Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Novel Phenol Resin Carbonizing Method for Carbon Interlayer Coating between Reinforcing Fiber and Matrix in Fiber Reinforced Ceramic Composite

페놀수지 탄화 코팅법을 이용한 섬유강화 복합재료 계면 형성에 관한 연구

  • Kim, Se-Young (Reaction and Separation Material Research Center, Korea Institute of Energy Research) ;
  • Woo, Sang-Kuk (Reaction and Separation Material Research Center, Korea Institute of Energy Research) ;
  • Han, In-Sub (Reaction and Separation Material Research Center, Korea Institute of Energy Research)
  • 김세영 (한국에너지기술연구원 반응분리소재연구센터) ;
  • 우상국 (한국에너지기술연구원 반응분리소재연구센터) ;
  • 한인섭 (한국에너지기술연구원 반응분리소재연구센터)
  • Published : 2009.05.31
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Abstract

The novel carbon coating process for interlayer of fiber reinforced ceramic composites between fiber and matrix was performed by carbonizing phenolic resin solution that coated on fiber surface in $N_2$ atmosphere at $600^{\circ}C$ to improve the strength and fracture toughness of CMC(ceramic matrix composite). 160 nm carbon layer was coated on fiber surface with 5 vol% of phenolic resin solution. Since the process temperature ($600^{\circ}C$) is lower than chemical vapor deposition($900{\sim}1000^{\circ}C$), the strength and toughness could be preserved. Furthermore the coating thickness uniformity was improved to 8% of deviation along the stacking sequence. Therefore, prevention from fiber degradation during coating process and controlling coating thickness uniformity along the preform depth were achieved by coating with phenolic resin carbonizing method.

Keywords

References

  1. J. P. Singh, D. Singh, and M. Sutaria, 'Ceramic Composites: Roles of Fiber and Interface,' Comp.:Part A, 30 445-50 (1999) https://doi.org/10.1016/S1359-835X(98)00133-X
  2. J.H. Miller, P.K. Liaw, and J.D. Landes, 'Influence of Fiber Coating Thickness on Fracture Behavior of Continuous Woven Nicalon Fabric-reinforced Silicon-carbide Matrix Ceramic Composites,' Mat. Sci. & Eng. A, A317 49-58 (2001) https://doi.org/10.1016/S0921-5093(01)01184-4
  3. S. Kumar, and R. N. Singh, 'Effects of Coating Properties on Crack Propagation in Nicalon-fiber/sic-matrix Composites,' Comp. Sci. & Tech., 56 1271-81 (1996) https://doi.org/10.1016/S0266-3538(96)00087-5
  4. Hua-Tay Lin, and Paul F. Becher, 'Effect of Fiber Coating on Lifetime of Nicalon Fiber-silicon Carbide Composites in Air,' Mat. Sci. & Eng. A, A231 143-50 (1997) https://doi.org/10.1016/S0921-5093(97)00079-8
  5. G. Hackl, H. Gerhard, and N. Popovska, 'Coating of Carbon Short Fibers with Thin Ceramic Layers by Chemical Vapor Deposition,' Thin Solid Films, 513 217-22 (2006) https://doi.org/10.1016/j.tsf.2006.02.001
  6. D.B. Fischbach and P.M. Lemoine, 'Influence of a CVD Carbon Coating on the Mechanical Property Stability of Nicalon SIC Fiber,' Comp. Sci. & Tech., 37 55-61 (1990) https://doi.org/10.1016/0266-3538(90)90092-J
  7. T. Horikawa, K. Ogawa, K. Mizuno, J. Hayashi, and K. Muroyama, 'Preparation and Characterization of the Carbonized Material of Phenol-formaldehyde Resin with Addition of Various Organic Substances,' Carbon, 41 465-72 (2003) https://doi.org/10.1016/S0008-6223(02)00352-4
  8. W.D. Brouwer, E.C.F.C. van Herpt, and M. Labordus, 'Vacuum Injection Moulding for Large Structural Applications,' Comp. :Part A, 34 551-58 (2003) https://doi.org/10.1016/S1359-835X(03)00060-5
  9. A. Kelly, and C. Zweben, 'Comprehensive Composite Materials:' Vol. 4, pp. 611-44, Elsevier science Ltd., Oxford, 2000
  10. N. Kuentzer, P. Simacek, S. G. Advani, and S. Walsh, 'Correlation of Void Distribution to VARTM Manufacturing Techniques,' Comp. :Part A, 38 802-13 (2007) https://doi.org/10.1016/j.compositesa.2006.08.005
  11. Michael D. Sacks, 'Effect of Composition and Heat Treatment Conditions on the Tensile Strength and Creep Resistance of SiC-based Fibers,' J. Euro. Ceram. Soc., 19 2305-15 (1999) https://doi.org/10.1016/S0955-2219(99)00114-4
  12. S. Wu, L. Cheng, L. Zhang, Y. Xu, J. Zhang, and H. Mei, 'Wet Oxidation Behaviors of Hi-Nicalon Fibers,' App. Surface Sci., 253 1447-50 (2006) https://doi.org/10.1016/j.apsusc.2006.02.021

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