DOI QR코드

DOI QR Code

Moisture Absorption Characteristics of Pt/Nafion Membrane for PEMFC Prepared by a Drying Process

건식법에 의해 제조한 PEMFC용 Pt/나피온 막의 흡습 특성

  • Lee, Jae-Young (Hydrogen Fuel Cell Parts and Applied Technology RIC, Woosuk University) ;
  • Lee, Hong-Ki (Hydrogen Fuel Cell Parts and Applied Technology RIC, Woosuk University)
  • 이재영 (우석대학교 수소연료전지 부품 및 응용기술 지역혁신센터) ;
  • 이홍기 (우석대학교 수소연료전지 부품 및 응용기술 지역혁신센터)
  • Received : 2012.07.27
  • Accepted : 2012.08.24
  • Published : 2012.08.31

Abstract

A simple drying process was developed for the preparation of a Pt/Nafion self-humidifying membrane to be used for a proton-exchange membrane fuel cell (PEMFC). Platinum (II) bis (acetylacetonate), $Pt(acac)_2$ was sublimed, penetrated into the surface of a Nafion film and then reduced to Pt nanoparticles simultaneously without any support of a reducing agent in a glass reactor at $180^{\circ}C$ for 15 min. The process was carried out in $N_2$ atmosphere to prevent the oxidation of Pt nanoparticles at high temperature. The morphology and distribution of the Pt nanoparticles were observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), and we found that the average Pt particle size was ca. 3.7 nm, the penetration depth was ca. $17{\mu}m$. Almost all Pt nanoparticles were formed just beneath the surface and the number density decreased rapidly as the penetration depth increased. To estimate water absorption characteristics of the Nafion membranes, water uptake at an isothermal condition was measured by dynamic vapor sorption (DVS), and it was found that water uptake of the Pt/Nafion membrane was higher than that of the neat Nafion membrane.

Keywords

References

  1. Y. Sasaki, M. Iijima, T. Osad, K. Miyamoto, and M. Nagai, "Nanostructure with Clusters in Nafion by DSC", International Journal of Thermophysics, Vol. 27, No. 6, 2006, p. 1792. https://doi.org/10.1007/s10765-006-0132-4
  2. K. A. Mauritz and R. B. Moore, "State of Understanding of Nafion", Chem. Rev., Vol. 104, No. 10, 2004, p. 4535. https://doi.org/10.1021/cr0207123
  3. K. Y. Ahn, C. N. Yang and S. Lee, "A Study on Electrochemical Characteristics of MEA with Nafion Ionomer Content in Catalyst Layer for PEMFC", Trans. of the Korean Hydrogen and New Energy Society, Vol. 21 No. 6, 2010, p. 540.
  4. M. Watanabe, H. Uchida, Y. Seki, M. Emori, and P. Stonehart, "Self‐Humidifying Polymer Electrolyte Membranes for Fuel Cells", Journal of the Electrochemical Society, Vol. 143, No. 12, 1996, p. 3847. https://doi.org/10.1149/1.1837307
  5. M. Watanabe, H. Uchida, and M. Emori, "Analyses of Self‐Humidification and Suppression of Gas Crossover in Pt‐Dispersed Polymer Electrolyte Membranes for Fuel Cells", Journal of the Electrochemical Society, Vol. 145, No. 4, 1998, p. 1137. https://doi.org/10.1149/1.1838429
  6. Y. Zhang, H. Zhang, Y. Zhai, X. Zhu, and C. Bi, "Investigation of Self-humidifying Membranes Based on Sulfonated Poly(ether ether ketone) Hybrid with Sulfated zirconia Supported Pt Catalyst for Fuel Cell Applications", Journal of Power Source, Vol. 168, No. 2, 2007, p. 323. https://doi.org/10.1016/j.jpowsour.2007.03.007
  7. F. Q. Liu, B. L. Yi, D. M. Xing, J. R. Yu, Z. J. Hou, and Y. Z. Fu, "Development of Novel Self-humidifying Composite Membranes for Fuel Cells", Journal of Power Source, Vol. 124, No. 1, 2003, p. 81. https://doi.org/10.1016/S0378-7753(03)00616-5
  8. Y. H. Liu, B. Yi, Z. G. Shao, L. Wang, D. Xing and H. Zhang, "Pt/CNTs-Nafion Reinforced and Self-humidifying Composite Membrane for PEMFC Applications", Journal of Power Source, Vol. 163, No. 2, 2007, p. 807. https://doi.org/10.1016/j.jpowsour.2006.09.065
  9. J. Y. Byun, H. W. Kim, J. Y. Sung, and H. W. Kim, "Preparation of Self-humidifying Pt/Nafion Membranes Using Supercritical $CO_{2}$ for PEMFCs", Clean Technology, Vol. 13, No. 2, 2007, p. 99.
  10. J. Y. Lee, D. Yin, and S. Horiuchi, "Site and Morphology Controlled ZnO Deposition on Pd Catalyst Prepared from Pd/PMMA Thin Film Using UV Lithography", Chemistry of Materials, Vol. 17, No. 22, 2005, p. 5498. https://doi.org/10.1021/cm0506555
  11. J. Y. Lee, Y. Liao, R. Nagahata, and S. Horiuchi, "Effect of Metal Nanoparticles on Thermal Stabilization of Polymer/metal Nanocomposites Prepared by a One-step Dry Process", Polymer, Vol. 47, No. 23, 2006, p. 7970. https://doi.org/10.1016/j.polymer.2006.09.034