• Title/Summary/Keyword: spectroscopic change

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Development and Application of Rotating Compensator Spectroscopic Ellipsometer (Rotating Compensator Spectroscopic Ellipsometer의 개발 및 응용)

  • 이재호;방경윤;박준택;오혜근;안일신
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.2
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    • pp.1-4
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    • 2003
  • We have developed a rotating compensator spectroscopic ellipsometer (RCSE). As the ellipsometry measures a change in the polarization state of a light wave upon non-normal reflection from surface, the degree of sensitivity is enhanced greatly through the detection of relative phase change. RCSE acquires additional information from the non-ideal surface of sample and operates over the photon energy range from 1.5 to 4.5 eV. We applied RCSE to measure the optical properties of films and the line-width of patterned PR films on crystalline silicon.

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A NEW ALTERNATIVE ELLIPTIC PDE IN EIT IMAGING

  • Kim, Sungwhan
    • Bulletin of the Korean Mathematical Society
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    • v.49 no.6
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    • pp.1291-1302
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    • 2012
  • In this paper, we introduce a new elliptic PDE: $$\{{\nabla}{\cdot}\(\frac{|{\gamma}^{\omega}(r)|^2}{\sigma}{\nabla}v_{\omega}(r)\)=0,\;r{\in}{\Omega},\\v_{\omega}(r)=f(r),\;r{\in}{\partial}{\Omega},$$ where ${\gamma}^{\omega}={\sigma}+i{\omega}{\epsilon}$ is the admittivity distribution of the conducting material ${\Omega}$ and it is shown that the introduced elliptic PDE can replace the standard elliptic PDE with conductivity coefficient in EIT imaging. Indeed, letting $v_0$ be the solution to the standard elliptic PDE with conductivity coefficient, the solution $v_{\omega}$ is quite close to the solution $v_0$ and can show spectroscopic properties of the conducting object ${\Omega}$ unlike $v_0$. In particular, the potential $v_{\omega}$ can be used in detecting a thin low-conducting anomaly located in ${\Omega}$ since the spectroscopic change of the Neumann data of $v_{\omega}$ is inversely proportional to thickness of the thin anomaly.

Spectroscopic Ellipsometry Measurement and Modeling of Hydrogenated Amorphous Silicon (수소화된 비정질 실리콘의 타원편광분광분석 측정 및 모델링)

  • Kim, Ka-Hyun
    • Journal of the Korean Solar Energy Society
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    • v.39 no.1
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    • pp.11-19
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    • 2019
  • Spectroscopic ellipsometry is a powerful tool for analyzing optical properties of material. Ellipsometry measurement results is usually given by change of polarization state of probe light, so the measured result should be properly treated and transformed to meaningful parameters by transformation and modeling of the measurement result. In case of hydrogenated amorphous silicon, Tauc-Lorentz dispersion is usually used to model the measured ellipsometry spectrum. In this paper, modeling of spectroscopic ellipsometry result of hydrogenated amorphous silicon using Tauc-Lorentz dispersion is discussed.

CRT Color Transform to CIELab Color System using RGB Image Data (RGB 화상테이터를 이용한 CRT 표현색의 CIELab 표색계로의 변화에 관한 연구)

  • 안석출
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.1
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    • pp.73-91
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    • 1995
  • Spectroscopic and Photoelectric Characteristics in the Cyanine and Merocyanine Dye according to systematically change of their structures were experimentally discussed. As result, in solution, Hetero atoms(X) of Cyanine and Merocyanine dye were participated in resonance X of d obital rather than X of pobital,effected in resonance and contributed in extension of conjugated system. in solid film,new spectra,called eximer-fluorenscence,were appeared in 3-dimensional fluorenscence of high density of Cyanine dye but not of Merocyanine. The activational energy of conductivity in Merocyanine dye was lower than in cyanine, an the contrary,the drift mobility was higher and the former in photoelectric characteristics was more effec-tive than the latter. In this paper,authors invertigated the changes of dye structure by molecular obital method to confirm the results of spectroscopic and photoelectric characteristics in the Cyanine and Merocyanine Dye acco-rding to systematically cally change of their structure, and counted total energy on dihedral angle and dipol miments if dyes in S0 and S1.

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Investigation on the Interaction of Gabapentin with Bovine Serum Albumin by Spectroscopic Techniques

  • Ashoka, S.;Seetharamappa, J.;Kandagal, P.B.;Shaikh, S.M.T.
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.113-117
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    • 2005
  • Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

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A study on the metamictization and color change in zircon by spectroscopic analysis (분광분석을 통한 지르콘의 메타믹상태와 색상 변화 분석)

  • Kim, Seong-Ki;Ahn, Yong-Kil;Seo, Jin-Gyo;Kim, Jong-Gun;Park, Jong-Wan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.12-20
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    • 2010
  • Metamictization and color change in zircons from Cambodia and Tanzania were investigated. Elements analysis to detect radioactivity of elements such as U and Th, and spectroscopic analysis using UV-VIS and Fourier transform infrared spectroscopy were performed. According to the UV-VIS spectroscopic analysis, it was perceived that many and high intense absorption peaks appeared in blue and colorless zircons, while less and low intense absorption peaks appeared in uranium contained green and yellow zircons. It was found that those stones have made progress to the metamictization. After heat treatment, we could detect opposite results. As the results of FTIR spectroscopy analysis, in the metamict green and yellow zircon, it is showed that 3-phonon combination mode bands of $[SiO_4]^{4-}$ internal vibration in the region of 3100~3400 $cm^{-1}$ are broad and some of them disappear. However, the disappeared bands are observed again due to restored crystal lattice by the heat treatment. Also, $U^{4+}$ peaks that can detect the uranium content in zircon appears at near 4800 $cm^{-1}$ in the green and yellow samples. From this investigation, we could observe the metamictization effect and color change in uranium-bearing zircon by heat treatment using spectroscopic analysis.

DETECTION OF PHYSIOLOGICAL PROCESSES IN WHEAT BY NIR

  • Salgo, A.;Gergely, Sz.;Scholz, E.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1158-1158
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    • 2001
  • Fast and dynamic biochemical, enzymatic and morphological changes occur during the so-called generative development and during the vegetative processes in seeds. The most characteristic biochemical and compositional changes of this period are the formation and decline of storage components or their precursors, the change of their degree in polymerization and an extensive change in water content. The aim of the present study was to detect the maturation processes in seed nondestructively and to verify the applicability of near infrared spectroscopic methods in the measurement of physiological, chemical and biochemical changes in wheat seed. The amount and variation of different water “species” has been changed intensively during maturation. Characteristic changes of three water absorption bands (1920, 1420 and 1150 nm) during maturation were analysed. It was concluded that the free/bound transition of water molecules could be followed sensitively in different region of NIR spectra. Kinetic changes of carbohydrate reserves were characteristic during maturation. An intensive formation and decline of carbohydrate reserves were observed during early stage of maturation (0 -13 days, high energy demand). An accelerated formation of storage carbohydrates (starch) was detected in the second phase of maturation. Five characteristic absorption bands were analysed which were sensitive indicators the changes of carbohydrates occurred during maturation. Precursors of protein synthesis and the synthesis of reserve proteins and their kinetic changes during maturation were followed from NIR spectra qualitative and qualitatively. Dynamic formation of amino acids and the changes of N forms were detected by spectroscopic, chromatographic and by capillary electrophoresis methods. Calibration equations were developed and validated in order to measure the optimal maturation time protein and moisture content of developing wheat seeds. The spectroscopic methods are offering chance and measurement potential in order to detect fine details of physiological processes. The spectra have many hidden details, which can help to understand the biochemical background of processes.

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The Inactivation Effects of UV Light on Bacteriophage f2 (박테리오파지 f2에 대한 자외광선의 살균효과)

  • Kim, Chi-Kyung;Quae Chae
    • Microbiology and Biotechnology Letters
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    • v.11 no.3
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    • pp.155-161
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    • 1983
  • The effects of ultraviolet light on bacteriophage f2 were investigated to determine the inactivation kinetics and its mechanism. The 260nm light showed a little higher inactivation rate than the one of 300 nm. In this work, our main concern was whether structural and/or conformational changes in the protein capsid could occur by UV irradiation. The inactivation for the first 20 minutes irradiation was rapid with a loss of about 4 logs and followed by a slower rate during the next 40 minutes with no survival noted in the samples irradiated for 90 minutes or longer. The structural change of the protein capsid was examined by optical spectroscopic techniques and electron microscopy. The absorption spectra of the UV irradiated phages showed no detectable differences in terms of the spectral shape and intensity from the control phage. However, the fluorescence emission spectroscopic data, i.e. 1) fluorescence quenching of tryptophan residues upon irradiation of 300 nm light, 2) enhancement of fluorescence emission of ANS (8-aniline-1-naphthalene sulfonate) bound to the intact phages compared to the one in the UV-treated phages, and 3) decrease of energy transfer efficiency from tryptophan to ANS in the UV-treated samples, presented remarkable differences between the intact and UV-treated phages. Such a structural alteration was also observed by electron microscopy The UV-treated phages appeared to be broken and empty capsids. Therefore, the inactivation of the bacteriophage f2 by UV irradiation is thought to be attributed to the structural change in the protein capsid as well as damage in the viral RNA by UV irradiation.

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Initial Photometric and Spectroscopic Characteristics of 55-inch CCFL and LED Backlights for LCD-TV Applications

  • Ko, Jae-Hyeon;Ryu, Jin-Sun;Yu, Mi-Yeon;Park, Seung-Mi;Kim, Su-Jin
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.3
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    • pp.8-13
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    • 2010
  • For better picture quality in LCD TVs, it is important to reach a steady emitting state within as short a time as possible in the initial stage after the TV is turned on. The initial characteristics of LCD TVs are mainly determined by the properties of the backlight. In the present study, the photometric and spectroscopic properties of a 55-inch Cold Cathode Fluorescent Lamp (CCFL) and Light Emitting Diode (LED) backlights were investigated. The measured properties include time dependence of the spectrum, luminance, and color coordinates. The results show that the change in the spectroscopic properties of the LED backlight is smaller than that of the CCFL backlight. This indicates that the initial picture quality of the LCD TV with the LED backlight is superior to that with the CCFL backlight. The origins of this difference were discussed in relation to the inherent characteristics of the two light sources.

Thermal stability analysis of interferometric snapshot spectro-polarimeter (간섭기반 스냅샷 분광편광위상측정의 열 안정성 분석)

  • Choi, Inho;Dembele, Vamara;Paul, Madhan Jayakumar;Choi, Sukhyun;Kim, Junho;Baek, Byung-Joon;Kim, Daesuk
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.70-74
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    • 2018
  • In typical spectroscopic ellipsometry, the optical and geometrical properties of thin film and nano pattern can be obtained by measuring the polarization state of light reflected/transmitted from the object by rotating a analyzer or a compensator. We proposed a snapshot spectroscopic ellipsometric system based on a modified Michelson interferometer to overcome the time-consuring measurement principle due to rotating part. The proposed system provides spectral ellipsometric parameters (psi, delta) in real time by using a single spectral interference signal generated in the interferometric polarization module. However, it has a long-term stability problem resulting in delta(k) drift. In this paper, it is experimentally proved that the drift problem is caused by anisotropic refractive index change of the beam intersection layer in beam splitter of interferometer.