Residence s Exposure to Nitrogen Dioxide and Indoor Air Characteristics

거주지역 실내공기 특성 및 이산화질소 노출에 관한 연구

  • 양원호 (서울대학교 보건대학원 환경보건학과) ;
  • 배현주 (서울대학교 보건대학원 환경보건학과) ;
  • 정문호 (서울대학교 보건대학원 환경보건학과)
  • Published : 2002.06.01

Abstract

Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level and so on. Although technologies exist to measure these factors directly, direct measurements of all factors are impractical in most field studies. The purpose of this study was to develop an alternative methods to estimate these factors by multiple measurements. Daily indoor and outdoor NO$_2$concentrations for 21 days in 20 houses in summer and winter, Seoul. Using a mass balance model and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor(emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the ventilation and source strength were estimated. During sampling period, geometric mean of natural ventilation was estimated to be 1.10$\pm$1.53 ACH, assuming a residential NO$_2$decay rate of 0.8 hr$^{-1}$ in summer. In winter, natural ventilation was 0.75$\pm$1.31 ACH. And mean source strengths in summer and winter were 14.8ppb/hr and 22.4ppb/hr, respectively. Although the method showed similar finding previous studies, the study did not measure ACH or the source strength of the house directly. As validation of natural ventilations, infiltrations were measured with $CO_2$tracer gas in 18 houses. Relationship between ventilation and infiltration was statistically correlated (Pearson r=0.63, p=0.02).

Keywords

References

  1. Skillas, G., Huglin, C.H. and Siegmann, H.C. : Determination of air exchange rates of rooms and deposition factors for fine particles by means of photoelectric aerosol sensors. Indoor Built Environment, 8, 246-254, 1999 https://doi.org/10.1177/1420326X9900800406
  2. Sherman, M.H. : Tracer-gas techniques for measuring ventilation in a single zone. Building and Environment, 25(4), 365-374, 1990 https://doi.org/10.1016/0360-1323(90)90010-O
  3. Nazaroff, W.W. and Cass, G.R. : Mathematical modeling of chemically reactive pollutants in indoor air. Environ. Sci. Technol., 20, 924-934, 1986 https://doi.org/10.1021/es00151a012
  4. Leaderer, B.P., Schaap, L. and Dietz, R.N. : Evaluation of the perfluorocarbon tracer technique for determining in infiltration rates in residences. Environ. Sci. Technol., 19, 1225-1232, 1985 https://doi.org/10.1021/es00142a015
  5. Esmen, N.A. : The status of indoor air pollution. Environmental Health Perspectives, 62, 259-265, 1985 https://doi.org/10.2307/3430123
  6. Moschandreas, D.J. and Relwani, S.M. : Emission rates from range top-burner assessment of measurement methods. Atmospheric Environment, 21, 285-289, 1987 https://doi.org/10.1016/0004-6981(87)90003-5
  7. Relwani, S.M., Moschandreas, D.J. and Billick I.H. : Effects of operational factors on pollutant emission rates from residential gas appliances. Journal of the Air Pollution Control Association, 36, 1233-1237, 1986 https://doi.org/10.1080/00022470.1986.10466170
  8. Kraenzmer, M. : Modeling and continuous monitoring of indoor air pollutants for identification of sources and sinks. Environment International, 25(5), 541-551, 1999 https://doi.org/10.1016/S0160-4120(99)00029-X
  9. Spicer, C.W., Coutant, R.W., Ward, G.F. and Joseph, D.W. : Rates and mechanisms of NO$_2$ removal from indoor air by residential material. Environmental International, 15, 634-654, 1986
  10. Tichenor, B.A. : Overview of source/sink characterization methods. American Society for Testing Materials, STP 1287, 9-19, 1996
  11. Yamanaka, S. : Decay rates of nitrogen oxides in a typical Japanese living room. Environ. Sci. Tech., 18, 566-570, 1984 https://doi.org/10.1021/es00125a017
  12. Cyrys, J., Heinrich, J., Richter, K., Wolke, G. and Wichmann, H.E. : Sources and concentrations of indoor nitrogen dioxide in Hamburg and Erfurt. The Science of the Total Environment, 250, 51-62, 2000 https://doi.org/10.1016/S0048-9697(00)00361-2
  13. Sexton, K., Letz, R. and Spengler, D. : Estimating human exposure to nitrogen dioxide: an indoor/outdoor modeling approach. Environmental Research, 32. 151-166, 1983 https://doi.org/10.1016/0013-9351(83)90202-5
  14. World Health Organization(WHO) : Air Quality Guidelines for Europe. European Series No. 23, Copenhagen, Denmark, 297-310, 1987
  15. Bauer, M.A., Utell, M.J., Morrow, P.E., Speers, D.M. and Gibb, H.P. : Inhalation of 0.3 ppm nitrogen dioxide potentiates exercise-induced bronchospasm in asthmatics. Am. Rev. Respir. Dis., 134, 1203-1208, 1986
  16. Mohensin, V. : Airway responses to nitrogen dioxide in asthmatic subjects. J. Toxicol. & Environ. Health, 22, 371-380, 1987 https://doi.org/10.1080/15287398709531080
  17. Yanagisawa, Y. and Nishmura, H. : A badge-type personal sampler for measurement of personal exposures to NO$_2$ and NO in ambient air. Environment International, 8, 235-242, 1982 https://doi.org/10.1016/0160-4120(82)90033-2
  18. Tichenor, B.A., Sparks, L.A., White, J.B. and Jackson, M.D. : Evaluating sources of indoor air pollution. Journal of the Air & Waste Management Association, 40, 487-492, 1990 https://doi.org/10.1080/10473289.1990.10466703
  19. Ott, W., Switzer, P. and Robinson, J. : Particle concentrations inside a tavern before and after prohibition of smoking: evaluating the performance of an indoor air quality model. Journal of the Air & Waste Manage ment Association, 46, 1120-1134, 1996 https://doi.org/10.1080/10473289.1996.10467548
  20. Furtaw, E.J., Pandian, M.D., Nelson, D.R. and Behar, J.V. : Modeling indoor air concentrations near emission sources in imperfectly mixed rooms. Journal of the Air & Waste Management Association, 46, 861-868, 1996 https://doi.org/10.1080/10473289.1996.10467522
  21. Dockery, D.W. and Spengler, J.D. : Indoor-outdoor relationships of respirable sulfates and particles. Atmospheric Environment, 15, 335-343, 1981 https://doi.org/10.1016/0004-6981(81)90036-6
  22. Dimitroulopoulou, C., Ashmore, M.R., Byrne, M.A. and Kinnersley, R.P. : Modelling of indoor exposure to nitrogen dioxide. Atmosphere Environment, 35, 269-279, 2001 https://doi.org/10.1016/S1352-2310(00)00176-X
  23. Yang, W., Bae, H., Yoo, S. and Chung, M. : Determination of deposition velocity for nitrogen dioxide In residence usmg two-point measurements. Proceeding of the 12th World Clean Air & Environment Congress and Exhibition, Seoul, Korea, Paper No VI Session 3e, 2001
  24. Wade, W.A., Cote, W.A. and Yocom, J.E. : A study of indoor air quality. Journal of the Air Pollution Control Association, 25(9), 933-939, 1975 https://doi.org/10.1080/00022470.1975.10468114
  25. Wikes, C.R., Koontz, M.D. and Billick, I.H. : Analysis of sampling strategies for estimating annual average indoor NO$_2$ concentrations in residence with gas appliance. Journal of the Air & Waste Management Association, 46, 853-860, 1996 https://doi.org/10.1080/10473289.1996.10467521
  26. Ryan, P.B., J.D. Spengler, and R. Letz : The effects of kerosene heaters on indoor pollutant concentrations: a monitoring and modeling study, Atmospheric Environment, 17, 1339-1345, 1983 https://doi.org/10.1016/0004-6981(83)90408-0
  27. Spicer, C.W., D.V. Kenny and F.W.Gerald : Transformations, lifetimes, and sources of NO$_2$, HONO, and HNO$_3$ in indoor environments, Journal of the Air & Waste Management Association, 43, 1479-1485, 1993
  28. Smith, R.L. : Use of Monte Carlo simulation for human exposure assessment at a superfund site, Risk Analysis, 14(4), 433-439, 1994 https://doi.org/10.1111/j.1539-6924.1994.tb00261.x
  29. Wilson, A.L., Colome, S.D., Tian, Y. Becker, E.W., Baker, P.E., Behrens, D.W., Billick, I.H. and Garrison, C.A. : California residential air exchange rates and residence volumes, Journal of Exposure Analysis and Environm ental Epidemiology, 6(3), 311-326, 1996