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Effects of oxygen partial pressure on the properties of indium tin oxide film on PET substrates by RF magnetron sputtering

RF 마그네트론 스퍼터링법에 의해 PET 기판 위에 증착된 ITO 박막의 특성에 대한 산소 분압의 영향

  • Kim, Seon Tae (Department of Nano Fusion Technology, Pusan National University) ;
  • Kim, Tae Gyu (Department of Nanomechatronics Engineering, Pusan National University) ;
  • Cho, Hyun (Department of Nanomechatronics Engineering, Pusan National University) ;
  • Kim, Jin Kon (Department of Nanomechatronics Engineering, Pusan National University)
  • 김선태 (부산대학교 나노융합기술학과) ;
  • 김태규 (부산대학교 나노메카트로닉스공학과) ;
  • 조현 (부산대학교 나노메카트로닉스공학과) ;
  • 김진곤 (부산대학교 나노메카트로닉스공학과)
  • Received : 2014.11.11
  • Accepted : 2014.12.12
  • Published : 2014.12.31

Abstract

Indium tin oxide (ITO) films with various oxygen partial pressure from 0 to $6{\times}10^{-5}$ Pa were prepared onto polyethylene terephthalate (PET) using RF magnetron sputtering at room temperature. The structural, electrical and optical properties of the grown ITO films were investigated as a function of the oxygen partial pressure. The amorphous nature of the ITO films was dominant at the partial pressure below $1{\times}10^{-5}$ Pa and the degree of crystallinity increased as the oxygen concentration increased further. This structural change comes with the increased carrier concentration and reduction of the electrical resistivity down to $9.8{\times}10^{-4}{\Omega}{\cdot}cm$. The average transmittance (at 400~800 nm) of the ITO deposited on the PET substrates increased as the oxygen partial pressure increased and transmittance above 80 % was achieved with the partial pressure of $4{\times}10^{-5}$ Pa. The results show that the choice of optimal oxygen partial pressure can present improved film crystallinity, the increased carrier concentration, and the enhancement in the electrical conductivity.

ITO(indium tin oxide) 박막을 RF 마그네트론 스퍼터링법에 의해 산소 분압을 0에서 $6{\times}10^{-5}$ Pa로 변화시킨 조건 하에서 PET 기판 위에 증착하였고, 산소 분압에 따른 ITO 박막의 전기적, 광학적 특성과 결정성의 변화를 조사하였다. 산소 분압이 $1{\times}10^{-5}$ Pa 이하에서는 증착된 ITO 박막은 비정질 구조를 가지는 반면에 $2{\times}10^{-5}$ Pa 이상에서는 결정질임을 확인하였다. 이러한 구조적 변화와 더불어 전하 캐리어 농도와 비저항이 증가하였다. 산소 분압이 $4{\times}10^{-5}$ Pa에서 최소 비저항($9.8{\times}10^{-4}{\Omega}{\cdot}cm$)을 얻을 수 있었다. ITO/PET 박막의 광투과율도 산소 분압이 증가함에 따라 증가하였으며 산소 분압 $4{\times}10^{-5}$ Pa에서 80 % 이상을 나타내었다. 본 연구를 통하여 최적의 산소 분압 선정이 ITO 박막의 결정성 향상, 캐리어 밀도 향상 그리고 전기전도도 향상 효과를 나타냄을 확인하였다.

Keywords

References

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