Effect of Excess MgO on Dielectric and Electrostrictive Properties of $0.99Pb(Mg_{1/3}Nb_{2/3})O_3-0.01Pb(Mn_{2/3}W_{1/3})O_3$

$0.99Pb(Mg_{1/3}Nb_{2/3})O_3-0.01Pb(Mn_{2/3}W_{1/3})O_3$계의 유전 및 전왜 특성에 미치는 과잉 MgO의 영향

  • 윤기현 (연세대학교 공과대학 세라믹공학과) ;
  • 김승연 (연세대학교 공과대학 세라믹공학과) ;
  • 남윤우 (연세대학교 공과대학 세라믹공학과) ;
  • 조용수 (연세대학교 공과대학 세라믹공학과) ;
  • 강동헌 (수원대학교 공과대학 전자재료공학과)
  • Published : 1993.08.01

Abstract

Dielectric and electrostrictive properties of 0.99Pb(Mg1/3Nb2/3)O3-0.01Pb(Mn2/3W1/3)O3 system using KCl-NaCl salts have been investigated as a function of the amount of excess MgO. For the specimens calcined at $700^{\circ}C$ for 1h and then sintered at 115$0^{\circ}C$ for 4h, the perovskite phase and the relative density were about 98% and 95%, respectively. With the addition of excess MgO up to 10mol%, the dielectric constant and the electrostrictive strain increased due to the increase of density and grain size, and these properties were degraded by the further addition of excess MgO. For the 10mol% excess MgO added specimen, the maximum electrostrictive strain, Xmax, and the electrostrictive coefficient, Q11, were 4.5$\times$10-4, 3.5$\times$10-2m4/C2, respectively. These results were correlated with the property of PMW and microstructure.

Keywords

References

  1. Sov. Phys. Solid. State v.1 no.10 Dielectric Polarization of a Number of Complex Compounds G.A. Smolensku;A.I. Agranovskaya
  2. Am. Ceram. Soc. Bull. v.66 no.4 Preparation of Lead Based Ferroelectric Relaxors for Capacitors T.R. Shrout;A. Halliyal
  3. Am. Ceram. Soc. Bull. v.65 no.4 Electrostrictive Actuators: Materials and Applications K. Uchino
  4. J. Am. Ceram. Soc. v.67 no.5 Dielectric Properties of Lead Magnesium Niobate Ceramics S.L. Swartz;T.R. Shrout;W.A. Schulze;L.E. Cross
  5. Electronic Ceramics L.M. Levinson
  6. Mater. Res. Bull. v.17 Fabrication of Perovskite Lead Magnesium Niobate S.L. Swartz;T.R. Shrout
  7. Am. Ceram. Soc. Bull. v.64 no.4 Optimization of Dielectric Properties of Lead Magnesium Niobate Ceramics M. Lejeune;J.P. Boilot
  8. J. Am. Ceram. Soc. v.71 no.3 Effect of Excess PbO on the Sintering Characteristics and Dielectric Properties of $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3-PbTiO_3$ Based Ceramics J.P. Guha;D.J. Hong;H.U. Anderson
  9. Ferroelectrics v.87 Dielectric Properties Due to Excess PbO and MgO in Lead Magnesim Niobate Ceramics D.H. Kang;K.H. Yoon
  10. Ferroelectrics v.116 Dielectric Properties of $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3$ Ceramics Prepared by KCI Molten Salt Synthesis K.H. Yoon;C.K. Kwak;D.H. Kang
  11. Ferroelectrics v.133 Effect of V₃O₃on Dielectric Properties of $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3-PbTiO_3$ Ceramics K.H. Yoon;J.H. Chung;D.H. Kang
  12. Ferroelectrics Effect of Eutectic Lithium Sulfate-Sodium Sulfate on the Synthesis of Lead Magnesium Niobate K.H. Yoon;Y.S. Cho;D.H. Kang;K. Uchino;K.Y. Oh
  13. J. Am. Ceram. Soc. v.72 no.8 Low Temperature Route to Lead Magnesium Niobate F. Chaput;J.P. Boilot;M. Lejeune;R. Papiernik;L.G. Hubert-Pfalzgraf
  14. Piezoelectric/Electrostrictive Actuator K. Uchino
  15. J. Am. Ceram. Soc. v.62 no.9-10 Structure and Dielectric Properties of Materials in the Solid Solution System $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3-PbTiO_3$, $Pb(W_{\frac{1}{2}}Mg_{\frac{1}{2}})O_3$ S. Nomura;S.J. Jang;L.E. Cross;R.E. Newnham
  16. Soviet Phys. JETP v.21 no.5 New Magnetic Ferroelectrics Y.E. Roginskaya;Y.N. Venevtsen;G.S. Zhdanov
  17. Mater. Res. Bull. v.14 no.5 Lead Zirconate Titanate Ceramics from Molten Salt Solvent Synthesized Powders R.H. Arendt;J.H. Rosolaskii;J.W. Szmaszek
  18. J. Am. Ceram. Soc. v.74 no.1 Molten Salt Synthesis of a Complex Perovskite, $Pb(Fe_{0.5}Nb_{0.5})O_3$ C.C. Chiu;C.C. Li;S.B. Desu
  19. Japan Kokai Tokkyo Koho JP 59-203759
  20. J. Am. Ceram. Soc. v.73 no.4 The Role of Excess Magnesium Oxide or Lead Oxide in Determining the Microstructure and Properteis of Lead Magnesium Niobate H.C. Wang;W.A. Schulze
  21. Jpn. J. Appl. Phys. v.24 no.SUP.24-2 Grain Size Dependence of Electrostriction in PMN Ceramics K. Uchino;M. Tatsumi;I. Hayashi;T. Hayashi
  22. J. Sol. Stat Chem. v.35 Ordering in $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3-Pb(Mg_{\frac{1}{2}}W_{\frac{1}{2}})O_3$ Solid Solutions A. Amin;R.E. Newnham;L.E. Cross;S. Nomura;D.E. Cox
  23. U.S. Patent 4,216,102 High Dielectric Constant Type Ceramic Composition Consisting Essentially of $Pb(Fe_{\frac{1}{2}}Nb_{\frac{1}{2}})O_3-Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3$ K. Furukawa;S. Fujiwara;N. Kikuchi;O. Izawa;H. Tanaka;H. Ueoka
  24. Phy. Stat. Sol. v.57 Electrostriction in the Solid Solution System $Pb(Mg_{\frac{1}{3}}Nb_{\frac{2}{3}})O_3-Pb(Mg_{\frac{1}{2}}W_{\frac{1}{2}})O_3$ S. Nomura;J. Kuwata;K. Uchino;S.J. Jang;L.E. Cross;R.E. Newnham