The Korean Journal of Ceramics

The Korean Ceramic Society (한국세라믹학회)
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Structural Relaxation of Semiconducting Vanadate and IR-Transmitting Gallate Glasses Containing Iron

  • Published : 2000.03.01
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Abstract

Glass transition temperature (T/sub g/) is proportional to the quadrupole splitting(Δ) of Fe(III) obtained from the /sup 57/Fe Mossbauer spectra (T/sub g/-Δ rule (1990)). The values of Δ reflect the distortion of Fe(III) atoms, which occupy the sites of network-forming atoms. Heat treatment of potassium vanadate and calcium gallate glasses at around the individual T/sub g/ causes a structural relaxation, accompanying a linear decrease of T/sub g/ and Δ values. These experimental results prove that T/sub g/ decreases with a decrease in the distortion of VO₄, GaO₄, and FeO₄tetrahedra, as the T/sub g/-Δ rule predicted.

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References

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