A Study on Natural Dyeing(6) - Extract, Purification and Characters of Berberine -

천연염색에 관한 연구(6) - 황벽색소의 추출, 정제 및 특성-

  • Published : 2002.08.01

Abstract

The most effective solvent for extract of dye from amur cork tree was methanol. Two protoberberine alkaloids, berberine and palmatine, were isolated from amur cork tree by Prep-TLC, and the developing solvent was Benzene : AcOEt ; PrOH ; MeOH ; EtNH$_2$(8: 4: 2: 0.5: 0.5). Dyes were stable at a high temperature and there wasn't any change of color at pH 3~9 and with added metal mordants. In adsorption spectra of aqueous solution of berberine and tannin mixture, two isosbestic points$(328^{nm},\;357^{nm})$ were found and the mole fraction of reaction of components was 1:1.

Keywords

References

  1. Phytochemistry v.48 no.2 A. Ikuta;T. Nakamura;H. Urabe https://doi.org/10.1016/S0031-9422(97)01130-8
  2. Syoyakugaku Zasshi v.27 no.1 T. Sawada;J. Yamahara;K. Chinlija
  3. Syoyakugaku Zasshi v.43 no.1 S. Tosa;S. Ishihara;Y. Nose;T. Tomimatsu
  4. Journal of Pharmaceutical and Biomedical Analysis v.21 H. S. Lee;Y. E. Eom;D. O. Eom https://doi.org/10.1016/S0731-7085(99)00113-2
  5. Phytochemistry v.31 no.4 K. Kishi;K. Yoshikawa;S. Arihara https://doi.org/10.1016/0031-9422(92)80285-M
  6. Syoyakugaku Zasshi v.30 no.2 Y. Hashimoto;K. Ando;M. Mizuno
  7. Syoyakugaku Zasshi v.97 no.11 T. Hattori;M. Inoue;M. Hayakawa https://doi.org/10.1248/yakushi1947.97.11_1263
  8. Syoyakugaku Zasshi v.38 no.3 A. Ikuta;A. Kobayashi;H. Itokawa
  9. Seoul University of Pharmaceutical Science v.1 N. H. Paik;M. K. Park;B. R. Lim
  10. Journal of natural products v.44 no.2 R. Verpoorte;J. Siwon;M. Tieken;A. Svendsen https://doi.org/10.1021/np50014a013
  11. Journal of natural products v.47 no.1 A. Ikuta;H. Itokawa
  12. Llydia v.40 no.4 W. N. Wu;J. L. Beal;R. P. Leu;R. W. Doskotch
  13. J. Agric. Food Chem. v.48 J. P. Kim;M. Y.Jung;J. P. Kim;S. Y. Kim https://doi.org/10.1021/jf9909297
  14. Syoyakugaku Zasshi v.26 no.1 T. Sawada;J. Yamahara;C. Iwao
  15. Syoyakugaku Zasshi v.27 no.2 T. Sawada;J. Yamahara;E. Morioka
  16. Syoyakugaku Zasshi v.28 no.2 T. Sawada;J. Yamahara;Y. Shintani
  17. Syoyakugaku Zasshi v.26 no.2 K. Kimura;Y. Noro;S. Handa
  18. Biol. Pharm. Bull v.22 no.10 N. Okamura;H. Miki;S. Ishda;H. Ono;A. Yano;T. Tanaka;Y. Ono;A. Yagi https://doi.org/10.1248/bpb.22.1015
  19. Bunseki kagaku v.46 no.6 Y. Akada;N. Ishi https://doi.org/10.2116/bunsekikagaku.46.491
  20. Journal of Chromatography A v.795 H. M. Liebich;R. Lehmann;C. Stefano;H. Haring;J. H. Kim;K. R. Kim https://doi.org/10.1016/S0021-9673(97)00972-2
  21. Pharmaceutica Acta Helvetiae v.74 X. Ji;Y. Li;H. Liu;Y. Yan;J. Li https://doi.org/10.1016/S0031-6865(99)00061-8
  22. JapanesePatent, 60-227690
  23. Syoyakugaku Zasshi v.26 no.1 T. Sawada;J. Yamahara;N. Ohashi;H. Tutihashi
  24. J. Pharm. Soc. Korea v.45 no.1 D. O. Eom;Y. C. Jeong
  25. Bunseki Kagaku v.45 no.8 K. Arai;M. Kimura;F. Kusu;K. Takamura https://doi.org/10.2116/bunsekikagaku.45.783
  26. 植物化學 刈米達夫
  27. 建國技術硏究論文志 v.24 K. S. Kim
  28. Ministry of Science & Technology A Study of extracting of the coloring matters and standardizing of the dyeing conditions about the vegetable natural dyestuffs H. O. So
  29. Chem. Pharm. Bull. v.25 no.6 T. Narao;I. Kinuko;K. Miyoko https://doi.org/10.1248/cpb.25.1426
  30. Organic Structure Determination D. J. Pasto;C. R. Hohnson
  31. Dyeing Industry v.37 no.3 T. Hirashima
  32. 色素の化學 西久夫
  33. Sen-i Gakkaishi v.31 no.10 S. Yoshikawa;E. Doi