Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Surface Treatment and Dyeability of Poly(phenylene sulfide) Films by UV/O3 Irradiation

UV/Ozone 조사에 의한 Poly(phenylene sulfide) 필름의 표면처리와 염색성

  • Jang, Yong-Joon (Department of Materials Design Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Department of Materials Design Engineering, Kumoh National Institute of Technology)
  • 장용준 (금오공과대학교 소재디자인공학과) ;
  • 장진호 (금오공과대학교 소재디자인공학과)
  • Received : 2011.11.29
  • Accepted : 2011.12.12
  • Published : 2011.12.27
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Abstract

Poly(phenylene sulfide)(PPS) films were photooxidized under UV/ozone irradiation. The effect of UV energy on the surface properties of the UV-irradiation PPS films were investigated by the measurement of reflectance, surface roughness, and contact angle. Reflectance decreased at the wavelength of 400nm and the surface roughness increased with increased UV energy. The improvement in hydrophilicity with increased $O_{1s}/C_{1s}$ was caused by the introduction of hydrophilic $SO_2$ bond. Surface energy increased from 46.6 to $78.3mJ/m^2$ with increased UV energy up to $21.2J/cm^2$. Also zeta potential decreased with increased UV energy. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the PPS films surfaces.he photochemically introduced anionic and dipolar dyeing sites on the PPS films surfaces.

Keywords

References

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