Effects of $TiB_{2},ZrB_{2}$ and Sintering Temperature on SiC Composites Manufactured by Pressureless Sintering

상압소결법에 의해 제조한 SiC 복합체의 특성에 미치는 $TiB_{2},ZrB_{2}$와 소결온도의 영향

  • 주진영 (원광대학교 전기전자 및 정보공학부) ;
  • 박미림 (원광대학교 전기전자 및 정보공학부) ;
  • 신용덕 (원광대학교 전기전자 및 정보공학부) ;
  • 임승혁 (성균관대학교 전기전자 및 컴퓨터공학부)
  • Published : 2001.07.01

Abstract

The $\beta$-SiC+ZrB$_2$ and $\beta$-SiC+TiB$_2$ceramic electroconductive composites were pressureless-sintered and annealed by adding l2wt% A1$_2$ $O_3$+Y$_2$ $O_3$(6 : 4wt%) powder as a function of sintering temperature. The relative density showed highest value of 84.92% of the theoretical density for SiC-TiB$_2$ at 190$0^{\circ}C$ sintering temperature. The phase analysis of the composites by XRD revealed of $\alpha$-SiC(6H), TiB$_2$, $Al_{5}$Y$_2$ $O_{12}$ and $\beta$-SiC(15R). Flexural strength showed the highest of 230 MPa for SiC-ZrB$_2$ composites sintered at 190$0^{\circ}C$. The vicker's hardness increased with increasing sintering temperature and showed the highest for SiC-ZrB$_2$ composites sintered at 190$0^{\circ}C$. Owing to YAG, the fracture toughness showed the highest of 6.50 MPa . m$^{1}$2/ for SiC-ZrB$_2$ composites at 190$0^{\circ}C$. The electrical resistivity was measured by the Rauw method from $25^{\circ}C$ to $700^{\circ}C$. The electrical resistivity of the composites showed the PTCR(Positive Temperature Coefficient Resistivity).).

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