• Title/Summary/Keyword: sulfate resistance

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Effects of Admixture to Sulfate Attack Resistance of Cement Mortar (시멘트 모르타르의 황산염 침식 저항성에 대한 혼화재의 영향)

  • 형원길;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.704-709
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    • 2000
  • This study is to test effects of sulfate attack on deterioration of cement mortar. Four tests have been carried out with four types of mortars mixed by ordinary portland cement and sulfate-resistant portland cement containing blast-furnace slag and fly-ash. It was immersed in sulfate solution for 7, 28, 91, and 180 days. from the test results, sulfate attack resistance of cement mortar was improved by admixtures (blast-furnace slag and fly-ash), sulfate-resistance portland cement mortar showed high resistance than ordinarily portland cement at compressive strength, and similar the resistance of sulfate attack with ordinarily portland cement mortar with admixtures.

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Combustibility of Cellulose Insulation Treated with Boric acid-Borax-Aluminium sulfate Formulation (붕산-붕사-Aluminium sulfate 계 셀룰로오스 단열재의 연소특성 연구)

  • Kim, Hong;In, Se-Jin
    • Journal of the Korean Society of Safety
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    • v.7 no.4
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    • pp.7-12
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    • 1992
  • The smouldering combustibility of cellulose insulation treated with boric acid-borax-aluminium sulfate as combustion retardants are examined by cigarette ignition method and electrical cardrige heater method. The effectiveness of Aluminium sulfate as a third combustion are acceptable both smouldering resistance and flame resistance at 18% level of all examined formulation. As the proportion of Aluminium sulfate in the formulation was increased, the flame resistance of cellulose insulation was improved.

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Evaluation of Fineness Levels on the Sulfate Resistance of Cement Matrix with GGBS

  • Moon, H.Y.;Kim, S.S.;Lee, S.T.;Jung, H.S.;Kim, J.P.
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.1097-1100
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    • 2003
  • This paper describes the sulfate resistance of cement pastes and mortar with or without ground granulated blast furnace slag (GGBS). Sulfate attack was performed on the cement pastes and mortar, which had been prepared by using a water-binder ratio of 0.45. Variables were the fineness levels of GGBS and the concentrations of two sulfate solution. In this present study, compressive strength and length change were carried out to evaluate the sulfate resistance of GGBS with various fineness levels. From the test results, it can be concluded that the deterioration modes of cement matrix with GGBS were dependent on the exposure solutions. Moreover, the influence of fineness levels of GGBS on the sulfate resistance was somewhat little because of a relative short exposure period.

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Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.141-151
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    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Sea Water Resistance of the Concrte Deteriorated by Repeat of Immersing and Drying in Sea Water (해수의 건습반복 촉진열화에 따른 콘크리트의 내해수성)

  • 박춘근;김병권;최재웅;고만기
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.307-312
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    • 1997
  • The sea water resistance of cement and concrete must be compared when it used for construction in the ocean. The sea water resistance of the concrete specimens using three types of cements such as ordinary Portland cement, sulfate resistance Portland cement, blastfurnace slag cement were studied. In this study, an accelerated test for access sea water resistance by subjecting the concrete specimens to repeated cycles of concentrated sea water immersion and hot wind drying was employed. This study proved that sulfate resistance Portland cement had higher resistance for sea water.

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Influence of Mineral Admixtures on the Resistance to Sulfuric Acid and Sulfate Attack in Concrete (콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향)

  • Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.219-228
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    • 2010
  • It has been well known that concrete structures exposed to acid and sulfate environments such as sewer, sewage and wastewater, soil, groundwater, and seawater etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to concrete matrix by forming expansive hydration products due to the reaction between portland cement hydration products and acid and sulfate ions. Objectives of this experimental research are to investigate the effect of mineral admixtures on the resistance to acid and sulfate attack in concrete and to suggest high-resistance concrete mix against acid and sulfate attack. For this purpose, concretes specimens with three types of cement (ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC) composed of different types and proportions of admixtures) were prepared at water-biner ratios of 32% and 43%. The concrete specimens were immersed in fresh water, 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solutions for 28, 56, 91, 182, and 365 days, respectively. To evaluate the resistance to acid and sulfate for concrete specimens, visual appearance changes were observed and compressive strength ratios and mass change ratios were measured. It was observed from the test results that the resistance against sulfuric acid and sodium sulfate solutions of the concretes containing mineral admixtures were much better than that of OPC concrete, but in the case of magnesium sulfate solution the concretes containing mineral admixtures was less resistant than OPC concrete due to formation of magnesium silicate hydrate (M-S-H) which is non-cementitious.

Magnesium Sulfate Resistance of Concrete Containing Waste Glass (폐유리를 혼입한 콘크리트의 황산마그네슘 저항성에 관한 연구)

  • Kim, Young-Su;Jeong, Yoo-Jin;Lee, Dong-Un
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.3
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    • pp.109-116
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    • 2009
  • The magnesium sulfate solution digestion test carried out for resistance of concrete containing waste glass powder on magnesium sulfate attack. Moreover, it yielded S.D.F index was used for the criteria of quantitative assessment to the resistance of magnesium sulfate for the purpose of evaluation of chemical deterioration on concrete. Furthermore, to evaluate for micro-cracks within concrete and external corrosion, the weight variation of specimens and the dynamic elasticity were compared and analyzed and also the applicability was examined using the analysis of product of hydration through out observing external deformation and micro-structural deformation.

Resistance against Chloride Ion and Sulfate Attack of Cementless Concrete (무시멘트 콘크리트의 염소이온 침투 및 황산염 침투 저항성)

  • Lee, Hyun-Jin;Bae, Su-Ho;Kwon, Soon-Oh;Lee, Kwang-Myong;Jeon, Jun-Tai
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.2
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    • pp.63-69
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    • 2015
  • It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

A Study on the Sulfate Attack Resistance of Concrete Using EAF Slag as Fine Aggregate (전기로슬래그 잔골재를 사용한 콘크리트의 황산염침식 저항성에 관한 연구)

  • Park, Moon-Seok;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.1
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    • pp.81-87
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    • 2009
  • The purpose of this study is to investigate the sulfate attack resistance of concrete using the EAF(electric arc furnace) Slag as fine aggregate. In order to figure out the effects of magnesium sulfate solution on the durability of concrete using the EAF Slag as fine aggregate, the experiments for the immerging test in the 10% magnesium sulfate solution was executed by selecting factors such as aging processes, replacement ratio(0, 10, 20, 30, 50%), and duration of immerging. The specimens were made with various EAF slag replacements for fine aggregates and with W/C ratio fixed 0.45. compressive strength and S.D.F(Sulfate Deterioration Factor), weight change, and SEM(Scanning Electron Microscope) were tested. From the test results, EAF slag aggregate treated with accelerated aging is better than treated with air aging. The compressive strength and resistance to the sulfate attack is slightly improved with an increase in the EAF slag aggregate treated with accelerated aging replacement for aggregate.

A Fundamental Study on Sulfate Resistance of Inorganic Binder with High Acid Resistance (고내산성 무기바인더의 내황산성에 관한 기초적 특성 연구)

  • Choi, Jung-Gu;Lee, Gun-Cheol;Lee, Gun-Young;Ko, Dong-Guen;Gao, Shan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.11-12
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    • 2015
  • This study analyzed sulfate resistance of strongly acid-resistant inorganic binder based on industrial byproducts. According to the study experiment, compared to OPC mixture, the mixture of high acid-resistant inorganic binder had excellent chemical resistance against 10% H2SO4 solution. In the case of ordinary portland cement, its sample with 28 days of immersion had severe corrosion on its mortar erosion part, and thus external appearance was damaged greatly, and compression strength decreased by around 57% and more.

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