Y.;Yuan, Z.Y.;Yang, Z.;Shan, G.L.;Shen, M.X.
    • Corrosion Science and Technology
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    • 제16권3호
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    • pp.141-150
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    • 2017
  • Impregnating with quality silicone water repellent on the concrete surface is an effective method of protecting concrete. Quality silicone water repellent has been widely used in the engineering profession because of its desirable properties such as hydrophobicity, keeping concrete breathable and preserving the original appearance of the concrete. The companies in China that produce silicone water repellent are listed. Test methods in the specifications or standards about silicone water repellent in China are summed. The test methods relative to durability of concrete impregnated with silicone water repellent (such as resistant to chloride ion penetration, resistant to alkali, resistance to freezing and thawing and weatherability etc.) and the constructive quality (such as water absorption rate, impregnating depth and the dry velocity coefficient etc.) are compared and analyzed. The results indicate that there are differences among test methods relative to different specifications with the same index and therefore, confusion has ensued when selecting test methods. All test methods with the exception of the method of water absorption rate by using a Karsten flask are not non-destructive methods or conducted in a laboratory. Finally, further research on silicone water repellent during application is proposed.

고출력 LED 인캡슐런트용 실리콘 레진의 경화공정중 잔류응력 발달에 대한 유한요소해석 (Finite Element Analysis of Residual Stress Evolution during Cure Process of Silicone Resin for High-power LED Encapsulant)

  • 송민재;김흥규;강정진;김권희
    • 한국정밀공학회지
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    • 제28권2호
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    • pp.219-225
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    • 2011
  • Silicone resin is recently used as encapsulant for high-power LED module due to its excellent thermal and optical properties. In the present investigation, finite element analysis of cure process was attempted to examine residual stress evolution behavior during silicone resin cure process which is composed of chemical curing and post-cooling. To model chemical curing of silicone, a cure kinetics equation was evaluated based on the measurement by differential scanning calorimeter. The evolutions of elastic modulus and chemical shrinkage during cure process were assumed as a function of the degree of cure to examine their effect on residual stress evolution. Finite element predictions showed how residual stress in cured silicone resin can be affected by elastic modulus and chemical shrinkage behavior. Finite element analysis is supposed to be utilized to select appropriate silicone resin or to design optimum cure process which brings about a minimum residual stress in encapsulant silicone resin.

실리콘액 주사에 의한 급성 폐색전증: 영상의학적 소견 (Acute Pulmonary Embolism by Silicone Injection: Radiologic Findings)

  • 이재교
    • Journal of Yeungnam Medical Science
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    • 제21권2호
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    • pp.215-223
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    • 2004
  • 실리콘의 부적절한 피하 주입으로 발생한 폐색전증의 방사선학적 특징은 초기에는 호흡기 증상만 보이지만 염증 매개성 반응이 진행함에 따라 양측 폐 침윤이 급격히 진행하는 것을 볼 수 있었다. 또한 실리콘의 비중이 혈액보다 낮아 중력 비의존성 분포를 보임을 알 수 있었고, 이는 기존의 다른 원인에 의한 폐색전증과 구분되는 소견이다.

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Salt fog 시험에서 silicone rubber에서 발생하는 방전 전류의 특성 (The surface discharge performance of silicone rubber in the Salt fog test)

  • 강성화;박영국;이광우;김완수;이용회
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.565-569
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    • 1999
  • In these days, the silicone insulators have been increasingly studied and applied for outdoor insulators because it has superior characteristics than porcelain and glass insulators, which have been used for outdoor insulators. First of all, The excellent performance of the silicone rubber in polluted and wet conditions is attributed to the ability of the material to maintain the hydrophobicity of the surface in the presence of severe contamination and wet conditions. This is because of the presence of low molecular weight mobile fluid in the silicone rubber which diffuses to the surface and to above the contamination layer. But, the leakage current and some surface discharge occurs on surface of the composite polymeric insulation materials when the insulator is used for a long time with severe contaminative condition and it can lead the contamination flashover. So the leakage current and the discharge current are important to estimate the condition of the silicone rubber surface. In this paper, the average leakage current, the relation of surface discharge current and phase angle were study to investigate electrical conduction of silicone rubber surface with the salt fog condition.

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실리콘이 라미네이팅된 신축성 소재의 위생 및 안전성과 역학적 성능 (Analysis of Physical Performance, Hygiene and Safety of Silicone-Laminated Stretch Material)

  • 권명숙;정기수
    • 한국의류학회지
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    • 제31권1호
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    • pp.77-84
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    • 2007
  • The purpose of this study was to investigate and to compare the performances of silicone laminated materials sold for swimming cap in market, to get the basic data for product development. We selected 4 specimens and tested their air permeability, waterproofness and breathability. We also tested the physical and mechanical properties of the specimens using KES system. Silicone-laminated material was not bursted on high hydraulic pressure since silicone membrane gave waterproofness while PU/Polyester substrate gave elasticity. It didn't have air permeability and breathability at all. Any toxic materials such as Formaldehyde, Deldrin, PCP, Amin, TDBPP were not detected in silicone-laminated material and other materials. Silicone-laminated material had higher stretchability with the low force but it had lower elastic recovery and shape stability comparing to PU laminated material. It had lower flexibility than PU laminated material. It had lower unrecoverable amount in shearing direction. Friction coefficient was higher in silicone-laminated material than PU laminated material due to its surface stickiness. It was compressed easily and its compression resiliency was higher with compared to PU laminated material.

고전압용 실리콘고무의 전기적 특성 (The Electrical Properties of High Voltage Silicone Rubber)

  • 김성필;송정우;이종필;이수원;김왕곤;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.779-782
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    • 2000
  • Silicone rubbers are first silicone polymers and has named silicone from existence of Si-O bond similar to Keton. Silicon in organic compound has been called silicone, and linear or network polymers. Silicone rubbers have been used as an power insulator because they are well weather proof, ozone proof and have excellent electric characteristics, thermal stability, cold resistance and low surface energy. Especially, it is known that they have very excellent characteristics at 200[$^{\circ}C$]. For this study, we made silicone rubbers as specimens and we measured dielectric loss tangent due to applied voltage at temperature range 25[$^{\circ}C$] to 180[$^{\circ}C$] and frequency range 20[Hz] to 1${\times}$10$\^$6/[Hz] to examine dielectric properties. We measured dielectric loss tangent to study the insulation performance of silicone rubbers.

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Silicone Rubber Membrane의 제조 및 기공특성 (Preparation of Silicone Rubber Membrane and its Porosity)

  • 이승범;김형진;홍인권
    • Elastomers and Composites
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    • 제30권3호
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    • pp.185-194
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    • 1995
  • Membrane process has been employed to separate a specific substance from gas or liquid mixture, and treat wastewater. This is due to the fact that the substance of mixture can be permeated and separated selectively by membrane. Since Initial equipment and operation costs are not expensive, membrane process has been adopted in various fields such as petroleum Industry, chemistry, polymer, electronics, foods, biochemical industry and wastewater treatment. In this study, $CaCO_3$ particles impregnated in silicone rubber network were extracted by using supercritical carbon dioxide and pore distribution of silicone $rubber-CaCO_3$ was investigated with varying amount of extract. Silicone rubber has excellent mechanical properties such as heat-resistance, cold-resistance etc. and $CaCO_3$ has microporous structure. It is possible to make silicone $rubber-CaCO_3$ composite sheets via work-intensive kneading processes. In so doing $CaCO_3$ particles become distributed and impregnated in silicone rubber network. Supercritical carbon dioxide diffuse through composite sample, then sample is swollen. $CaCO_3$ in silicone rubber network Is dissolved in supercritical carbon dioxide, and its sites become pores. Pore distribution, pore shape and surface area are observed by SEM(scanning electron microscope) micrograph and BET surface area analyzer examination respectively. Pore characteristics of membrane suggest the possibilities that the membrane can be used for process of mixture separation and wastewater treatment.

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BTCA와 실리콘 처리 면직물의 물리적 성질 (Physical Properties of Cotton Fabric Treated with BTCA and P olyalkyleneoxide-modified amino-functional silicone)

  • 남승현;유효선
    • 한국의류학회지
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    • 제22권4호
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    • pp.525-534
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    • 1998
  • Cotton fabrics were finished with mixture of BTCA(1,2,3,4,-butanetetracarboxylic acid) and polyalkyleneoxide-modified amino-functional silicone by pad-dry-cure process to achieve better DP performance with a higher retention of physical properties as compared to those of finished with BTCA alone. The results indicated that BTCA improved the wrinkle recovery but reduced significantly the tensile and tear strength of the treated fabrics. Whereas silicone imparted a lower wrinkle recovery, a lower loss of tensile strength than BTCA, in addition improved considerably the tear strength owing to reduction in inter-fiber and/or inter-yarn frictional forces. The concentration and curing temperature needed to enhance physical properties were as follows; for BTCA treatments 6%, at 18$0^{\circ}C$, for silicone treatments 1% at 14$0^{\circ}C$. This optimum concentration of silicone was observed by using the mixture of BTCA and silicone. The wrinkle recovery and DP rating of cotton fabrics treated with mixture of 4% BTCA and 1% silicone at a curing temperature of 17$0^{\circ}C$ was similar to those of treated with 6% BTCA at a curing temperature of 18$0^{\circ}C$, and other performance properties observed were; an increase in tensile strength, extension, toughness, abrasion resistance and moisture regain due to the reduction of BTCA concentration and curing temperature, futhermore an improvement in bending and surface properties due to the lubricating effect of silicone. On the other hand 1% aqueous silicone solution showed the lowest surface tension. Such nonionic surface activity resulted in a more uniform and rapid deposition of BTCA on the fiber or fabric.

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Cannula-typed Silicone Voice Prosthesis(소망$\circledR$)의 개발 (Development of Cannula-typed Silicone Voice Prosthesis(So-Mang$\circledR$))

  • 최홍식;정은주;전희선;문인석;김영호;김광문
    • 대한후두음성언어의학회지
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    • 제12권2호
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    • pp.152-157
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    • 2001
  • Background : Electrolarynx, Esophageal voice, and Silicone voice prosthesis with tracheoesophageal(T-E) fistula have been used as vocal rehabilitating methods for the post-laryngectomized patients. Prosthetic rehabilitation of voice after total laryngectomy has gained wide acceptance and has become a common practice in many clinics since the pioneering works of Singer and Blom In 1979. Since the introduction of tracheo-esophageal puncture and application of Blom Singer$\circledR$ voice prosthesis in 1980, several reliable voice prostheses have been developed and are successfully being used. Objectives : Even though quality of voice produced by Silicone voice prosthesis with T-E fistula is superior to other modalities, it still has some disadvantages. We devised a new cannulatyped silicone voice prosthesis. Methods : 1) Devising a new prototype of cannula-typed silicone voice prosthesis. 2) Application of the prototype using canine animal model(laryngectormized dog) and fitting trial on human patient whose previously inserted Silicone voice prosthesis is not functioning due to presumed fungal infection. Discussion : Final form of prototype was made after several times of major and minor modifications. Insertion of the newly developed Cannula-typed Silicone voice prosthesis on canine animal model and human trial were done without any difficulty. There were no serious leakage of saliva or food during swallowing. Conclusion : The newly developed Cannula-typed Silicone voice prosthesis(So-Mang$\circledR$) and the modified replacement method will further improve the results of post-laryngectomized prosthetic voice rehabilitation. Long-term animal study and human trial are planned in the near future.

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견직물의 수지가공에 관한 연구 (A Study on the Resin Finishing of Silk Fabric -Silicone Resin Finishing-)

  • 남중희;탁태문
    • 한국잠사곤충학회지
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    • 제27권2호
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    • pp.28-39
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    • 1985
  • 견직물의 실용성능(방추도, 세탁성)을 개선할 목적으로 실크하브다이(silk habutae)에 실리콘수지를 유화 가공법으로 처리하였다. 실리콘가공 하브다이의 방추도, 발수도, 유연도, 강신도, 수분율 등은 직물검사 방법에 따라서 검사하였고 가공 후 견피브로인의 구조적인 변화를 구명하기 위하여 주사전자현미경, 아미노산분석, X-선 회절강도, FT-IR 흡수분석에 의하여 검토한 결과 아래와 같은 결과를 얻었다. 1) 견하브다이 직물의 방추도는 soaping 처리오 큐어링 조건에 의하여 현저히 개선되었다. 2) 실리콘 수지 가공에 의하여 견하브다이의 발수도와 유연도가 향상되었고, 가공 후 silk fibroin을 주사전자현미경으로 관찰한 결과 견섬유 특유의 불규칙한 섬유표면은 평활하게 관찰되었다. 3) 실리콘 수지와 silk fibroin의 반응에 따라서 피브로인 조성 아미노산 중 극성기를 가지고 있는 아미노산의 감소비율이 현저하였다. 4) 실리콘 수지가공 silk habutae는 soaping에 의하여 X-선 회절강도가 높아지는 경향이었다. 5) 가공 후 견하브다이의 FT-IR 흡수곡선에 실록산등의 peak가 검출된 것으로 미루어 fibroin의 개질이 가능하다고 생각된다.

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