The Effect of Silicon-Alloying on the Characteristics of the Pyrolytic Carbonds Deposited in Tumbling Bed by CVD

Tumbling Bed에서 화학증착법에 의해 증착되는 열분해탄소의 특성에 미치는 Silicon-Alloying의 효과

  • 윤영진 (한국과학기술원 재료공학과) ;
  • 이재영 (한국과학기술원 재료공학과)
  • Published : 1983.02.01

Abstract

In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.

Keywords

References

  1. Chemistry and Physics of Carbon v.1 H. B. Palmer;C. F. Cullis;P. L. Walker, Jr.(ed.)
  2. Carbon v.10 Carbon-An Old but New Materials P. L. Walker, Jr.
  3. AFRDL-TR-74-15 v.1 Interim Report for Perid Dec. 1972-Jan. 1974 Martin C. Hughes;Joseph P. Copeland;Richard H. Singleton;Kenneth E. Undercoffer
  4. Carbon v.15 Biomedical applications of carbon fibre reinforced carbon in implanted prosthese Gywn M. Genkins
  5. Muel. Sci. Eng. v.20 Development and utilization of pyrolytic-carbon-coated carbide fuel for the high-temperature gas-codled reactor W. V. Gooddel
  6. Electro-chem-Tech v.5 Low density pyrolytic-carbon coatings for nuclear fule particles B. Geutler;Rl L. Beatty
  7. Chemistry and Physics of Carbon v.5 J. C. Bokios;P. L. Walker, Jr.(ed.)
  8. Carbon v.15 Carbon biomedical devices J. C. Bokros
  9. KAIST Thesis Study on the process development and the charateristics of pyrolytic carbon-Effects of concentration and bed area Jung-Ho Je
  10. KAIST Thesis Study on the process development and the characteristics of pyrolytic carbon Woo-Seok Ryu
  11. ORNL-TM-1649 Pyrolytic carbon deposited from propane in a fluidized bed Ronald Lee Beatty
  12. J. Am. Cer. Soc. v.54 Structure and mechanical properties of codeposited pyrolytic C-SiC alloys J. L. Kaae;T. D. Gulden
  13. J. Am. Cer. Soc. v.51 Deposition and microstructure of vapor-deposited silicon carbide T. D. Gulden
  14. Carbon v.4 Structure and properties of pyrolytic carbons prepared in a fluidized bed between 1900 and 2400°C R. J. Price;J. C. Bokros;K. Koyama;J. Chin
  15. Carbon v.12 The deposition of pure and alloyed isotropic carbons in steady-state fluidized beds R. J. Akins;J. C. Bokros
  16. Nucl. Tech. v.35 Transmission electron microscopy of pyrocarbon coatings E. Pollmann;J. Pelissier;C. S. Yust;J. L. Kaae
  17. Carbon v.3 Variation in the crystallinity of carbons deposited in fluidized beds J. C. Bokros
  18. J. Chim. Phys. v.57 The deposition of pyrolytic graphite R. J. Diffendorf
  19. Carbon v.12 The influence of chlorine on the formation and properties pyrolytic carbon C. F. Cullis;A. C. Norris