Abstract
In the present study the effect of the addition of Fe on the pressureless and hot press sintering behavior was studied under Ar atmosphere. Pressureless sintering was performed 1900~220$0^{\circ}C$ under. Ar atmosphere. The addition of 1 wt% Fe was increased effectively of the sintered density. However it was impossible to obtain high density higher than 90%,. Zr-Fe-B compound in liquid phase was observed from the EDS and WDS analysis. It was considered that sinterability was enhanced due to the mass transfer through Fe based liquid phase formed at the sintering temperature. Hot pressing was performed at 1600~1$700^{\circ}C$ under Ar atmos-phere for 1 hr. It was possible obtain 95% relative density of ZrB2 specimen which is higher density at pressure-less sintering. It could be thought that ZrB2 particles was rearranged through liquid phase by applied pressure during initial stage of sintering.
