Synthesis of Kaolinite and Transformation of Halloysite byHydrothermal Reaction

열수반응에 의한 Kaolinite의 합성 및 Halloysite의 개질

  • 김성규 (한국과학기술연구원 금속재료공정연구실) ;
  • 이화영 (한국과학기술연구원 금속재료공정연구실) ;
  • 오종기 (한국과학기술연구원 금속재료공정연구실)
  • Published : 1993.01.01

Abstract

synthesis of artificial kaolinite and the transformation of domestic halloysite have been attempted by means of the hydrothermal treatment. The hydrothermal reaction of the mixtures of gibbsite and amorphous silica was conducted for the synthesis of kaolinite under the pressure of 125MPa at 30$0^{\circ}C$ and especially the seed of kaolinite was added so as to facilitate the synthesis reaction. Domestic pink kaolin of B-grade was hydrothermally treated, in a similar way, for the transformation of crystalline form of it. Boehmite and the artificial kaolinite less than 0.4${\mu}{\textrm}{m}$ could be obtained through the hydrothermal reaction. It could also be found that the majority of hyalloysite was transformed into the plate-type kaolinite through the recrystallization by treating hydrothermally for a long time.

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References

  1. 대한광산학회지 v.15 no.4 저품위 고령토 정제에 관한 연구 황기엽;오종기;이동휘
  2. 대한광산학회지 v.18 no.4 하동-단성-산청지구 도색고령토의 탄철에 관한 연구 황기엽;오종기
  3. 한국과학기술원 보고서 국내 저품위 고령토의 활용에 관한 연구 이동휘(외)
  4. 한국요업학회지 v.14 no.2 국산 Kaolin의 개질에 관한 연구 이종근;이병하;김성일
  5. 粘土科學 v.28 no.1 Mineralogical and Chemical Properties of Shidare Kibushi Clay Y.Shibasaki;T.Maeda;S.Tomura;H.Mizuta;Y.Akatsuka;T.Osawa;H.Machimura
  6. 粘土科學 v.27 no.2 Soluble Cation Composition of Plastic Clays from Seto,Tono and Iga Districts,Japan T.Maeda;Y.Shibasaki;H.Kumagai
  7. 化學と工業 v.39 no.5 The Source of Ceramic Raw Material in Japan Y.Shibasaki
  8. 化學技術誌 MOL no.9月 住目される 人工粘土 Y.Shibasaki
  9. 제16회 자원활용기술 심포지움 논문집 Bacteria-leaching에 의한 점토의 정제 최용식