대한전기학회논문지:전기물성ㆍ응용부문C (The Transactions of the Korean Institute of Electrical Engineers C)

대한전기학회 (The Korean Institute of Electrical Engineers)
권호 표지

고체 산화물 연료전지 금속 연결재용 $LaCrO_3$가 분산된 Cr 합금의 특성 연구

Characteristics of $LaCrO_3$-Dispersed Cr Alloy for Metallic Interconnector of Solid Oxide Fuel Cell

  • 전광선 (아주대 전자공학과) ;
  • 송락현 (한국에너지기술연구소 연료전지연구팀) ;
  • 신동렬 (한국에너지기술연구소 연료전지연구팀)
  • 발행 : 1999.08.01
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초록

$LaCrO_3$-dispersed Cr alloys for metallic interconnector of solid oxide fuel cell have been studied as function of $LaCrO_3$ content in the range of 5 to 25 vol.% in order to examine the electric conductivity, the oxidation property and the thermal expansion behavior of these alloys. The $LaCrO_3$-dispersed Cr alloys showed high electrical conductivities of $3~5\times10^4$ S/cm at room temperature, and as the $LaCrO_3$content increased the conductivity decreased slightly. During the cyclic oxidation test at $1100^{\circ}C$, the weight change of the Cr alloys decreased with increasing number of oxidation cycle except first cycle, which is attributed to the vaporization of the oxide scale. More addition of the $LaCrO_3$ content reduced also the weight change of the Cr alloys. These mean that the oxide scale formed at the surface of the Cr alloy becomes stable with increasing number of oxidation cycle and$LaCrO_3$ content. The measured thermal expansion of the Cr alloy was well fitted to that of 8 mol% $Y_2O_3$-stabilized $ZrO_2$ electrolyte. These results demonstrate that $LaCrO_3$-dispersed Cr alloy is a useful material for metallic interconnector of solid oxide fuel cell.

키워드

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