Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Preparation of Mg(OH)2 Dispersion and its Application to PET Non-woven Textile as Flame Retardant Coating

수산화마그네슘 분산상의 제조와 PET 부직포 섬유의 난연 코팅제 적용

  • Lim, Hyung-Mi (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Hyun, Mi-Kyung (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Jeong, Sang-Ok (Nanotech Ceramics Co. Ltd.) ;
  • Lee, Dong-Jin (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Seung-Ho (Eco-Composite Materials Center, Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology)
  • 임형미 (한국세라믹기술원 그린세라믹본부 에코복합소재센터) ;
  • 현미경 (한국세라믹기술원 그린세라믹본부 에코복합소재센터) ;
  • 정상옥 ((주)나노텍세라믹스) ;
  • 이동진 (한국세라믹기술원 그린세라믹본부 에코복합소재센터) ;
  • 이승호 (한국세라믹기술원 그린세라믹본부 에코복합소재센터)
  • Received : 2011.10.17
  • Accepted : 2011.11.09
  • Published : 2011.11.30
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Abstract

Magnesium hydroxide as a non-halogen flame retardant has increasing attention due to its non-toxicity, high decomposition temperature and smoke suppressant ability during combustion. For the application of magnesium hydroxide retardant to the textile by soaking and coating method, the prerequisite for the coating is a small particle size, stable dispersion, and adhesion to the textile. The dispersion of $Mg(OH)_2$ particles and stability of the coating was checked by monitoring the change of transmittance and backscattering by varying the types of dispersion agents, binder, solvent, and $Mg(OH)_2$ source, and their compositions in the coating. The $Mg(OH)_2$ dispersion coating was applied to PET(poly(ethylene terephthalate)) non-woven textile. The physical properties are characterized by surface morphology, amount of coating, particle dispersion, and adhesion test. The flame retardant $Mg(OH)_2$ coated textile has been compared by limited oxygen index(LOI) and thermal gravimetry and differential scanning calorimetry(TG-DSC). It was found that phosphorous additive may give synergistic effect on $Mg(OH)_2$ flame retardant coating to make the flame retardant PET non-woven textile.

Keywords

References

  1. A. R. Horrocks, "Flame Retardant Chanllenges for Textiles and Fibers: New Chemistry Versus Innovatory Solutions," Polymer Degradation Stability, 96 377-92 (2001).
  2. H. M. Lim, J. Yoon, S. O. Jeong, D. J. Lee, and S.-H. Lee, "Preparation of $Mg(OH)_2$-melamine Core-shell Particle and its Flame Retardant Property (in Korean)," Kor. J. Mater. Res., 20 [12] 691-98(2010). https://doi.org/10.3740/MRSK.2010.20.12.691
  3. H. M. Lim, J. Yun, M. Hyun, Y. Yoon, D. J. Lee, C. M. Whang, S. O. Jeong, and S. H. Lee, "Magnesium Hydroxide Flame Retardant and its Application to a Low-density Polyethylene/ ethylene Vinyl Acetate Composite," J. Ceram. Process. Res., 10 [4] 571-76 (2009).
  4. F. Carosio, G. Laufer, J. Alongi, G. Camino, and J. C. Grunlan, "Layer-by Layer Assembly of Silica-based Flame Retardant thin Film on PET Fabric," Progress in Polym. Sci., 96 745-50 (20110).
  5. P. Kiliaris and C. D. Papaspyrides, "Polymer/layered Silicate(Clay) Nanocomposites: An Overview of Flame Retardancy," Progress in Poly. Sci., 35 902-58 (2010). https://doi.org/10.1016/j.progpolymsci.2010.03.001
  6. M. Qu, Y. Wang, C. Wang, X. Ge, D. Wang, and Q. Zhou, "A Novel Method for Preparing Poly(ethylene terephthalate)/ $BaSO_4$ Nanocomposites," Europ. Polymer J., 41 [11] 2569-74 (2005). https://doi.org/10.1016/j.eurpolymj.2005.05.013
  7. W. Liu, X. Tian, P. Cui, Y. Li, K. Zheng, and Y. Yang, "Preparation and Characterization of PET/silica Nanocomposites," J. Appl. Polymer Sci., 91 [2] 1229-32 (2004). https://doi.org/10.1002/app.13284
  8. D. Y. Wang, X. Q. Liu, J. S. Wang, Y. Z. Wang, A. A. Stec, and R. Hull, "Preparation and Characterisation of a Novel Fire Retardant PET/${\alpha}$-zirconium Phosphate Nanocomposite," Polymer Degradation Stability, 94 [4] 544-49 (2009). https://doi.org/10.1016/j.polymdegradstab.2009.01.018
  9. Y. H. Shin, W. D. Lee, and S. S. Im, "Effect of A-zeolite on the Crystallization Behavior of In-situ Polymerized Poly(ethylene terephthalate) (PET) Nanocomposites," Macromolecular Res., 15 [7] 662-70 (2007). https://doi.org/10.1007/BF03218947
  10. Zeng Ke and Bai Yongping, "Improve the Gas Barrier Property of PET Film with Montmorillonite by in Situ Interlayer Polymerization," Mater. Lett., 59 [27] 3348-51 (2005). https://doi.org/10.1016/j.matlet.2005.05.070

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