Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Preparation and Characterization of Chitosan/Cellulose Acetate Blend Film

키토산/셀룰로오스 아세테이트 복합필름의 제조와 특성

  • Jung, Young-Jin (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • An, Byung-Jae (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Choi, Hae-Wook (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Kim, Hong-Sung (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Lee, Young-Hee (Dept. of Organic Material System Engineering, Pusan National University)
  • 정영진 (부산대학교, 생명자원과학대학, 바이오소재) ;
  • 안병재 (부산대학교, 생명자원과학대학, 바이오소재) ;
  • 최해욱 (부산대학교, 생명자원과학대학, 바이오소재) ;
  • 김홍성 (부산대학교, 생명자원과학대학, 바이오소재) ;
  • 이영희 (부산대학교, 유기소재시스템공학)
  • Published : 2007.08.27
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Abstract

Chitosan(CS) and cellulose acetate(CA) composite films were prepared using formic acid as a cosolvent by casting, solvent evaporating and neutralization method. This study examines if the blending method, which uses formic acid as a cosolvent is efficient in improving the mechanical properties of CS film, especially wet strength and elongation. Formic acid is an effective cosolvent for the blend of CS and CA. Under wet condition, tensile strength and elongation of the composite films were obviously higher than those of the films made from pure CS. FTIR, DSC, and X-ray diffraction showed that the composite films exhibit a high level of compatibility and that strong interaction between the CS and CA was caused by intermolecular hydrogen bonding. The affinity series of composite film to transition metal ions are Cu(II) > Cd(II) > Cr(III). The adsorption of Cu((II) ion was shown to be highly pH sensitive.

Keywords

References

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