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자전연소 합성법을 이용한 Zn2SiO4:Mn2+ 형광체 합성시 Zn 및 Mn의 영향

Effect of Zn and Mn on the Synthesis of Zn2SiO4:Mn2+ Phosphor by SHS

  • 이종은 (충남대학교 급속응고 신소재 연구소) ;
  • 김병범 (충남대학교 급속응고 신소재 연구소) ;
  • 이혁희 (한국화학연구원) ;
  • 원창환 (충남대학교 급속응고 신소재 연구소)
  • Lee Jong Eun (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University) ;
  • Kim Byeong Beom (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University) ;
  • Lee Hyeok Hui (Korea Research Institute of Chemical Technology) ;
  • Won Chang Whan (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University)
  • 발행 : 2004.12.01

초록

The synthesis of $Zn_{2}SiO_4:Mn^{2+}$ for PDP green phosphor by SHS(Self-propagating High temperature Synthesis method) was studied. The precursors were well mixed and cold compacted. And then, the green pellet was synthesized at high temperature through self-propagating high temperature zone. Because this reaction uses the heat resulted from the oxidation of Zn metal powder in this system, Zn/ZnO mole ratio is one of the most important reaction variable. Throughout several experiments, the optimal condition of Zn/ZnO mole ratio and Mn concentration are 1.2/0.8 and 0.05mo1e, respectively.

키워드

참고문헌

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