• Title/Summary/Keyword: trace element

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Evaluation of LA-ICP-MS Whole Rock Trace Element Analysis Using Fused Glass Bead of Silicate Rocks (규산염 암석의 알칼리 용융 유리원판에 대한 LA-ICP-MS 전암 미량원소 분석법 평가)

  • Kim, Myong Jung;Kim, Taehoon;Park, Kye-Hun;Lee, Ye Ji;Yang, Yun Seok;Moon, Jeongjin
    • The Journal of the Petrological Society of Korea
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    • v.24 no.2
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    • pp.141-147
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    • 2015
  • Using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we evaluated the reliability of trace element abundance data measured from the silicate rock references of JR-3, JG-3, JGb-1 and JB-1b using glass discs made by alkali fusion. For 28 elements including rare earth elements, relative standard deviations (RSD) are better than 7% in case when the concentrations of the elements in the rock samples are greater than 10 ppm. However, RSD shows somewhat increased values for the concentrations less than 10 ppm, but never exceeds 25%. Compared with previously reported averages of the compiled abundance data, our data display satisfactory results for the most cases with differences less than 10%. We suggest that LA-ICP-MS analysis using fused glass beads is a reliable, precise and time-saving method of trace element analysis for the silicate rocks spanning from mafic to felsic compositions.

Association between Trace Element and Heavy Metal Levels in Hair and Nail with Prostate Cancer

  • Karimi, Golgis;Shahar, Suzana;Homayouni, Nasim;Rajikan, Roslee;Bakar, Nor Faizah Abu;Othman, Mohd Sham
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.9
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    • pp.4249-4253
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    • 2012
  • While associations between trace elements and heavy metals with prostate cancer are still debatable, they have been considered as risk factors for prostate cancer. Thus, this study aimed to detect any links between selected minerals and heavy metals including Se, Zn, Cu, Mn and Fe with prostate cancer. A case control study was carried out among 100 subjects (case n=50, control n=50), matched for age and ethnicity. Trace elements and heavy metals level in hair and nail samples were determined by ICP-MS. Mean selenium levels in hair and nail of the cases were significantly lower as compared to controls. A similar trend was noted for zinc in both hair and nail samples, whereas the mean level of copper was significantly higher in cases than controls. Similar elevation was noted for iron and manganese (p<0.05 for all parameters). Low levels of selenium and zinc and high levels of copper, iron and manganese appear to be associated with the risk of prostate cancer. Further studies to elucidate the causal mechanisms and appropriate chemopreventive measures are needed.

Levels of Serum Trace Elements in Renal Cell Carcinoma Cases

  • Pirincci, Necip;Gecit, Ilhan;Gunes, Mustafa;Kaba, Mehmet;Tanik, Serhat;Yuksel, Mehmet Bilgehan;Arslan, Harun;Demir, Halit
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.1
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    • pp.499-502
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    • 2013
  • Trace elements which are essential components of biological structures may also be toxic when present at levels above the amounts required for biological function. In our study, trace element levels were measured with furnace atomic absorption spectrophotometry in 33 newly diagnosed renal cell carcinoma cases (preoperative) and 32 healthy controls. When compared with the control group, it was found that the levels of cadmium (Cd), lead (Pb) were higher and the levels of zinc (Zn), iron (Fe) and manganese (Mn) were lower in the patient group. These changes may be important in the formation of renal cell carcinoma, a question which should be explored with postoperative comparative studies.

Elemental Analysis of herbal medicine, Foundry Air and Hair for the Study of Human Surroundings (인체 환경 연구를 위한 한약재, 작업장 공기 및 모발의 원소분석)

  • 강상훈;이상순;조승연;정용삼
    • Journal of Environmental Health Sciences
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    • v.28 no.3
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    • pp.64-71
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    • 2002
  • Hair provides important information about the body's mineral status. Therefore, we have studied the trace elemental distribution in human hair under different inhalation and ingestion environment using neutron activation analysis (NAA). NAA is a powerful analytical method which can be used successfully to determine trace elements in environmental and biological materials. Total diet and six different herbal medicine were analysed to study ingestion environment. Airborne dust in foundry was analysed and compared with outdoor dust to study inhalation environment. Human hairs of common person, herbal medicine taker and foundry worker were analysed to estimate the trace elemental distribution of people under different inhalation and ingestion environment. Analytical results show that herbal medicines contain higher micronutrients such as Ca, Mg, Mn and Cu that total diet and airborne dust in foundry has high Cr. The concentration of Ca, Mg and Mn in hair of herbal medicine taker is two times higher than in hair of common person and Cr con-centration in hair of foundry worker is about three times higher than in hair of common person. These results show that NAA can be used importantly to monitor human health through biological and environmental samples.

A post-peak analysis of concrete structures using a 9-node assumed strain shell element (9절점 가변형도 쉘요소를 이용한 콘크리트 구조물의 후-정점하중 해석)

  • 이상진;이홍표;서정문
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.10a
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    • pp.59-66
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    • 2001
  • The post-peak analysis of concrete structures is carried out using a nine-node Reissner-Mindlin(RM) shell element which is formulated by using degenerated solid concepts. In order to avoid element deficiencies inherited in the standard RM shell element, assumed strains are adopted in the present shell element. A microscopic material model is adopted to represent the inelastic characteristic of concrete material. In particular, a concrete softening model is introduced to this material model. The arc-length control method is used to trace the post-peak behaviour of concrete structures. From the numerical test of the single-edge-notched beam, the present shell element shows a reasonable agreement with experimental data.

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AN UPSTREAM PSEUDOSTRESS-VELOCITY MIXED FORMULATION FOR THE OSEEN EQUATIONS

  • Park, Eun-Jae;Seo, Boyoon
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.1
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    • pp.267-285
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    • 2014
  • An upstream scheme based on the pseudostress-velocity mixed formulation is studied to solve convection-dominated Oseen equations. Lagrange multipliers are introduced to treat the trace-free constraint and the lowest order Raviart-Thomas finite element space on rectangular mesh is used. Error analysis for several quantities of interest is given. Particularly, first-order convergence in $L^2$ norm for the velocity is proved. Finally, numerical experiments for various cases are presented to show the efficiency of this method.

A NONCONFORMING PRIMAL MIXED FINITE ELEMENT METHOD FOR THE STOKES EQUATIONS

  • Cho, Sungmin;Park, Eun-Jae
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.6
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    • pp.1655-1668
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    • 2014
  • In this article, we propose and analyze a new nonconforming primal mixed finite element method for the stationary Stokes equations. The approximation is based on the pseudostress-velocity formulation. The incompressibility condition is used to eliminate the pressure variable in terms of trace-free pseudostress. The pressure is then computed from a simple post-processing technique. Unique solvability and optimal convergence are proved. Numerical examples are given to illustrate the performance of the method.

Nonlinear Static Analysis of Cable Roof Structures with Unified Kinematic Description

  • LEE, Sang Jin
    • Architectural research
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    • v.18 no.1
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    • pp.39-47
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    • 2016
  • A finite element analysis technology applicable to the prediction of the static nonlinear response of cable roof structure is presented. The unified kinematic description is employed to formulate the present cable element and different strain definitions such as Green-Lagrange strain, Biot strain and Hencky strain can be adopted. The Newton-Raphson method is used to trace the nonlinear load-displacement path. In the iteration process, the compressive stress of a cable element is not allowed. For the verification of the present cable element, four numerical examples are tackled. Finally, numerical results obtained by using the present cable element are provided as new benchmark test results for cable structures under static loads.

An element-based 9-node resultant shell element for large deformation analysis of laminated composite plates and shells

  • Han, S.C.;Kim, K.D.;Kanok-Nukulchai, W.
    • Structural Engineering and Mechanics
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    • v.18 no.6
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    • pp.807-829
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    • 2004
  • The Element-Based Lagrangian Formulation of a 9-node resultant-stress shell element is presented for the isotropic and anisotropic composite material. The effect of the coupling term between the bending strain and displacement has been investigated in the warping problem. The strains, stresses and constitutive equations based on the natural co-ordinate have been used throughout the Element-Based Lagrangian Formulation of the present shell element which offers an advantage of easy implementation compared with the traditional Lagrangian Formulation. The element is free of both membrane and shear locking behavior by using the assumed natural strain method such that the element performs very well in thin shell problems. In composite plates and shells, the transverse shear stiffness is defined by an equilibrium approach instead of using the shear correction factor. The arc-length control method is used to trace complex equilibrium paths in thin shell applications. Several numerical analyses are presented and discussed in order to investigate the capabilities of the present shell element. The results showed very good agreement compared with well-established formulations in the literature.

Geometrically Nonlinear Analysis of Hinged Cylindrical Laminated Composite Shells (활절로 지지된 원통형 적층복합쉘의 기하학적 비선형 해석)

  • Han, Sung-Cheon
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.3 no.2
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    • pp.1-10
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    • 2012
  • In the present study, an Element-Based Lagrangian Formulation for the nonlinear analysis of shell structures is presented. The strains, stresses and constitutive equations based on the natural co-ordinate have been used throughout the Element-Based Lagrangian Formulation of the present shell element which offers an advantage of easy implementation compared with the traditional Lagrangian Formulation. The Element-Based Lagrangian Formulation of a 9-node resultant-stress shell element is presented for the anisotropic composite material. The element is free of both membrane and shear locking behavior by using the assumed natural strain method such that the element performs very well in thin shell problems. The arc-length control method is used to trace complex equilibrium paths in thin shell applications. Numerical examples for laminated composite curved shells presented herein clearly show the validity of the present approach and the accuracy of the developed shell element.