Studies on Hexagonal Ferrite (III) Coprecipitation-Method Preparation of Ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$ and Its magnetic Properties

Hexagonal Ferrite에 관한 연구 (III) 공침법에 의한 Ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$의 합성과 그 자성

  • Published : 1979.02.01

Abstract

In order to prepare ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$, which would be useful for GHz-band communication, the optimum coprecipitation condition of 1 $BaCl_{2-1} Zn(NO_3)_2-6FeCl_3$ in $NaOH-Na_2CO_3$ solution was investigated by use of a new apparatus invented in our laboratory. By freeze-drying and calcining the coprecitated hydroxide-carbonate, the very reactive powder was obtained, from which the synthesis process of ZnY and the other related crystals were investigated by means of X-ray diffraction. In results, it was found that the reactive powder containing ZnY as the major component can be prepared by this method, which may be used in manufacturing the various magnetic cores for the microwave communication.

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References

  1. Philips Tech. Rev v.18 no.6 Ferroxplana Hexagonal Ferromagnetic Iron-Oxide Compound for Very High Friequencies G.H. Jonker;H.P. Wijn;P.B. Braun
  2. Philips Res, Rep v.12 The Crystal Structures of a New Group of Ferromagnatic Compounds P.B. Braun
  3. J. Korean Cer. Soc v.13 no.3 Hexagonal Ferrite에 관한 硏究(Ⅰ),Ferroxplana $Zn_{1-x}\;MnxY\;(Ba_2Zn_{2(1-x)}\;Mn_{2x}Fe_{12}O_{22}$의 磁性 金泰玉
  4. Tokin Tech. Rev v.7 no.1 Devlopement of Electromagnetic Wave Absorber by use of Y-type Ferroxplana T. Yamamoto;M. Kikuchi;S. Hikichi;S. Otsuki
  5. J. Korean cer. Soc v.13 no.4 Hexagonal Ferrite에 관한 硏究(Ⅱ), Ferroxplana $Co_{1-x}\;Zn_xZ\;(Ba_2Co_{2(1-x)}Zn_{2x}Fe_{24}O_{41})$ Magnetostriction 金泰玉
  6. Proc. of I.C.F The Application of Ferroxplana Single Crystal to VTR Head T. Iwasawa;H. Abe
  7. ibid Crystal Growth of Hexagonal Ferrite and its Magnetic Characteristic S. Shinoyama;Y. Sucmune
  8. J. amer. Cer. Soc v.47 no.1 Growth and Properties of Single Crystals of Hexagonal Ferrite R.O. Savage;A. Tauer
  9. J. Appl. Phys v.35 no.3 Improvement of the Ferromagnetic Resonance Line Width of Single Crystal ZnY by New Growth Technique A. Tauer;S. Dixon
  10. ibid v.37 no.7 Growth of Hexagonal Ferrite Crystal by Modified Pulling Techniques T.R. Aucoin;R.O. Savage
  11. Philips Tech, Rev v.19 no.7-8 Crystal-Oriented Ferroxplana A.L. Stuijts;H.P.J. Wijn
  12. 日本 電信電話 硏究所 硏究實用化報告 v.21 no.11 Growth and Magnetic Charteristics of ZnY Single Crystals S. Shinoyama
  13. Magnetic Properties of Some Ferroxplana Single Crystals J. Verweel
  14. Soviet Physics Solid State v.9 no.8 Magneto-ㅊrystalline Anisotropy of Hexagonal Ferrite Single crystal of the System $Ba_2CoxZn_{2-x}Fe_{12}O_{22}$ N.N. Agapova;T.M. Perekalia
  15. 最近の高透磁率フェライト(3) v.2 no.2 富永 匡昭
  16. Amer. Cer, Soc v.60 no.1-2 Effect of Poristy and Grain Size on the Magnetic Properties of Ni-Zn Ferrites H. Iganashi;K. Okazaki
  17. Amer. Cer, Soc v.57 no.8 Preparation of High-Coercivity Ba₂Fe₁₂O19 K. Haneka;C. Miyakawa;H. Kojima
  18. 電氣化學(日本) v.44 no.2 濕式法によるバリウムフェライトの合成と磁機特性 吳在熙;山崎陽太郞;佐藤實
  19. 分析化學 朴斗元;朴永圭
  20. J. Am. Chem, Soc v.69 M. Erchak;Jr.I. Frankuchen;R. Ward
  21. 釜山大學校 附設 臨海地域開發硏究院 生産技術硏究所 硏究報告 v.18 Zn Y(Ba₂Zn₂Fe₁₂O₂₂) 單結晶의 磁정 金泰玉