분석과학 (Analytical Science and Technology)

  • 제25권6호
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  • Pages.435-440
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  • 2012
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  • 1225-0163(pISSN)
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  • 2288-8985(eISSN)
한국분석과학회 (The Korean Society of Analytical Sciences)
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금강 지표수에서 LC-ESI-MS/MS에 의한 염소산이온의 극미량 분석

Determination of perchlorate in the Gum-River surface water by LC-ESI-MS/MS

  • 이영준 (국립환경과학원 금강물환경연구소) ;
  • 이준배 (국립환경과학원 금강물환경연구소) ;
  • 홍선화 (국립환경과학원 금강물환경연구소) ;
  • 김현지 (공주대학교 환경과학과) ;
  • 신호상 (공주대학교 환경교육과)
  • Lee, Young Joon (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Lee, Jun Bae (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Hong, Seon Haw (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Kim, Hyun-Ji (Department of Environmental Science, Kongju National University) ;
  • Shin, Ho-Sang (Department of Environmental Education, Kongju National University)
  • 투고 : 2012.08.28
  • 심사 : 2012.10.08
  • 발행 : 2012.12.25
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초록

지표수 중에 과염소산이온을 LC-ESI-MS/MS을 사용하여 분석하였다. 시료는 단지 PTFE 필터를 사용하여 거른 후 LC-ESI-MS/MS 시스템에 직접 주입하여 분석하였다. 이 방법은 3% 이내의 정밀도를 보였고 정량한계는 0.17 ${\mu}g/L$이었다. 시료는 금강물 35 개 유역에서 2, 4, 6월에 각각 시료를 채취하였다. 그 결과 일반 하천수에서는 과염소산이온이 0.23-3.73 ${\mu}g/L$ (평균 0.20 ${\mu}g/L$) 농도범위로 15% 빈도로 검출되었고 공단 근처의 지표수에서는 0.36-25.10 ${\mu}g/L$ (평균 1.69 ${\mu}g/L$)로 36%의 빈도로 검출되었다.

A liquid chromatography-electrospray ionization-tandem mass spectrometry method (LC-ESI-MS/MS) was used for determining perchlorate in the Gum-River surface water. Sample was directly injected into LC-ESI-MS/MS after the filtrations using PTFE filter paper. The coefficient of variation of perchlorate was less than 3% and the limit of quantification was 0.17 ${\mu}g/L$. Water samples were collected from thirty-five basins of Gum-River on February, April and June 2012, respectively. As a result, perchlorate was detected in the concentration range of 0.23-3.73 ${\mu}g/L$ (mean 0.20 ${\mu}g/L$) in the frequency of 15% in general surface water and in the concentration range of 0.36-25.10 ${\mu}g/L$ (mean 1.69 ${\mu}g/L$) in the frequency of 36% in surface water samples near industry area.

키워드

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