Effects of $N_2O$/$SiH_4$Flow Ratio and RF Power on Properties of $SiO_2$Thick Films Deposited by Plasma Enhanced Chemical Vapor Deposition

PECVD법에 의해 증착된 $SiO_2$후막 특성에서 $N_2O$/$SiH_4$Flow Ratio와 RF Power가 미치는 영향

  • 조성민 (성균관대학교 신소재공학과) ;
  • 김용탁 (성균관대학교 신소재공학과) ;
  • 서용곤 (전자부품연구원 광부품연구센터) ;
  • 임영민 (전자부품연구원 광부품연구센터) ;
  • 윤대호 (성균관대학교 신소재공학과)
  • Published : 2001.11.01

Abstract

Silicon diosixde thick film using silica optical waveguide cladding was fabricated by Plasma Enhanced Chemical Vapor Deposition (PECVD) method, at a low temperature (32$0^{\circ}C$) and from (SiH$_4$+$N_2$O) gas mixtures. The effects of deposition parameters on properties of SiO$_2$thick films were investigated by variation of $N_2$O/SiH$_4$flow ratio and RF power. As the $N_2$O/SiH$_4$flow ratio decreased, deposition rate increased from 2.9${\mu}{\textrm}{m}$/h to maximum 10.1${\mu}{\textrm}{m}$/h. As the RF power increased from 60 W to 120 W, deposition rate increased (5.2~6.7 ${\mu}{\textrm}{m}$/h) and refractive index approached at thermally grown silicon dioxide (n=1.46).

저온(32$0^{\circ}C$)에서 SiH$_4$$N_2$O 가스의 혼합을 통해 플라즈마화학기상증착(PECVD)법을 이용하여 실리카 광도파로의 클래딩막으로 사용되는 SiO$_2$후막을 제조하였다. 증착변수가 SiO$_2$후막의 특성에 미치는 영향을 살펴보기 위해 $N_2$O/SiH$_4$flow ratio와 RF power에 변화를 주었다. $N_2$O/SiH$_4$ flow ratio가 감소함에 따라 증착속도는 2.9 $mu extrm{m}$/h), 굴절률은 thermal oxide의 굴절률(n=1.46)에 근접하였다.

Keywords

References

  1. J. of Lightwave Technol. v.6 Silica-based Single-mode Waveguide on Silicon and their Application to Guided-wave Optical Interferometers N. Takato;K. Jinguji;M. Yasu;H. Toba;M. Kawachi
  2. Jpb. J. Appl. Phys. v.22 no.1932 Flame Hydrolysis Deposition of SiO₂-TiO₂Glass Planar Optical Waveguide on Silicon M. Kawachi;M. Yasu;et al.
  3. J. Kor. Ceram. Soc. v.35 no.4 The Effective P₂$O_5$ Doping into B₂O₃-P₂$O_5$-SiO₂Silica Layer Fabrication by Flame Hydrolysis Deposition J. K. Sim;Y. H. Lee;H. K. Sung;T. G. Choi
  4. J. Vac. Sci. Technol. v.A11 Fabrication of Waveguide using Low-temperature Plasma Processing Technique E. S. Bulat;M. Tabasky;B. Tweed;et al.
  5. Microelectronics Reliablity v.40 Annealing Effects in the PECVD SiO₂Thin Films Deposited using TEOS, Ar and O₂Mixture C. E. Viana;N. I. Morimoto;O. Bonnaud
  6. J. Kor. Asso. Crystal Growth v.10 no.1 Surface Analysis of a-SiC:H Deposited by RF Plasma-enhanced CVD Y. T. Kim(et al.)
  7. J. Non-Crystalline Solid v.212 High Quality Low Temperature DPECVD Silicon Dioxide Pereyra;M. I. Alayo
  8. J. Vac. Sci. Technol. v.A8 no.3 Thermal Stabilization of Device Quality Films Deposited at Low Temperature J. T. Fitch;S. S. Kim;G. Lucovsky
  9. Thin Solid Films v.332 Thick Si$O_x$$N_y$ and SiO₂Films Obtained by PECVD Technique at Low Temperatures M. I. Alayo;I. Pereyra;M. N. P. Carreno
  10. J. Vac. Sci. Technol. v.B10 The Role of Oxygen Excitation and Loss in Plasma-enhanced Deposition of Silicon Dioxide from Tetraethylorthosilicate G. P. Raupp;T. S. Cale
  11. Thin Solid Films v.280 Effects of N₂O/SiH₄Ratio on the Properties of Low-temperature Silicon Oxide Films from Remote Plasma Chemical Vapour Deposition Y. B. Park;J. K. Kang;S. W. Rhee
  12. Jpn. J. Appl. Phys. v.25 no.10 Silicon Nitride Films Prepared by Plasma Enhanced Chemical Vapour Deposition (PECVD) of SiH₄/NH₃/N₂Mixture : Some Physical Properties C. H. Ling;C. Y. Kwok;K. Prasad
  13. J. Vac. Sci. Technol. v.A8 no.3 Substrate Temperature Dependence of Subcutaneous Oxidation at Si/SiO₂Interfaces Formed by Remote Plasma-enhanced Chemical Vapor Deposition S. S. Kim;D. J. Stepleen;G. Lucovsky
  14. Thin Solid Films v.117 Silane Oxidation Study : Analysis of Data for SiO₂Films Deposited by Low Temperature Chemical Vapour Deposition C. Cobian;C. Pavelescu
  15. J. Vac. Sci. Technol. v.B8 no.4 Formation of Device Quality Si/SiO₂Interface at Low Substrate Temperature by Remote Plasma Enhanced Chemical Vapor Deposition of SiO₂ G. Lucovsky;S. S. Kim;J. T. Fitch
  16. J. Electrochem. Soc. v.140 no.5 Chemistry of SiO₂Plasma Deposition D. L. Smith;A. S. Alimonda
  17. Surface and Coating Technology v.131 Effects of Process Parameters on the Growth of Thick SiO₂using Plasma Enhanced Chemical Vapor Deposition with Hexamethyld-isilazane J. K. Choi;D. H. Kim;J. L;J. B. Yoo