멤브레인 (Membrane Journal)

  • 제15권2호
  • /
  • Pages.85-104
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  • 2005
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  • 1226-0088(pISSN)
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  • 2288-7253(eISSN)
한국막학회 (The Membrane Society of Korea)
권호 표지

Membrane Morphology: Phase Inversion to Electrospinning

  • Chanunpanich N. (Department of Industrial Chemistry, Faculty of Applied Science, King Mongkut's Institute of Technology North Bangkok) ;
  • Byun Hongsik (Department of Chemical System Engineering, Keimyung University) ;
  • Kang Inn-Kyu (Department of Polymer Engineering, Kyungpook National University)
  • 발행 : 2005.06.01
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초록

Recently, membrane can be prepared by two methods, phase inversion and electrospinning techniques. Phase inversion technique is a conventional but commercially preparation membrane. The most versatile of preparation in this technique is immersion of the cast film into nonsolvent bath, causing dense top layer with a finger-like pattern in the sub layer membrane. The membrane pore size getting from phase inversion is in the range of micro or submicrometer. As a result, it can be used as microfiltration and ultrafiltration applications. A new technique, electrospinning, is introduced for membrane preparation. Nonwoven nanofibrous mat or nanofibrous membrane is obtained. In this technique, electrostatic charge is introduced to the solution jet, causing a thin fiber with high surface area; hence it can be used in the applications where high surface area-to-volume or length-to-diameter ratios are required. Moreover, the pore size can be controlled by controlling the time of electrospinning. Hence, it can be used as a filter for filtering microparticles as well as nanoparticles.

키워드

참고문헌

  1. M. Mulder, 'Basic Principles of Membrane Technology,' 2nd ed. Kluwer Academic Publishers, Dordrecht, Germany (1996)
  2. El. R. Kenawy, J. M. Layman, J. R. Watkins, G. L. Bowlin, J. A. Matthews, D. G. Simpson, and G. E. Wnek, 'Electrospinning of poly( ethylene-co-vinyl alcohol) fibers,' Biomaterials, 24, 907 (2003) https://doi.org/10.1016/S0142-9612(02)00422-2
  3. D. Bo and K Zhu, 'Preparation and properties of polyimide ultrafitration membranes,' J. Membrane Sci., 60, 63 (1991)
  4. I.-C. Kim, H.-G. Yun, and K-H. Lee, 'Formation of integrally skinned asymmetric polyetherimide nanofiltration membrane by phase inversion process,' J. Appl. Poly. Sci., 84(6), 1300 (2002)
  5. B. Jung, J. K Yoon, B. Kim, and H.-W. Rhee, 'Effect of crystallization and annealing on polyacrylonitrile membranes for ultrafiltration,' J. Membrane Sci., 246, 67 (2005)
  6. C. Kleinlogel and L. J. Gauckler, 'Sintering and Properties of nanosized Ceria Solid solutions,' Solid State Ionics, 135, 567 (2000)
  7. K Darcovich, F. Toll, P. Hontanx, V. Roux, and K Shinagawa, 'An Experimental and numerical study of particle size distribution effects on the sintering of porous ceramics,' Mater. Sci. Eng., A 348, 76 (2003) https://doi.org/10.1016/S0921-5093(02)00634-2
  8. E. Levnen and T. Mntyl, 'Effect of sintering Temperature on functional Properties of Alumina Membranes,' J. Euro. Cer. Soc., 22, 613 (2002)
  9. S. Liu, K Li, and R Hughes, 'Preparation of Pores Aluminium Oxide ($Al_2O_3$) hollow fibre membranes by a combined phase-inversion and sintering method,' Ceramics International, 29, 875 (2003)
  10. S. P. S. Badwal, F. T. Ciacchi, and K M. Giampietro, 'Analysis of Conductivity of Commercial easy Sintering grade 3 mol% $Y_2O_3-ZrO_2$ materials,' Solid State Ionics, 176, 169 (2005) https://doi.org/10.1016/j.ssi.2004.06.012
  11. H. Middleton, S. Diethelm, R. Ihringer, D. Larrain, J. Sfeir, and J. V. Herle, 'Co-casting and cosintering of porous MgO support plates with thin dense perovskite layers of $LaSrFeCoO_3$,' J. Euro. Cer. Soc., 24, 1083 (2004)
  12. J. Zhou, R F. Childs, and A. M. Mika, 'Pore-filled nanofiltration membranes based on poly(2-acrylamido2-methylpropanesulfonic acid) gels,' J. Membrane Sci., 254, 89 (2005) https://doi.org/10.1016/j.memsci.2004.12.043
  13. M. Bengisu and E. Yilmaz, 'Gel casting of alumina and zirconia using chitosan gels,' Ceramics International, 28, 431 (2002)
  14. K Lindqvist and E. Liden, 'Preparation of alumina membranes by tape casting and dip coating,' J. Euro. Cer. Soc., 17, 359 (1997)
  15. Z. P. Zhao, J. Li, J. Chen, and C. X. Chen, 'Nanofiltration membrane prepared from polyacrylonitrile ultrafiltration membrane by low-temperature plasma 2. Grafting of styrene in vapor phase,' J. Membrane Sci., 251, 239 (2005)
  16. C. Qiu, F. Xu, Q. T. Nguyen, and Z. Ping, 'Nanofiltration membrane prepared from cardo polyetherketone ultrafiltration membrane by UV-induced grafting method,' J. Membrane Sci., 255, 107 (2005)
  17. S. A. Altinkaya, H. Yenal, and B. Ozbas, 'Membrane formation by dry-cast process Model validation through morphological studies,' J Membrane Sci., 249, 163 (2005)
  18. G.-J. Wang, L.-Y. Chu, W.-M. Chen, and M.-Y. Zhou, 'A porous microcapsule membrane with straight pores for the immobilization of microbial cells,' J. Membrane Sci., 252, 279 (2005)
  19. J.-D. Jeon, B.-W. Cho, and S.-Y. Kwak, 'Solventfree polymer electrolytes based on thermally annealed porous P(VdF-HFP)/P(EO-EC) membranes,' J. Power Sources, 143, 219 (2005)
  20. H. C. Park, Y. P. Kim, H. Y. Kim, and Y. S. Kang, 'Membrane formation by water vapor induced phase inversion,' J. Membrane Sci., 156, 169 (1999)
  21. S. Yang, Z. Liu, and H. Chen, 'A gas-liquid chemical reaction treatment and phase inversion technique for formation of high permeability PAN UP membranes,' J. Membrane Sci., 246, 7 (2005)
  22. W. R. Bowen, S. Y. Cheng, T. A. Doneva, and D. L. Oatley, 'Manufacture and characterisation of polyetherimide/sulfonated poly(ether ether ketone) blend membranes,' J. Membrane Sci., 250, 1 (2005)
  23. M. Khayet, J. I. Mengual, and T. Matsuura, 'Porous hydrophobic/hydrophilic composite membranes Application in desalination using direct contact membrane distillation,' J. Membrane Sci., 252, 101 (2005)
  24. D. Rana, T. Matsuura, R. M. Narbaitz, C. Feng, 'Development and characterization of novel hydrophilic surface modifying macromolecule for polymeric membranes,' J. Membrane Sci., 249, 103 (2005)
  25. L. Ying, E. T. Kang, K G. Neoh, K Kato, and H. Iwata, 'Drug permeation through temperaturesensitive membranes prepared from poly(vinylidine fluoride) with grafted poly(N-isopropylacrylamide) chains,' J. Membrane Sci., 243, 253 (2004)
  26. S. S. Zhang, M. H. Ervin, K Xu, and T. R. Jow, 'Li-ion battery with poly(acrylonitrile-methyl methacrylate)-based microporous gel electrolyte,' Solid State Ionics, 176, 41 (2005)
  27. Y.-C. Wang, M.-Y. Teng, K-R. Lee, and J.-Y. Lai, 'Comparison between the pervaporation and vapor permeation performances of polycarbonate membranes,' Euro. Polym. J, 41, 1667 (2005)
  28. B. Tang, T. Xu, M. Gong, and W. Yang, 'A novel positively charged asymmetry membranes from poly (2,6-dimethy1-1,4-phenylene oxide) by benzyl bromination and in situ amination: membrane preparation and characterization,' J. Membrane Sci., 248, 119 (2005) https://doi.org/10.1016/j.memsci.2004.09.027
  29. J.-H. Kim and K-H. Lee, 'Effect of PEG additive on membrane formation by phase inversion,' J. Membrane Sci., 138, 153 (1998)
  30. A. Frenot and I. S. Chronakis, 'Polymer nanofibers assembled by electrospinning,' Curr. Opinion in Colloid Interf. Sci., 8, 64 (2003)
  31. H. Fong, I. Chun, and D. H. Reneker, 'Beaded nanofibers formed during electrospinning,' Polymer, 40, 4585 (1999)
  32. S. A. Theron, E. Zussman, and A. L. Yarin, 'Experimental investigation of the governing parameters in the electrospinning of polymer solutions,' Polymer, 45, 2017 (2004)
  33. A. Koski, K. Yim, and S. Shivkumar, 'Effect of molecular weight on fibrous PVA produced by electrospinning,' Mat. Lett., 58, 493 (2004)
  34. K. J. Pawlowski, H. L. Belvin, D. L. Raney, J. Su, J. S. Harrison, and E. J. Siochi, 'Electro spinning of a micro-air vehicle wing skin,' Polymer, 44, 1309 (2003)
  35. W. K. Son, J. H. Youk, T. S. Lee, and W. H. Park, 'The effects of solution properties and polyelectrolyte on electrospinning of ultrafine poly (ethylene oxide) fibers,' Polymer, 45, 2959 (2004)
  36. X. Zong, K. Kim, D. Fang, S. Ran, B. S. Hsiao, and B. Chu, 'Structure and process relationship of electrospun bioabsorbable nanofiber membranes,' Polymer, 43, 4403 (2002)
  37. G. M. McKee, C. L. Elkins, and T. E. Long, 'Influence of self-complementary hydrogen bonding on solution rheology/electrospinning relationships,' Polymer, 45, 8705 (2004)
  38. J. M. Deitzel, J. Kleinmeyer, D. Harris, and N. C. B. Tan, 'The effect of processing variables on the morphology of electrospun nanofibers and textiles,' Polymer, 42, 261 (2001) https://doi.org/10.1016/S0032-3861(00)00352-9
  39. R. J. Cranford, H. Darmstadt, J. Yang, and C. Roy, 'Polyetherimide/polyvinypyrolidone vapor permeation membranes. Physical and Chemical Characterization,' J. Membrane Sci., 155, 231 (1999)
  40. I. D. Norris, M. M. Shaker, F. K. Ko, and A. G. MacDiarmid, 'Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends,' Synth. Met., 114, 109 (2000)
  41. S. A. Theron, A. L. Yarin, E. Zussman, and E. Kroll, 'Multiple jets in electrospinning: experiment and modeling,' Polymer, 46, 2889 (2005) https://doi.org/10.1016/j.polymer.2004.11.004
  42. B. Ding, E. Kimura, T. Sato, S. Fujiita, and S. Shiratori, 'Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning,' Polymer, 45, 1895 (2004)
  43. B. M. Min, S. W. Lee, J. N. Lim, Y. You, T. S. Lee, P. H. Kang, and W. H. Park, 'Chitin and Chitosan nanofibers: electrospinning of chitin and deacetylation of chitin nanofibers,' Polymer, 45, 7137 (2004)