대한환경공학회지 (Journal of Korean Society of Environmental Engineers)

  • 제33권4호
  • /
  • Pages.281-288
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  • 2011
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  • 1225-5025(pISSN)
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  • 2383-7810(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
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다양한 형태의 Pilot Scale 초음파 시스템 개발 및 나프탈렌 분해효율 검증

Development of Various Pilot Scale's Ultrasound Systems and Sonodegradation of Naphthalene in Water

  • 박종성 (육군3사관학교 화학환경과학과) ;
  • 이하윤 (육군3사관학교 화학환경과학과) ;
  • 한종훈 (육군3사관학교 화학환경과학과) ;
  • 허남국 (육군3사관학교 화학환경과학과)
  • Park, Jong-Sung (Department of Chemistry and Environmental Sciences, Korea Army Academy at Young-Cheon) ;
  • Lee, Ha-Yun (Department of Chemistry and Environmental Sciences, Korea Army Academy at Young-Cheon) ;
  • Han, Jong-Hun (Department of Chemistry and Environmental Sciences, Korea Army Academy at Young-Cheon) ;
  • Her, Nam-Guk (Department of Chemistry and Environmental Sciences, Korea Army Academy at Young-Cheon)
  • 투고 : 2011.01.03
  • 심사 : 2011.04.27
  • 발행 : 2011.04.29
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초록

초음파 기술은 공동현상(cavitation)에 의한 산화분해 및 열분해 과정을 이용해 오염물질을 저감시키는 활발한 연구가 진행되고 있으나 대부분 저용량 소규모(Lab scale) 실험에 그치고 있다. 본 연구에서는 대용량 연속식 처리가 가능한 Pilot Scale의 초음파 시스템을 개발하고, 분해 대상물질로 나프탈렌을 선정하여 개발된 시스템의 처리효율을 비교 검증하였다. 전반사가 유도된 최적의 다주파 조사 조건으로 V-$120^{\circ}$ 형태가 일반형에 비해 약 1.4~2.2배 우수한 효율을 나타내었다. V-$120^{\circ}$ 초음파 조사 형태, 연속식 처리가 가능하기 위한 유입 유출수 설치, 보조제 첨가부 및 외곽 냉각 순환시스템을 적용하여 총 3가지 형태의 pilot scale(20~40 L) 반응조를 제작하였다. 세 반응조의 나프탈렌 처리 결과는 모두 EPA의 나프탈렌 음용수 권고기준을 만족하였으며, 특히, 전반사 조건이 유도된 PS1과 PS2 type이 약 97% 이상의 우수한 분해효율을 보였다. 연속식(CSTR형) 처리 방식에서도 2.5~10 mg/L의 나프탈렌을 시간당 10~20 L를 처리한 결과 약 84~96%의 우수한 분해효율을 나타내었다. 인공 현장 지하수 조건에서의 초음파 적용시 초음파 효율의 큰 차이를 보이지 않아 개발된 본 시스템의 현장 적용 가능성을 확인하였다.

Recently, researches that a variety of contaminants in water are removed by sonolysis technology with oxidation and pyrolysis process from cavitation were conducted. However, there are few studies for sonochemical treatment by a pilot-scale ultrasound system. This research focused on developing pilot-scale ultrasound systems, which could be an continuously effective treatment for a large volumes of contaminants, and demonstrating the feasibility of utilizing these systems to remove naphthalene from groundwater. V-120 type reactor was found to be 1.4~2.2 times higher effective than the normal type. A total of three different pilot scale's systems consisted of installing effluent and irrigation water in order to be a continuos system, including supplemental additives, and applying a V-120 type reactor and a external cooling cycle system. Naphthalene levels treated by three systems were lower than a recommended guideline of naphthalene for drinking water in EPA. Especially, the naphthalene removal efficiencies of PS1 and PS2 systems were over 97%. The pilot-scale continuous ultrasound clean-up system delivered over 84~95% naphthalene removal efficiency for treatment of 10~20 liter of groundwater. In addition, the ultrasound system could be successfully applied to the conditions of artificial and genuine groundwater contaminated with naphthalene.

키워드

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