Journal of Korean Society of Water and Wastewater (상하수도학회지)

The Korean Society of Water and Wastewater (대한상하수도학회)
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Degradation of 2-Chlorophenol in the Aqueous Phase by a Photo-Fenton Process

광펜톤 반응에 의한 수중 2-클로로페놀 분해특성연구

  • Received : 2012.10.24
  • Accepted : 2012.11.29
  • Published : 2012.12.15
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Abstract

The degradation of 2-chlorophenol(2-CP) by various AOPs(Advanced Oxidation Processes) including the photo-Fenton process has been examined. In sole $Fe^{2+}$, UV or $H_2O_2$ process without combination, low removal efficiencies have been achieved. But the photo-Fenton process showed higher removal efficiency for degradation of 2-chlorophenol than those of other AOPs including the Fenton process and the UV processes. In the photo-Fenton process, the optimal experimental conditions of 2-chlorophenol degradation were obtained at pH 3 and the $Fe^{2+}/H_2O_2$molar ratio of 1. Also the 2-chlorophenol removal efficiency increased with decreasing of the initial 2-chlorophenol concentration. 3-chlorocatechol and chlorohydroquinone were identified as photo-Fenton reaction intermediates, and a degradation pathway of 2-chlorophenol in the aqueous phase during the photo-Fenton reaction was proposed.

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References

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