A Study on the Initial Stage of Sintering and the Grain Growth of ZnO in ZnO-Bi2O3 System

ZnO-Bi2O3계의 소결초기단계와 입자성장에 관한 연구

  • 성건용 (한국과학기술원 재료공학과) ;
  • 강을손 (한국과학기술원 재료공학과) ;
  • 김종희 (한국과학기술원 재료공학과)
  • Published : 1989.04.01

Abstract

The sintering behavior and grain growth of ZnO in 99.0mol% ZnO-1.0mol% Bi2O3 which are the basic compositions of ZnO varistor were studied. The microstructrual observation confirmed that the final sintered density was mainly determined at the initial stage of sintering, i.e. grain rearrangement and grain growth which were induced by the penetration of eutectic melts formed at eutectic temperature(74$0^{\circ}C$). But when the liquid penetration was terminated, the grain growth did not promote further densification. Activation energy of the grain growth of ZnO in the system of 99.0mol% ZnO-1.0mol% Bi2O3 was 44.8$\pm$1.8Kcal/mol.

Keywords

References

  1. Advances in Ceramics;Grain Boundary Phenomena in Electronic Ceramics v.1 Propreties of Multilayer ZnO Ceramic Varistors N.Shohata;T.Matsumura;K.Utsumi;T.Ohno;L.M. Levinson(ed.)
  2. Jpn. J. Appl. Phys. v.22 no.1 Thin-film Bulk type ZnO Varistor Fabricated by RF Sputtering K. Eda;H. Eguchi;H. Okinaka;M. Matsuoka
  3. Low-Voltage Varistors B. Hoffman;U. Schwing
  4. J. Appl. Phys. v.51 no.1 Low Voltage ZnO Varistor : Device Process and Defect Model F.A.Selim;T.K.Gupta;P.L.Hower;W.G.Calson
  5. J. Appl. Phys. v.54 no.51 Grain Growth Control in ZnO Varistor Using Seed Grains K.Eda;M.Inada;M.Matsuka
  6. Advances in Ceramics;Additives and Interfaces in Electronic Ceramics v.7 Influence of Additives on Varistor Microstructure M.Trontelj;D.Kolar;V.Karsevec;M. F. Yan(ed.);A. H. Heuer(ed.)
  7. J. Appl. Phys. v.54 no.5 Microstructure, Electrical Properties, and Failure Prediction in Low Clamping Voltage Zinc Oxide Varistors L.J.Bowen;F.J.Avella
  8. J. Am. Ceram. Soc. v.56 no.7 Electrical Properties of ZnO-Bi₂O₃Ceramics W.G.Morris
  9. Ceram. Bull. v.53 no.11 Microstructure and Phases in Nonohmic ZnO-Bi₂O₃ Ceramics J.Wong;W.G.Morris
  10. J. Appl. Phys. v.51 no.8 Sintering and Varistor Characteristics of ZnO-Bi₂O₃Ceramics J.Wong
  11. J. Am. Ceram. Soc. v.61 no.11-12 Average Grain Size in Polycrystalline Ceramics M.I.Mendelson
  12. Ceramic International v.12 Grain Growth of PLZT Ceramics during Hot Pressing D.Y.Kim;H.Yamamura
  13. J. Am. Ceram. Soc. v.48 no.4 Grain Growth in Zinc Oxide G.C.Nicholson
  14. J. Am. Ceram. Soc. v.51 no.9 Sintering of ZnO :Ⅰ. Densification and Grain Growth T.K.Gupta;R.L.Coble
  15. J. Am. Ceram. Soc. v.53 no.1 Grain Growth in Fully Dense ZnO S.K.Dutta;R.M.Spriggs
  16. J. Appl. Phys. v.46 no.4 Nature of an Intergranular Thin-film Phase in a Highly Non-Ohmic Metal Oxide Varistor J.Wong;P.Rao;E.H.Koch
  17. Proceeding of International Symposium on Factors in Densification and Sintering of Oxide and Non-Oxide Ceramics Grain Growth in Zinc Oxide Y.Morlyoshi;T.Ikegami;O.Maruyama;S.Shirasaki