DOI QR코드

DOI QR Code

A theoritical study on spin coating technique

  • Tyona, M.D. (Department of Physics, Benue State University)
  • 투고 : 2012.06.21
  • 심사 : 2013.04.08
  • 발행 : 2013.12.25

초록

A comprehensive theory of the spin coating technique has been reviewed and the basic principles and parameters controlling the process are clearly highlighted, which include spin speed, spin time, acceleration and fume exhaust. The process generally involves four stages: a dispense stage, substrate acceleration stage, a stage of substrate spinning at a constant rate and fluid viscous forces dominate fluid thinning behaviour and a stage of substrate spinning at a constant rate and solvent evaporation dominates the coating thinning behaviour. The study also considered some common thin film defects associated with this technique, which include comet, striation, chucks marks environmental sensitivity and edge effect and possible remedies.

키워드

참고문헌

  1. Al-Juaid, F., Merazga, A., Abdel-Wahab, F. and Al-Amoudi, M.N. (2012), "ZnO Spin-Coating of $TiO_2$ photo-electrodes to enhance the efficiency of associated dye-sensitized solar cells", World J. Condensed Matter Physics. 2, 192-196. https://doi.org/10.4236/wjcmp.2012.24032
  2. Chang, P.C. and Lu, J.G. (2008), "ZnO nanowire field-effect transistors", IEEE T. Electron. Dev., 55, 2977-2987. https://doi.org/10.1109/TED.2008.2005181
  3. Chiou, W.T., Wu, W.Y. and Ting, J.M. (2003), "Growth of single crystal ZnO nanowires using sputter deposition", Diam. Relat. Mater., 12, 1841-1844. https://doi.org/10.1016/S0925-9635(03)00274-7
  4. Emslie, D., Bonner, P. and Peck, C. (1958), "Fluid flow basics (ideal Case)", J. Appl. Phys. 29, 858-862. https://doi.org/10.1063/1.1723300
  5. Hanaor, D., Trianni, G. and Sorrell, C. (2011), "Morphology and photocatalytic activity of highly oriented mixed phase titanium dioxide thin film", Surf. Coat. Tech., 205(12), 855-874.
  6. Hellstrom, S.L. (2007), Published course work for physics 210, Stanford University, Autumn 2007.
  7. Heo, Y.W., Varadarajan, V., Kaufman, M., Kim, K., Norton, D.P., Ren, F. and Fleming, P.H. (2002), "Site-specific growth of ZnO nanorods using catalysis-driven molecular-beam epitaxy", Appl. Phys. Lett. 81, 3046-3048. https://doi.org/10.1063/1.1512829
  8. Hewes, J. (2011), "Power supplies", The Electronics Club.
  9. Holt, C.A. (1978), Electronic Circuits, Digital and Analog. John Wiley and Sons, New York.
  10. Hong, J.I., Bae, J., Wang, Z.L. and Snyder, R.L. (2009), "Room temperature, texture-controlled growth of ZnO thin films and their application for growing aligned ZnO nanowire arrays", Nanotechnology, 20, 085609. https://doi.org/10.1088/0957-4484/20/8/085609
  11. Huang, M.H., Wu, Y.Y., Feick, H., Tran, N., Weber, E. and Yang, P.D. (2001), "Catalytic growth of zinc oxide nanowires by vapor transport", Adv. Mater., 13, 113-116. https://doi.org/10.1002/1521-4095(200101)13:2<113::AID-ADMA113>3.0.CO;2-H
  12. Ilican, S., Caglar, Y. and Caglar, M. (2008), "Preparation and characterization of ZnO thin films deposited by sol-gel spin coating method", J. Optoelectron. Adv. Mater., 10(10), 2578-2583.
  13. Oliveira, J.P., Laia, C.T. and Branco, L.C. (2012), "Optimization of Ionic Liquid Film Deposition by Spin and Dip Coating Techniques", J. Maters. Sc. Eng. B, 2(8), 437-441.
  14. Kamaruddin, S.A., Chan, K., Yow, H., Sahdan, M.Z., Saim, H. and Knipp, D. (2010), "Zinc oxide films prepared by sol-gel spin coating technique", Appl. Phys. A. 104, 263-268.
  15. Lin, D., Wu, H. and Pan, W. (2007), "Photoswitches and memories assembled by electrospinning aluminum-doped zinc oxide single nanowires", Adv. Mater. 19, 3968-3972. https://doi.org/10.1002/adma.200602802
  16. Madou, M. (2002), Fundamentals of Microfabrication. The Science of Miniaturization, 2nd ed., CRC Press.
  17. Middleman, S. and Hochberg, A.K. (1993), Process Engineering Analysis in Semiconductor Devices Fabrication, McGraw Hill, P. 313.
  18. Mihi, A., Oca-mtlide, M. and Miguez, H. (2006), "Oriented colloidal-crystal thin films by spin-coating microspheres dispersed in volatile media", Adv. Mat., 18, 2244. https://doi.org/10.1002/adma.200600555
  19. Mitzi, D.B., Kosbar, L.L., Murray, C.E., Copel, M. and Atzali, A. (2004), "High mobility ultrathin semiconducting films prepared by spin coating", Nature, 428, 299-303. https://doi.org/10.1038/nature02389
  20. Meyerhofer, D. (1978), "Key stages in spin coating process", J. Appl. Phys., 49, 3993. https://doi.org/10.1063/1.325357
  21. Niranjan, S., Parija, B. and Panigrahi, S. (2009), "Fundamental understanding and modeling of spin coating process: A review", Indian J. Phys., 83(4), 493-502. https://doi.org/10.1007/s12648-009-0009-z
  22. Pan, Z.W., Dai, Z.R. and Wang, Z.L. (2001), "Nanobelts of semiconducting oxides", Science, 291, 1947-1949. https://doi.org/10.1126/science.1058120
  23. Panigrahi, S., Waugh, S., Rout, S.K., Hassan, A.K. and Ray, A.K. (2008), "Study of spin coated organic thin film under spectrophotometer", J. Mater. Res., 28, 858.
  24. Peeters, T. and Remoortere, B.V. (2008), "Parameters of the spin coating process", J. Appl. Sci., 46, 685-696.
  25. Schubert, D.W. and Dunkel, T. (2003), "Spin coating from molecular point of view: Its concentration regimes, Influence of molar of molar mass and distribution", Mater. Res. Innov., 7, 314. https://doi.org/10.1007/s10019-003-0270-2
  26. Schuler, A.C. (1999), Electronics Principles and Applications. Fifth edition; McGraw-Hill, New York.
  27. Schwartz, L.W. and Roy, R.V. (2004), "Theoretical and numerical results for spin coating of viscous liquids", Phys. Fluid, 16, 569. https://doi.org/10.1063/1.1637353
  28. Spin Coating Machine (2013), Available @: http://www.holmarc.com/spin_coating_machine.html., Retrieve on February 18.
  29. Sui, X.M., Shao, C.L. and Liu, Y.C. (2005), "White-light emission of polyvinyl alcohol/ZnO hybrid nanofibers prepared by electrospinning", Appl. Phys. Lett., 87, 113-115.
  30. Swati, S., Tran, A., Nalamasu, O. and Dutta, P.S. (2006), "Spin-coated ZnO thin films using ZnO Nano-colloid", J. Electron. Mater., 35(6), 9965-9968.
  31. Wu, J.J., Wen, H.I. Tseng, C.H. and Liu, S.C. (2004), "Well-aligned ZnO nanorods via hydrogen treatment of ZnO films", Adv. Funct. Mater. 14, 806-810. https://doi.org/10.1002/adfm.200305092
  32. Xu, S. and Wang, Z.L. (2011), "One-dimensional ZnO nanostructures: solution growth and functional properties", Nano Res., 4(11), 1013-1098 https://doi.org/10.1007/s12274-011-0160-7
  33. Xu, C.K., Xu, G.D., Liu, Y.K. and Wang, G.H. (2002), "A simple and novel route for the preparationof ZnO nanorods", Solid State Commun., 122, 175-179. https://doi.org/10.1016/S0038-1098(02)00114-X
  34. Vayssieres, L., Keis, K., Lindquist, S.E. and Hagfeldt, A. (2001), "Purpose-built anisotropic metal oxide material: 3D highly oriented microrod array of ZnO", J. Phys. Chem. B, 105, 3350-3352. https://doi.org/10.1021/jp010026s
  35. Verges, M.A., Mifsud, A. and Serna, C.J. (1990), "Formation of rodlike zinc-oxide microcrystals in homogeneous solutions", J. Chem. Soc. Faraday Trans., 86, 959-963. https://doi.org/10.1039/ft9908600959
  36. Wang, Z.L. (2008), "Towards self-powered nanosystems: From nanogenerators to nanopiezotronics", Adv. Funct. Mater. 18, 3553-3567. https://doi.org/10.1002/adfm.200800541
  37. Washo, B.D. (1977), "Rheology and modeling of the spin coating process", IBM J. Res. Develop., 190-198.
  38. Yuan, H. and Zhang, Y. (2004), "Preparation of well-aligned ZnO whiskers on glass substrate by atmospheric MOCVD", J. Cryst. Growth., 263, 119-124. https://doi.org/10.1016/j.jcrysgro.2003.11.084
  39. Zhang, H., Yang, D.R., Ma, X.Y., Du, N., Wu, J.B. and Que, D.L. (2006), "Straight and thin ZnO nanorods: Hectogram-scale synthesis at low temperature and cathodoluminescence", J. Phys. Chem. B, 110, 827-830. https://doi.org/10.1021/jp055351k

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