Cure Kinetics of DGEBA/MBA/MN and DGEBA/MDA/MN/HQ Systems by Kissinger Equation and Fractional Life Method

Kissinger Equation과 Fractional Life법에 의한 DGEBA/MDA/MN계와 DGEBA/MDA/MN/HQ계의 경화반응 속도론

  • 이재영 (서울시립대학교 화학공학과) ;
  • 심미자 (서울시립대학교 생명과학과) ;
  • 김상욱 (서울시립대학교 화학공학과)
  • Received : 1994.05.20
  • Accepted : 1994.06.22
  • Published : 1994.08.01

Abstract

Cure kinetics of DGEBA/MDA/MN system with and without HQ were studied by Fractional life method and Kissinger equation. And the effect of HQ as a catalyst was studied. As cure temperature increased, the reaction rate increased and reaction order was almost constant. The activation energy of the system with HQ was lower about 13% and the reaction rate was higher than that of the system without HQ. It was because hydroxyl group of HQ formed a transition state with epoxide group and amine group and opened the epoxide ring easily and rapidly.

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