촉매의 열화에 관한 연구 I

Study I of Catalyst Aging

  • 손건석 (고등기술연구원 자동차기술연구실) ;
  • 이지연 (고등기술연구원 자동차기술연구실) ;
  • 이귀영 (정회원, 고등기술연구원 자동차기술연구실) ;
  • 최병철 (정회원, 전남대학교 기계공학과)
  • 발행 : 1997.05.01

초록

Quick aging of catalysts has done with IAE(Institute for advanced engineering) AGING MODE suggested by IAE. To estimate the effects of number of aging cycle, temperature and $H_2O$, characteristics of surfaces, mechanical properties and weibull modulus were estimated. Also, the conversion efficiency of aged catalysts was evaluated with model gas bench test. The area of surface and pore volume were decreased according to the number of aging cycle. The precious metal which is well dispersed in fresh state was sintered and agglomerated with aging. The mechanical of deactivation and sintering of catalysts are discussed on the basis of mechanical tests. The conversion efficiency was decreased with the repeats of aging. Especially, the existence of $H_2O$ in supply gas had a main role in catalyst deactivation withy high temperature.

키워드

참고문헌

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