• 제목/요약/키워드: stabilizers

검색결과 277건 처리시간 0.027초

Alumina 소지상의 무전해 동도금층의 밀착력에 미치는 안정제의 영향 (The Effects of Stabilizers on Adhesion of Electroless Copper Deposits on Alumina)

  • 최순돈;이희록
    • 한국표면공학회지
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    • 제29권2호
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    • pp.109-119
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    • 1996
  • In order to improve adhesion of electroless copper deposits on alumina substrates, some stabilizers such as 2-Mercapto Benzothiazole, thiourea and NaCN were added over a wide range of concentrations. The adhesion tests of the deposits were performed by using the cellophane tape and the push-pull scale. With the minor addition of the stabilizers, 2-MBT having a large molecular size gives poor adhesion, together with a finer grain structure, whereas Thiourea and NaCN show a high mechanical strength of the deposits. The high mechanical strength is supposed to be due to the easy desorption of hydrogen gas generated from the electroless reactions. A large amount of the three stabilizers decreases the adhesion for all the cases, resulting from strong adsorption of the stabilizers to the substrates.

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중금속 오염토양에 대한 안정화 및 식물상 정화공법의 동시 적용연구 (Feasibility Test for Phytoremediation of Heavy Metals-Contaminated Soils using Various Stabilizers)

  • 전종원;배범한;김영훈
    • 한국지반환경공학회 논문집
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    • 제13권3호
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    • pp.59-70
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    • 2012
  • 본 연구에서는 중금속오염 토양에 대하여 소량의 다양한 안정화제를 이용한 안정화공법과 식물정화증진공법을 동시에 적용하여 식물상 정화공법의 보조단계로 최적의 효과를 가진 안정화제를 알아보고자 하였다. 국내의 비교적 큰 규모의 중금속 오염토양인 제련소 오염토양을 대상으로 zeolite, Mn dioxide, slag, Ca oxide, 및 magnetite를 안정화제로 처리한 후 고사리과 식물을 이용한 식물상 정화증진공법 실험을 진행하였다. 안정화제 사용여부 및 종류에 따른 토양의 중금속 추출율을 확인하였으며, 식물시료의 성장 특성과 중금속 흡수율을 확인하였다. 안정화제 적용 시 토양의 용출율은 감소되었으며 중금속의 안정화가 이루어졌으며, magnetite, calcium oxide등의 안정화제가 좋은 효과를 보였다. 식물시료의 분석결과 Pb, Cu, Zn, 그리고 Ni등의 중금속은 식물의 뿌리 부분에 높은 농도로 농집 되는 것을 확인하였고, As의 경우 잎에 높게 농집 되는 것을 확인하였다. 안정화제를 투입한 결과 식물의 성장이 촉진되어 바이오매스생산량이 증대되었다. 안정화제는 식물상 정화공법이 적용되는 비교적 장기간 동안 토양 내의 중금속의 용출을 막아주며 식물의 성장을 촉진시켜 식물상 정화공법만을 사용할 경우 염려되는 오염의 유출 등의 식물상 정화공법의 단점을 보완해줄 것으로 판단된다.

Analysis of Hypoxia-Inducible Factor Stabilizers by a Modified QuEChERS Extraction for Antidoping Analysis

  • Kim, Si Hyun;Lim, Nu Ri;Min, Hophil;Sung, Changmin;Oh, Han Bin;Kim, Ki Hun
    • Mass Spectrometry Letters
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    • 제11권4호
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    • pp.118-124
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    • 2020
  • An analytical method was developed for hypoxia-inducible factor (HIF) stabilizers based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) sample preparation and liquid chromatography-high resolution mass spectrometry analysis. HIF stabilizers potentially enhance the performance of athletes, and hence, they have been prohibited. However, the analysis of urinary HIF stabilizers is not easy owing to their unique structure and characteristics. Hence, we developed the QuEChERS preparation technique for a complementary method and optimized the pH, volume of extraction solvent, and number of extractions. We found that double extraction with 1% of formic acid in acetonitrile provided the highest recovery of HIF stabilizers. Moreover, the composition of the mobile phase was also optimized for better separation of molidustat and IOX4. The developed method was validated in terms of its precision, detection limit, matrix effect, and recovery for ISO accreditation. To the best of our knowledge, this is the first demonstration of the application of the QuEChERS method, which is suitable as a complementary analytical method, in antidoping.

Aerodynamic stabilization of central stabilizers for box girder suspension bridges

  • Ge, Yaojun;Zou, Xiaojie;Yang, Yongxin
    • Wind and Structures
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    • 제12권4호
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    • pp.285-298
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    • 2009
  • For long-span suspension bridges with their intrinsic limit in flutter, some counter measures, for example, central stabilizers, should be adopted to improve aerodynamic stability to meet with the appropriate wind resistance requirements. The present paper introduces aerodynamic stabilization for long-span suspension bridges with box girders by using central stabilizers based on Xihoumen Bridge with the main span of 1650 m. The aerodynamic stabilization study covers experimental investigation of sectional model testing, comprehensive evaluation of three central stabilizers and theoretical analysis of stabilizing mechanism related to flutter derivatives, aerodynamic damping and degree participation.

합성 열안정제에 의한 나일론 4의 분해거동 (Degradation Behavior of Nylon 4 in the Presence of Newly Synthesized Thermal Stabilizers)

  • 장근석;김종호;김대근;김영준;이택승
    • 폴리머
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    • 제38권3호
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    • pp.314-319
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    • 2014
  • 힌더드 아민기를 포함하고 있는 헤테로환을 가지며 알킬사슬 길이가 서로 다른 세 종류의 나일론 4 열안정제를 합성하였다. 힌더드 아민기를 이용하여 라디칼에 의한 열분해를 방지하고, 열안정제와 나일론 4의 아마이드기 간 수소결합을 조절하여 나일론 4의 열적 특성에 미치는 영향을 확인하였다. 안정제의 알킬사슬의 수가 4개일 때 수소결합이 가장 최적화되는 것으로 등온 TGA 결과를 통해서 확인하였다. 또한 시판중인 나일론 6의 열안정제를 사용하여 나일론 4에 대한 열안정성을 비교 실험한 결과, 합성 열안정제가 나일론 4의 열안정성을 실질적으로 향상시킨 것을 확인하였다.

토양 특성에 따른 중금속 안정화 효율 평가 (Efficiency of Heavy Metal Stabilizers in Various Soils)

  • 김영현;오세진;금동혁;신민환;김동진;이상수
    • 한국환경농학회지
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    • 제40권3호
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    • pp.231-238
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    • 2021
  • BACKGROUND: Metal contamination of farmlands nearby abandoned mines is a serious environmental problem. This study was conducted to evaluate the efficiency of stabilizers on different type of the soils contaminated with metals. METHODS AND RESULTS: The texture of silt loam soil initially contaminated with heavy metal was artificially adjusted to loam and sandy loam by adding sand, and the soil organic matter content (1.5%) was also altered by adding peat to the soils at 3.5 and 8.0%. The soils were mixed with 3% (w/w) of each limestone, dolomite, and steel slag. For the soils with different textures, the bioavailability of As was found to be the lowest in sandy loam compared to others metals such as Cu, Pb, and Zn. The efficacy of limestone and dolomite was not significantly different compared to the soils having different organic matter contents, but the stabilization efficiency of steel slag increased as the soil organic matter content increased. Moreover, stabilizers showed inhibition effect on the uptake of metals to plant. CONCLUSION: The stabilizers were found as effective materials to immobilize metals in soil and to decrease plant uptake of metals. Studies are needed to deeply elucidate the interaction between influencing factors and various stabilizers.

Yoghurt의 안정제 종류에 따른 물성 변화 (Changes of Rheological Properties of Yoghurt by Different Kinds Stabilizers)

  • 최순호;장운기;정종국;오동규;이부웅
    • 한국축산식품학회지
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    • 제18권1호
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    • pp.35-41
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    • 1998
  • The objective of this study was to examine the changes of physical properties by additions of different kinds of stabilizers milk proteins concentration, when stored at 4$^{\circ}C$ or 20$^{\circ}C$ for yoghurt. the results were summarized as follows: 1. Addition of 2% carboxyl methyl cellulose and carrageenan, gelation 0.4%, pectin and starch 0.6%, and carrageenan & pectin 0.8% in the manufacture of yoghurt increased the viscosity, water-holding capacity and protein hydration of yoghurt. 2. Addition of 3% skim milk powder, Ca-caseinate or Na-caseinate 0.6% increased the viscosity, water-holding capacity and protein hydration of yoghurt. 3. Twenty five percent of evaporation of milk promoted to build up the optimal structure of the micelles of yoghurt and improved viscosity, water-holding capacity and protein hydration of yoghurt. 4. Addition of stabilizers to yoghurt showed an increase of viscosity, water-holding capacity and protein hydration when compared with non-addition of stabilizers to yoghurt at 4$^{\circ}C$, 20$^{\circ}C$ storage for 12hrs, 96hrs followed by the decrease of it.

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Effect of Chemical Stabilizers in Silver Nanoparticle Suspensions on Nanotoxicity

  • Bae, Eun-Joo;Park, Hee-Jin;Park, Jun-Su;Yoon, Je-Yong;Kim, Young-Hun;Choi, Kyung-Hee;Yi, Jong-Heop
    • Bulletin of the Korean Chemical Society
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    • 제32권2호
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    • pp.613-619
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    • 2011
  • Colloidal silver nanoparticles (AgNPs) have been commercialized as the typically stabilized form via the addition of a variety of surfactants or polymers. Herein, to examine the effects of stabilizing AgNPs in suspension, we modified the surface of bare AgNPs with four type of surfactants (NaDDBS, SDS, TW80, CTAB) and polymers (PVP, PAA, PAH, CMC). The modified AgNPs was applied to compare suspension stability and nanotoxicity test using Escherichia coli (E. coli) as a model organism. Modification of AgNPs surface using chemical stabilizer may be not related with molecular weight, but chemical structure such as ionic state and functional group of stabilizer. In this study, it is noteworthy that AgNPs modified with a cationic stabilizer (CTAB, PAH) were importantly toxic to E. coli, rather than anionic stabilizers (NaDDBS, SDS). Comparing similar anionic stabilizer, i.e., NaDDBS and SDS, the result showed that lipophilicity of chemical structure can affect on E. coli, because NaDDBS, which contains a lipophilic benzene ring, accelerated the cytotoxicity of AgNPs. Interestingly, none of the stabilizers tested, including biocompatible nonionic stabilizers (i.e., TW80 and cellulose) caused a reduction in AgNP toxicity. This showed that toxicity of AgNPs cannot be reduced using stabilizers.

시멘트계 고화재에 의해 혼합처리된 지반의 설계정수에 관한 연구 (A Study on the Design-parameter of Mixed Ground by Using Cement-type Stabilizer)

  • 천병식;임해식;전진규
    • 한국지반공학회논문집
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    • 제16권2호
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    • pp.79-89
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    • 2000
  • The application of stabilization method has increased because of short construction periods, no environmental problems with dumped and replaced soil, assurance of required strength and economical effect with mid to small size construction. The unconfined and triaxial(UU-condition) compression tests were executed with each mixing sample for the study of the improvement effects and the effect of design-parameters by the stabilization methods. Three typical stabilizers, which are representative in Korea, were applied in this study, and three common soils(very soft clay, general weathered soil, common clay), which are common in Korea, were used in this study. In this study, the effect of engineering factors(soils, stabilizers and water contents, etc.) which are important parameters for the improvement effects of mixed ground by stabilizers, was analyzed. As results, the tendencies of design-parameters(unconfined compression strength, deformation modulus and strength parameter) are presented and the criteria of the application of stabilization methods are suggested.

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약물상호작용 : 기분안정제와 항불안제 (Drug-Drug Interactions : Mood Stabilizers and Anti-Anxiety Drugs)

  • 김영훈;이정구
    • 생물정신의학
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    • 제7권1호
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    • pp.34-45
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    • 2000
  • Pharmacotherapy of bipolar disorder is a rapidly evolving field. Mood stabilizers and anticonvulsants have varying biochemical profiles which may predispose them to different adverse effects and drug-drug interactions. Several of the new anticonvulsants appear less likely to have the problems with drug-drug interaction. To provide more effective combination pharmacotherapies, clinicians should be allowed to anticipate and avoid pharmacokinetic and pharmacodynamic drug-drug interactions. We reviewed the role of cytochrome P450 isozymes in the metabolism of the drugs and their interactions. The drug-drug interactions of several classes of drugs which used as mood stabilizers and new anticonvulsants, some of which may have psychotropic profiles, are discussed mainly in this article. Finally, potential pharmacokinetic interactions between the benzodiazepines and other coadministered drugs are discussed briefly.

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