• 한국염색가공학회지
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• 제19권5호
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• pp.17-23
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• 2007

As polyvinyl alcohol(PVA) filament yarn is commercially used in many fields due to its high strength and modulus properties. This research was carried out to study the dyeing behavior of PVA and to find out appropriate dye for better dyeing. As the dyeing behavior of PVA fiber is similar to cellulose due to the same functional group, reactive and vat dyes were selected for the dyeing. Color strength of PVA fibers treated with vat dyes was found to be better than those with reactive dyes, because of the low fixation of reactive dye on fibers. Most of the reactive dye may became hydrolyzed, and flushed away with water in washing. Colorfastness to laundering was shown to be very high for both of the reactive-dyed and vat-dyed PVA fibers.

• 한국의류학회지
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• 제34권12호
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• pp.1933-1946
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• 2010

This paper is a comparative analysis of the $19^{th}$ century practice of indigo dyes and dyeing in Korea and England. From over hundreds species of indigo plants in the world, it was dyer's knotweed and woad that were cultivated in Korea; however, the only indigo plant grown in England was woad. Indigo dye was produced in the form of damp indigo sediment (jeon) in Korea; however, imported indigo (as a main dye) and couched woad (as an additional dye) were indigo dyes used in England. There existed three kinds of indigo vats, the ice vat, ash-water vat, and indigo sediment (jeon) vat, in Korea. The fresh leaves of indigo were used for both the ice vat and ash-water vat. The ice vat was very convenient for preparation, but had a weakness in the inability to produce a very deep shade of blue. The ash-water vat and indigo sediment (jeon) vat were in use for producing a very deep shade of blue. The indigo sediment Goon) vat was employed presumably only by professional dyers. The indigo vat practiced in England was categorized into two types; one was woad-indigo vat, and the other was an indigo powder vat prepared by using imported indigo rock. There was a tendency to adopt different kinds of indigo vats according to the material to be dyed. The woad-indigo vat was employed for the dyeing of wool. A few of chemical vats with imported indigo were adopted, especially for the dyeing of cotton. Indigo dyers in 19th century Korea were differentiated from the rest of the dyers. They managed the growing of indigo plants as well as the production of indigo sediment (jeon). Woad dyers in 19th century England handled woolen cloth as well as worsted and woolen yarn in general. However, they sometimes dyed silk skein as well. They produced several colors such as black, blue, slates, grays, by using both woad and imported indigo.

• 한국산학기술학회논문지
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• 제21권12호
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• pp.23-32
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• 2020

본 연구는 PTT에 vat 염료의 염색성을 살펴보고, vat 염료로 염색된 PTT의 취화거동 및 퇴색거동을 연구하였다. PTT 소재에 vat 염료의 염착을 개선하기 위하여 pad-steam 법을 응용하였으며, 염색 중에 산 처리 효과를 살펴보았다. 염색 과정에서 산 처리는 vat 염료의 입자 크기를 작게 만들어 소재 내부 침투를 용이하게 하고 염료의 과환원을 방지하여 염색성을 향상시켰다. 여기에 pad-steam 염색법은 일반적인 침염법보다 염료의낯 고착성을 증가시켜 균염을 개선하였다. Vat 염료로 염색된 PTT의 취화와 퇴색거동은 열과 자외선에 일정시간 동안 노출시킨 후 인장강도와 K/S 값으로 분석하였다. 열과 자외선의 온도가 올라갈수록, 또 노출 시간이 증가할수록 시료의 인장강도 저하되었으나, 이러한 취화 속도는 산화방지제와 함께 분산염료로 염색된 시료보다 더 느리게 나타나서 향상된 거동을 보였다. 퇴색거동 역시 vat 염료로 염색된 시료가 자외선흡수제가 포함되고 분산염료로 염색된 시료보다 훨씬 뛰어난 특징을 나타냈다. 결과적으로 vat 염료는 pad-steam 법으로 PTT 소재에 효과적으로 적용시킬 수 있으며, 이때의 내열성과 내광성은 우수하게 나타났다.

• 한국염색가공학회지
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• 제22권2호
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• pp.88-93
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• 2010

Using extracted sepia melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions, vat dyeing of wool and cotton fabrics was carried out under various dyeing conditions including concentration of melanin, alkali, reducing agent and salt, as well as dyeing time and temperature. A K/S of 25.3 for wool fabrics was obtained at the optimal dyeing condition with 9% owf melanin, 0.5g/L NaOH and 56g/L $Na_2S_2O_4$ without salt at $80^{\circ}C$ for 90minutes. The vat dyeing of sepia melanin was applicable to both cotton and wool fabrics but the wool showed higher dyeability. The color fastness properties of the dyed wool and cotton fabrics were excellent to washing, rubbing and light irradiation.

• 한국염색가공학회지
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• 제15권3호
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• pp.168-175
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• 2003

Ultramicrofiber(UMF) PET knitted fabric and regular PET plain woven fabric as reference sample were impregnated with waterborne polyurethane(PU) in a two-step process with dyeing/PU treatment and PU treatment/dyeing to investigate the effect of the treatment sequence. The waterborne PU impregnated fabrics were dyed with two kinds of vat and disperse dyes to investigate the dyeing properties and the dyeing fastnesses. In vat dyeing the rank of color strength(K/S) was in order of dyeing/PU impregnation > dyeing only > PU impregnation/dyeing, whereas in case of disperse dyeing, the order was dyeing/PU impregnation > PU impregnation/dyeing >dyeing only. Wash fastness of vat dyeing showed a higher 2-3 grade than disperse dyeing, while rubbing and light fastnesses were not good for disperse dyes.

• 한국염색가공학회지
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• 제17권6호
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• pp.11-19
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• 2005

Textile dyeing with vat dyes has the highest color fastness although one and the same dye of all vat dyes cannot always satisfy every color fastness requirement. So we examined cotton, nylon 6, and polyester fabrics dyed with vat dyes. Cotton, nylon 6 and polyester fabrics were dyed with vat dyes such as C. I. Vat Blue 1, Blue 19, Black 9, Green 1, Orange 2, and Violet 1 containing sodium hydrosulfite and NaOH. Oxidation were carried out by a sodium peroxoborate after dyeing. The dyed materials were soaped at the boil after oxidation. Especially hydrolysis and overreduction for dyed polyester with vats dyes containing -NHCO- and -NH- groups such as C. I. Vat Blue 6, Black 25, Black 27, Red 10, and Green 3 occurred. It seems that these phenomena are due to a high dyeing temperature. Wash and rubbing fastness of nylon are higher than that of cotton and polyester. Light fastness of cotton is higher than that of polyester and nylon.

• 한국염색가공학회지
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• 제13권5호
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• pp.41-41
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• 2001

In this study, synthetic fiber fabrics such as polyester, nylon 6, acrylic and acetate were dyed with indigoid vat dye. The effects of the composition of alkaline reduction, dyeing time and dyeing temperature on color strength and color fastness of the fabrics were investigated. Also the color fastnesses to wash and light of the dyed fabrics were studied. In dyeing of polyester, nylon, acrylic and acetate fiber fabrics with indigo vat dyes, it appears that these fabrics have high values of K/S up to Ig/L of sodium hydroxide and 6g/L of reducing agent. Indigo vat dyeing for synthetic fiber fabrics was verb fast, and lead to dyeing equilibrium within twenty minutes. The K/S values of dyed fabrics did not changed in dye concentration more than 10% o.w.f.. Synthetic fiber fabrics dyed with indigoid dyes had bad light fastness.

• 한국염색가공학회지
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• 제13권5호
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• pp.329-335
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• 2001

In this study, synthetic fiber fabrics such as polyester, nylon 6, acrylic and acetate were dyed with indigoid vat dye. The effects of the composition of alkaline reduction, dyeing time and dyeing temperature on color strength and color fastness of the fabrics were investigated. Also the color fastnesses to wash and light of the dyed fabrics were studied. In dyeing of polyester, nylon, acrylic and acetate fiber fabrics with indigo vat dyes, it appears that these fabrics have high values of K/S up to Ig/L of sodium hydroxide and 6g/L of reducing agent. Indigo vat dyeing for synthetic fiber fabrics was verb fast, and lead to dyeing equilibrium within twenty minutes. The K/S values of dyed fabrics did not changed in dye concentration more than 10% o.w.f.. Synthetic fiber fabrics dyed with indigoid dyes had bad light fastness.

• 한국염색가공학회지
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• 제15권6호
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• pp.1-7
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• 2003

Polyester microfiber has usually greater dye uptake than normal denier polyester fiber in same dyeing condition. In spite of this high dye uptake dyed microfiber fabric has not only low visual colour depth but also poor washing fastness property. In order to study high colouring dyeing technology and high washing fastness of polyester microfiber, dyeing property of polyester microfiber was investigated according to the dye solubility and particle size of used disperse dyes in aqueous dye solution. After disperse dyeing, dyed fabric with disperse dye was redyed with a vat dye without reduction clearing in order to obtain a high washing fastness property. The result were as followings ; A small particle sized disperse dyes such as C. I. Disperse Blue 56 and Red 60 showed high rate of initial exhaution compared with a large particle sized disperse dyes like C. I. Disperse Blue 165 and Red 343. In study of dyeing property of polyester microfiber with C. I. Vat Blue 1, polyester microfiber could achieve high dye uptake at a given optimum vatting process conditions. On the other hand, in consecutive dyeing with disperse and vat dye, K/S value of polyester microfiber with a small particle sized disperse dye increased without reduction clearings, but K/S value of polyester microfiber with a large particle sized disperse dye decreased with reduction clearings.

• Fibers and Polymers
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• 제7권2호
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• pp.164-168
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• 2006

Three vat dyes have been applied to regular viscose rayon and their dyeing and wash fastness properties were evaluated. Particle size determination was undertaken to obtain information about the size of dye particles converted by a reducing agent, to see if dye particle size has an affect on dyeing properties of regular viscose rayon. It is observed that viscose rayon exhibits more dyeability with reducing agent concentrations between 5-7.5 g/l. Also, we found that the vat dyeing system is greatly affected by the particle size of the vat dye converted to leuco form by a reducing agent.