Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Photo-Crosslinking of Poly(glycidyl methacrylate) Initiated by N-Hydroxyphthalimide Sulfonates

  • Kyu Ho Chae (Department of Polymer Engineering, Chonnam National University) ;
  • Ik Ju Park (Department of Polymer Engineering, Chonnam National University) ;
  • Min Ho Choi (Department of Polymer Engineering, Chonnam National University)
  • Published : 1993.10.20
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Abstract

The photoacid generation efficiency of four N-hydroxyphthalimide sulfonate derivatives was studied by photo-crosslinking reaction of poly(glycidyl methacrylate) in solid film state. The relative photoacid generation efficiency was increased in the order of N-hydroxyphthalimide methanesulfonate > -toluenesulfonate > -nitrobenzenesulfonate > -dinitrobenzensulfonate, and the reaction was efficiently sensitized by benzophenone suggesting that this photoreactions is likely to proceed through its triplet excited state.

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References

  1. J. Rad. Curing v.14 G. L. Bassi
  2. Chem. & Eng. News v.29 R. Seltzer
  3. Polymer Bulletin v.19 D. J. Wilson;A. D. Jenkins
  4. ACS Symposium Series 242 Polymers in Electronics J. V. Crivello;T. Davidso(ed.)
  5. J. Electrochem. Soc. v.133 C. G. Wilson;H. Ito;J. M. J. Frechet
  6. J. Polymer Sci. Symposium v.56 J. V. Crivello;J. H. W. Lam
  7. Macromolecules v.10 J. V. Crivello;J. H. W. Lam
  8. Chemtech v.10 J. V. Crivello
  9. Development in Polymer Photochemistry v.2 J. V. Crivello;N. S. Allen(ed.)
  10. J. Rad. Curing v.13 G. Berner;R. Kirchmayr;G. Rist;W. Rutsch
  11. Macromol. Chem. Rapid Commun. v.5 M. Shirai;T. Masuda;M. Tsunooka;M. Tanaka
  12. Macromolecules v.21 F. M. Houlihan;A. Shugard;R. Gooden;E. Reichmanis

Cited by

  1. Photoacid and photobase generators: Chemistry and applications to polymeric materials vol.21, pp.1, 1993, https://doi.org/10.1016/0079-6700(95)00014-3
  2. Development of 1‐Hydroxy‐2(1H)‐quinolone‐Based Photoacid Generators and Photoresponsive Polymer Surfaces vol.18, pp.38, 1993, https://doi.org/10.1002/chem.201104065