Characterization and Bacteicidal Effect of Na_2O-Al_2O_3-SiO_2$ Glass System by $Na^+$$\longleftrightarrow$$Ag^+$ Ion Exchange

$Na^+$$\longleftrightarrow$$Ag^+$ 이온교환에 따른 Na_2O-Al_2O_3-SiO_2$ 계 유리의 특성 및 살균효과

  • 이광희 (연세대학교 세라믹공학과) ;
  • 최세영 (연세대학교 세라믹공학과)
  • Published : 1996.02.01

Abstract

Glasses of Na2O-Al2O3-SiO2 system were prepared and ion-exchange characteristics change of properties and bactericidal effects by Na+↔Ag+ ion exchange were studied. Parent glasses with three compositions of varying Na2O in the 20~30 wt% were ion-exchanged in the molten salt of 2 mol% AgNO3+98 mol% NaNO3 at 320~36$0^{\circ}C$ for 15~16min. Amount of ion exchange and penetration depth of Ag+ ion increased with Na2O content in the parent glass ion exchange temperature and time. After ion exchange densities and Vickers hardness of the glasses increased and the glasses showed yellow-brown color and as amount of ion exchange increased the color turned deep because partial reduction and agglomeration of Ag+ into Ag0 results in absorption of visible light. After ion exchange chemical durability of the glass to wter was enhanced compara-bly that weight loss and change of surface of the glass were not found for the leaching test in 5$0^{\circ}C$ K.I water for 240hrs. Bactericidal effect of ion exchanged glass on Staphylococcus aureus and E. coli was determined by microorganism test and bactericidal effect increased with amount of ion exchange and incubation time.

Keywords

References

  1. 第1障 銀の抗菌性とえの 作用機構 銀處理水 エリ·ア·クリスキ
  2. Ceramics Japan v.28 no.7 抗菌性 セラミクス 吉成彪;內田眞志
  3. New Glass v.8 no.1 抗菌·抗薇 セラミクス 山本幸一
  4. Phys. Chem. Glasses v.5 no.5 The Strengthening of Glass by Ion Exchange A.J. Burgraaf;J. Cornelissen
  5. J. Non-Cryst. Solids v.73 Strong Glass R. Cardon
  6. Yogyo-Kyokai-Shi v.78 no.8 Formation of Ag and Ag Centers and Tentatively Proposed Mechanism of Silver Colloid Formation in Photosensitive Glass Ryosuke Yokota
  7. J. Non-Cryst. Solids v.107 Dependence of Refractive Index on Silver Concentration in Gradient-index Glass S.N. Houde-Walter;B.L. Mcintyre
  8. Applied Optics v.12 no.6 Optical Waveguides Formed by Thermal Migration of Ions in Glass T.G. Giallorenzi;E.J. West;R. Kirk;R. Ginther;R.A. Andrews
  9. J. Am. Ceram. Soc. v.47 no.5 Strengthening by Ion Exchange M.E. Nordberg;E.L. Mochel
  10. Glass Technology v.16 no.1 The Strengthening of Mixed Alkali Glass by Ion Exchange H. Ohta
  11. Ceramics Japan v.12 no.4 Basic Theory on Ion Exchange in Glass and Its Practical Applications H. Ohta
  12. 유리공학 H. Scholze;이정훈(역)
  13. J. Am. Ceram. Soc. v.33 no.3 Glasses as Electrolytes in Glavanic Cells; Silver Glasses G.E. Rindone;W.A. Weyl
  14. Ceramics Japan v.1 no.7 ガラスの着色に關する 二,三の考察 境野照雄
  15. J. Non-Cryst. Solids v.19 Coloring of Glass Surfaces by Ion Exchange G.H. Frischat
  16. J. Am. Ceram. Soc. v.58 no.3-4 Influence of Strain Energy on Kinetics of Ion Exchange in Glass A.K. Varshneya
  17. Corrosion of Glass D.E. Clark;C.G. Pantano, Jr.;L.L. Hench
  18. J. Am. Ceram. Soc. v.50 no.12 Effect of Stress on Durability of Ion Exchanged Surfaces D.L. Rothermel