• Title/Summary/Keyword: specific degradation

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Fungal Metabolism of Environmentally Persistent Compounds: Substrate Recognition and Metabolic Response

  • Wariishi, Hiroyuki
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.6
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    • pp.422-430
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    • 2000
  • Mechanism of lignin biodegradation caused by basidiomycetes and the history of lignin biodegradation studies were briefly reviewed. The important roles of fungal extracellular ligninolytic enzymes such as lignin and manganese peroxidases (LiP and MnP) were also summarized. These enzymes were unique in their catalytic mechanisms and substrate specificities. Either LiP or MnP system is capable of oxidizing a variety of aromatic substrates via a one-electron oxidation. Extracellular fungal system for aromatic degradation is non-specific, which recently attracts many people working a bioremediation field. On the other hand, an intracellular degradation system for aromatic compounds is rather specific in the fungal cell. Structurally similar compounds were prepared and metabolized, indicating that an intracellular degradation strategy consisted of the cellular systems for substrate recognition and metabolic response. It was assumed that lignin-degrading fungi might be needed to develop multiple metabolic pathways for a variety of aromatic compounds caused by the action of non-specific ligninolytic enzymes on lignin. Our recent results on chemical stress responsible factors analyzed using mRNA differential display techniques were also mentioned.

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Model Development for Specific Degradation Using Data Mining and Geospatial Analysis of Erosion and Sedimentation Features

  • Kang, Woochul;Kang, Joongu;Jang, Eunkyung;Julien, Piere Y.
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.85-85
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    • 2020
  • South Korea experiences few large scale erosion and sedimentation problems, however, there are numerous local sedimentation problems. A reliable and consistent approach to modelling and management for sediment processes are desirable in the country. In this study, field measurements of sediment concentration from 34 alluvial river basins in South Korea were used with the Modified Einstein Procedure (MEP) to determine the total sediment load at the sampling locations. And then the Flow Duration-Sediment Rating Curve (FD-SRC) method was used to estimate the specific degradation for all gauging stations. The specific degradation of most rivers were found to be typically 50-300 tons/㎢·yr. A model tree data mining technique was applied to develop a model for the specific degradation based on various watershed characteristics of each watershed from GIS analysis. The meaningful parameters are: 1) elevation at the middle relative area of the hypsometric curve [m], 2) percentage of wetland and water [%], 3) percentage of urbanized area [%], and 4) Main stream length [km]. The Root Mean Square Error (RMSE) of existing models is in excess of 1,250 tons/㎢·yr and the RMSE of the proposed model with 6 additional validations decreased to 65 tons/㎢·yr. Erosion loss maps from the Revised Universal Soil Loss Equation (RUSLE), satellite images, and aerial photographs were used to delineate the geospatial features affecting erosion and sedimentation. The results of the geospatial analysis clearly shows that the high risk erosion area (hill slopes and construction sites at urbanized area) and sedimentation features (wetlands and agricultural reservoirs). The result of physiographical analysis also indicates that the watershed morphometric characteristic well explain the sediment transport. Sustainable management with the data mining methodologies and geospatial analysis could be helpful to solve various erosion and sedimentation problems under different conditions.

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Electrochemical Advanced Oxidation of Lamotrigine at Ti/DSA (Ta2O5-Ir2O5) and Stainless Steel Anodes

  • Meena, Vinod Kumar;Ghatak, Himadri Roy
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.292-307
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    • 2022
  • The study presents kinetics of degradation and mineralization of an anti-epileptic drug Lamotrigine (LAM) in the aqueous matrix by electrochemical advanced oxidation process (EAOP) on Ti/DSA (Ta2O5-Ir2O5) and Stainless Steel (SS) anodes using sodium sulphate as supporting electrolyte. On both the anodes, kinetic behaviour was pseudo-first-order for degradation as well as mineralization of LAM. On Ti/DSA anode, maximum LAM degradation of 75.42% was observed at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 100 ppm Na2SO4 concentration. Maximum mineralization attained was 44.83% at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 50 ppm concentration of Na2SO4 with energy consumption of 2942.71 kWh/kgTOC. Under identical conditions on SS anode, a maximum of 98.92% LAM degradation was marked after a specific charge (Q) of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 100 ppm concentration of Na2SO4. Maximum LAM mineralization on SS anode was 98.53%, marked at a specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 75 ppm concentration of Na2SO4, with energy consumption of 1312.17 kWh/kgTOC. Higher Mineralization Current Efficiency (MCE) values were attained for EAOP on SS anode for both degradation and mineralization due to occurrence of combined electro-oxidation and electro-coagulation process in comparison to EAOP on Ti/DSA anode due to occurrence of lone electro-oxidation process.

Cometabolism of MTBE by pure culture isolated from gasoline contaminated aquifer

  • 장순웅;이시진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.364-367
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    • 2003
  • In this paper, we have examined the MTBE cometabolic degradation by pure culture, which is isolated gasoline contaminated aquifer. Propane was more effectively utilized as a growth substrate to oxidize MTBE. Specific substrate degradation rate was Increased with increasing initial propane amount. Respiking propane was enhanced and continued MTBE degradation and TBA observation was supported MTBE degradation. The mass balance of MTBE and TBA indicated that MTBE was oxidized to TBA as well as further oxidation of TBA.

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A Study on the Image Processing for Effective Insulation Material Degradation Testing (효과적인 절연재료 열화검사를 위한 영상처리에 관한 연구)

  • 정기봉;오무송;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.230-233
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    • 1999
  • Because Insulation material is play an important part for normal work of electricity equipment, the study is advanced, but as the voltage of electricity system is raising, we required that new lnsulation material. They have excellent specific against high stress, namely the study of insulation increase and prevention diagnosis of insulation degradation of Epoxy or XLPE and so on. In this thesis. I utilize image processing technique for effective inspection of insulation material degradation.

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Model development for the estimation of specific degradation using classification and prediction of data mining (데이터 마이닝의 분류 및 예측 기법을 적용한 비유사량 추정 모델 개발)

  • Jang, Eun-kyung;Kang, Woochul
    • Journal of Korea Water Resources Association
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    • v.53 no.3
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    • pp.215-223
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    • 2020
  • The objective of this study is to develop a prediction model of specific degradation using data mining classification especially for the rivers in South Korea river. A number of critical predictors such as erosion and sediment transport were extracted for the prediction model considering watershed morphometric characteristics, rainfall, land cover, land use, and bed material. The suggested model includes the elevations at the mid relative area of the hypsometric curve of watershed morphomeric characteristics, the urbanization ratio, and the wetland and water ratio of land cover factors as the condition factors. The proposed model describes well the measured specific degradation of the rivers in South Korea. In addition, the development model was compared with the existing models, since the existing models based on different conditions and purposes show low predictability, they have a limit about the application of Korean River. Therefore, this study is focusing on improving the applicability of the existing model

A Review on Degradation of Silicon Photovoltaic Modules

  • Yousuf, Hasnain;Khokhar, Muhammad Quddamah;Zahid, Muhammad Aleem;Kim, Jaeun;Kim, Youngkuk;Cho, Sung Bae;Cho, Young Hyun;Cho, Eun-Chel;Yi, Junsin
    • New & Renewable Energy
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    • v.17 no.1
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    • pp.19-32
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    • 2021
  • Photovoltaic (PV) panels are generally treated as the most dependable components of PV systems; therefore, investigations are necessary to understand and emphasize the degradation of PV cells. In almost all specific deprivation models, humidity and temperature are the two major factors that are responsible for PV module degradation. However, even if the degradation mode of a PV module is determined, it is challenging to research them in practice. Long-term response experiments should thus be conducted to investigate the influences of the incidence, rates of change, and different degradation methods of PV modules on energy production; such models can help avoid lengthy experiments to investigate the degradation of PV panels under actual working conditions. From the review, it was found that the degradation rate of PV modules in climates where the annual average ambient temperature remained low was -1.05% to -1.16% per year, and the degree of deterioration of PV modules in climates with high average annual ambient temperatures was -1.35% to -1.46% per year; however, PV manufacturers currently claim degradation rates of up to -0.5% per year.

Photocatalytic Degradation of Rhodamine B Using Carbon-Doped Carbon Nitride under Visible Light

  • Wang, Zhong-Li;Zhang, Zai-Teng;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.279-284
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    • 2020
  • In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2 h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.

Identification of Receptor-like Protein for Fructose-1,6-bisphosphatase on Yeast Vacuolar Membrane

  • Ko, Je-Sang
    • BMB Reports
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    • v.33 no.6
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    • pp.448-453
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    • 2000
  • In yeast the key gluconeogenic enzyme, fructose-1,6-bisphosphatase (FBPase), is selectively targeted from the cytosol to the lysosome (vacuole) for degradation when glucose starved cells are replenished with glucose. The pathway for glucose induced FBPase degradation is unknown. To identify the receptor-mediated degradation pathway of FBPase, we investigated the presence of the FBPase receptor on the vacuolar membrane by cell fractionation experiments and binding assay using vid mutant (vacuolar import and degradation), which is defective in the glucose-induced degradation of FBPase. FBPase sedimented in the pellets from vid24-1 mutant after centrifugation at $15,000{\times}g$ for 15 min, suggesting that FBPase is associated with subcellular structures. Cell fractionation experiments revealed that FBPase is preferentially associated with the vacuole, but not with other organelles in vid24-1. FBPase enriched fractions that cofractionated with the vacuole were sensitive to proteinase K digestion, indicating that FBPase is peripherally associated with the vacuole. We developed an assay for the binding of FBPase to the vacuole. The assay revealed that FBPase bound to the vacuole with a Kd of $2.3{\times}10^6M$. The binding was saturable and specific. These results suggest that a receptor for FBPase degradation exists on the vacuolar membrane. It implies the existence of the receptor-mediated degradation pathway of FBPase by the lysosome.

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Biodegradation of PAHs (Polycyclic Aromatic Hydrocarbon) Using Immobilized Cells of Phanerochaete chrysosporium (고정화 Phanerochaete chrysosporium을 이용한 다환 방향족 화합물의 분해)

  • 서윤수;류원률;김창준;장용근;조무환
    • KSBB Journal
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    • v.15 no.3
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    • pp.247-253
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    • 2000
  • This study was aimed to enhance polycyclic aromatic hydrocarbon(PAHS) biodegradation rate by repeated-batch treatment using immobilized cells of Phanerochaete chrysosporium. In the repeated-batch operations with 30 mg/L of pyrene the maximum degradation rate was 6.58 mg/L day. As the number of batches increased the concentration of immobilized cells significantly decreased and the degradation rate and specific acitivity gradually increased to a maximum value and then decreased. To have PAH degradation activity and cell mass recovered one batch of cultivation using the growth medium instead of the PAH-degrading medium was carried in the course of repeated-batch operations. This maximum degradation rates of pyrene and anthracene were 4.29 and 4.46 mg/L$.$day respectively. Overall the rate of PAH degradation could be enhanced 2.5-30 folds by using immobilized cells compared to the case of using suspended cells.

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