• Journal of Industrial Technology
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• v.22 no.B
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• pp.13-20
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• 2002

The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in uncoated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.1
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• pp.13-20
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• 2008

The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in un-coated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

• Proceedings of the KSR Conference
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• 2004.10a
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• pp.988-993
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• 2004

This paper considers corrosion problems in the bolt connection of weathering steel box girder bridge using the external electric type corrosion resistance method which resisted to local corrosion in coated steel surface with contacted air. The weathering steel was created a rust itself in the passive state. but a coated box girder type was easily dew form could be made galvanic cell that accelerated corrosion. so that it was ruled by protection coat with some paint. Therefore, it needed that can be applied the external electric type corrosion resistance method in coated surface. As a result of the test of polarization amount had measured that the weathering steel was higher currents than the general steel by about $5\~10\%$. Therefore. an external electric type corrosion resistance method can be used to protect local corrosion in the coated bolt connection of weathering steel box girders effectively.

• Journal of Korean Society of Steel Construction
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• v.15 no.2
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• pp.147-157
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• 2003

The application in steel structures is increasing the mill sheet for the weathering steels by minimum maintenance cost in a life cycle cost. These have been collected and statistically analyzed to investigate chemical compositions, mechanical properties, weldability indices, weathering index and impact absorbed energy. From this study, although the band of dispersion in chernical compositions, mechanical properties and impact absorbed energy of the weathering steels appeared a little larger, the results revealed that these values have adequately satisfied the standard values of the Korean Standard. Furthermore, it was found that the weldability indices and the weathering index for the weathering steels have respectively satisfied the value prescribed by the Japanese Highway Specification and ASTM.

• Journal of Korean Society of Steel Construction
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• v.20 no.5
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• pp.591-599
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• 2008

Weathering steel has been widely used in bridges and cladding materials due to its superior atmospheric corrosion resistance. Actually, weathering steel has often been used in Korea as cladding material. However, the performance of the weathering steel in claddings has not been fully monitored. We conducted a field study on the performance of weathering steels and measured the quantity of corrosion loss on the weathering steel claddings in Korea. Based on the measured corrosion loss and weather (environmental) data, the equation to predict corrosion loss of weathering steels was proposed by using environmental factors in KIHO region in Korea. The proposed equation predicted very well the real corrosion losses of KIHO region.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.119-124
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• 2008

Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.

• Journal of Welding and Joining
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• v.18 no.3
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• pp.97-105
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• 2000

The stress corrosion cracking(SCC) and hydrogen embrittlement cracking(HEC) characteristics of a weathering steel weldment were investigated in aerated acid-chloride solution. The electrochemical properties of weldment were investigated by polarization test and galvanic corrosion test. Weathering steel did not show passive behavior in the acid-chloride solution. Galvanic corrosion between the weld metal and the base metal was not observed because the base metal was anodic to the weld metal. The slow-strain-rate tests(SSRT0 were conducted at a constant strain rate o 7.87×{TEX}$10^{-7}${/TEX}/s at corrosion potential, and at potentiostatically controlled anodic and cathodic potentials. The weldment of weathering steel was susceptible to both anodic dissolution SCC and hydrogen evolution HEC.

• Corrosion Science and Technology
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• v.4 no.4
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• pp.121-129
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• 2005

Basic design concept of the future steel structure requires environmental compatibility and maintenance free capability to minimize economic burdens. Recent trends in alloy design for advanced weathering steel include addition of various alloying elements which can enhance formation of stable and protective rust layer even in polluted urban and/or high $Cl^{-}$ environment. The effects of Ca, Ni, W, and Mo addition on the corrosion property of Ca-modified weathering steel were evaluated through a series of electrochemical tests (pH measurement and electrochemical impedance spectroscopy: EIS) and structural analysis on rust layer formed on the steel surface. Ca-containing inclusions of Ca-Al-Mn-O-S compound are formed if the amount of Ca addition is over 25 ppm. Steels with higher Ca content results in higher pH value for condensed water film formed on the steel surface, however, addition of Ni, W, and Mo does not affect pH value of the thin water film. The steels containing a high amount of Ca, Ni, W and Mo showed a dense and compact rust layer with enhanced amount of ${\alpha}-FeOOH$. Addition of Ni, W and Mo in Ca-modified weathering steel shows anion-selectivity and contributes to lower the permeability of $Cl^{-}$ ions. Effect of each alloying element on the formation of protective rust layer will be discussed in detail with respect to corrosion resistance.

• Corrosion Science and Technology
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• v.2 no.4
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• pp.183-188
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• 2003

Corrosion of carbon and weathering steels were evaluated under 3 environmental exposures in Thailand (urban, rural and marine) for a year. The seasonal study was designed to determine different corrosion mechanisms by 6 months of dry season and 6 months of rainy season in a year. The sheltered exposure racks were used to determine the washing effect of min. At each site, climatic and pollutants analyses were carried out. The present study showed that the difference in corrosion rates of carbon and weathering steels was not so distinguished in both rural (AIT) and urban (TISTR) environments. The corrosion rate of weathering steel was somewhat lower than that of carbon steel and the decreasing tendency of corrosion rate with time was slightly higher for weathering steel than for carbon steel. In marine (Rayong) environment, the corrosion rate was higher and the effect of wet and dry seasons was observed. The corrosion rate in 6 dry months was higher for direct exposure than for sheltered exposure. However, in 6 rainy months. the corrosion rate of sheltered exposure was higher than that of direct exposure. In direct exposure for I year, that is, the first 6 dry months and the next 6 rainy months, the corrosion rate decreased with time. but in sheltered exposure, the corrosion rate did not decrease with time. instead, increased in the next 6 rainy months. This indicated that the protect ive layer formed in the first 6 dry months could be destroyed by high deposition of chloride to r sheltered exposure in the next 6 rainy months; whereas the rust layer for direct exposure could be kept sound due to washing effect in rainy season, even though the deposition rate of chloride was almost the same for direct and sheltered exposures. In marine environment, the weathering steel showed higher corrosion resistance than carbon steel but its corrosion rate was higher than those in other environments.

• Journal of Korean Society of Steel Construction
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• v.16 no.4 s.71
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• pp.415-423
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• 2004

To investigate the long-term corrosion resistance of an uncoated weathering steel, an important outdoor constructional steel material, skyward surfaces of the weathering steel and a control steel initially exposed to rural and industrial atmospheres for 9 years were electrochemically tested in neutral artificial rain in terms of electrochemical potentials, impedances, and anodic potentiodynamic polarization curves. Their results were then discussed. A quite passive and stable rust layer to the artificial rain was well formed on the skyward surface of the weathering steel exposed to the industrial and rural atmospheres, and its corrosion rate in the artificial rain was measured to be about a low $3{{\mu}m}/y$. Continuous immersion of all the weathered surfaces in the artificial rain revealed the gradual degradation of the weathered corrosion layers on the steel, resulting in a cathodically controlled corrosion of the substrate steel by the electrochemical measurements. Alloy components of the weathering steel were found to retard the degradation of the weathered corrosion layers on the steel in the artificial rain. For better corrosion evaluation of the weathering steel, more electrochemical measurements of surfaces that have been exposed for more than 9 years to more closely simulated atmospheric waters are needed. These measurements are almost non-destructive and can provide online and in situ information on the corrosion rate, the development of corrosion and the conditions of rust layers on any interested surface and at any exposure time of the steel, so they can be effectively applicable to the corrosion evaluation of steel structures such as bridges, towers, and architectures by forming an electrochemical cell on an interested structural surface and by using a portable electrochemical instrument.