Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Carbonylation of (Dichloromethyl)benzene Catalyzed by Cobalt Carbonyl and Iron Carbonyl under Phase Transfer Catalysis

  • Sang Chul Shiim (Department of Industrial Chemistry, Kyungpook National University) ;
  • Chil Hoon Doh (EV task Force Team, Korea Electrotechnology Research Institute) ;
  • Dong Yub Lee (Department of Industrial Chemistry, Kyungpook National University) ;
  • Jae Goo Shim (Department of Industrial Chemistry, Kyungpook National University) ;
  • Young Zoo Youn (Department of Industrial Chemistry, Kyungpook National University) ;
  • Woo Hyung Park (Department of Industrial Chemistry, Kyungpook National University) ;
  • Li Hong Jiang (Department of Industrial Chemistry, Kyungpook National University) ;
  • Ju Hee Kim (Department of Industrial Chemistry, Kyungpook National University)
  • Published : 1993.10.20
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Abstract

Treatment of (dichloromethyl)benzenes with CO (1 atm) in the presence of catalytic amount of $Co_2(CO)_8,\;Fe(CO)_5$ and BTEAC under two phase systems with NaOH(_{aq}) and $PhCH_3$ containing small amount of alcohol for 20 hours at 80$^{\circ}$C gives phenylacetic acids in moderate yields.

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References

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